• Proceedings of the Korean Radioactive Waste Society Conference
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• 2004.06a
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• pp.292-303
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• 2004

The previous exponential experiment system has been improved for the automatical and accurate axial movement of the neutron source and detector with attaching the automatical control system which consists of a Programmable Logical Controller(PLC) and a stepping motor set. The automatic control program which controls MCA and PLC consistently has been also developed on the basis of GENIE 2000 Library. The exponential experiments have been carried out for Kori 1 unit spent fuel assemblies, Cl4, Jl4 and G23, and Kori 2 unit spent fuel assembly, J44, using the improved systematical measurement system. As the results, the average exponential decay constants for 4 assemblies are determined to be 0.1302, 0.1267, 0.1247, and 0.1210, respectively, with the application of Poisson regression.

• Journal of Korean Society for Atmospheric Environment
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• v.12 no.3
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• pp.341-350
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• 1996

We determined 6 polycyclic aromatic hydrocarbons (PAHs) fluranthene, pyrene, benz(a)anthracene, chrysene, benzo(a)pyrene, dibenzo(a,h)anthracene). A total of 129 samples has been collected from September 1990 to September 1994 on 2 different types of filters (quartz fiber filter, glass fiber filter) by a PM-10 high volume air sampler at the Kyung Hee University-Suwon campus. The organic components in the PM-10 were extracted by an ultrasonication process with benzene:ethanol(4:1, v/v) prior to the analysis by using a GC/FID. We had also investigated the decaying quantity of 6PAHs at the room temperature. For example, chrysene was decayed by 56.7% after 4 days and benzo(a)anthracene by 84.2% after 30 days. All of PAHs were almost completely decayed after a year. We extensively estimated the decay rates by regression analyses for existing 18 raw data sets. Based on the decay rate constants $(\beta)$, pyrene was rapidly decayed by 19.0 $\times 10^{-2}$/day; on the other hand, dibenzo(a,h)anthracene slowly by 0.7 $\times 10^{-2}$/day. Applying the decay rates of PAHs on stored and dated samples, we could reasonably determine annual and seasonal concentration average of PAHs in particulate matters smaller than 10 $\mu$m.

• Bulletin of the Korean Chemical Society
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• v.24 no.11
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• pp.1675-1679
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• 2003

The photodynamics of excited-state intramolecular proton transfer reaction of 1-hydroxyanthraquinone (1-HAQ) and 1-deuterioanthraquinone was investigated in toluene with time-resolved emission and femtosecond transient transmittance techniques at room temperature. The temporal profiles of transient transmittance of 1-HAQ could be well described with multi-decaying time constants. The ultrafast time constant within ca. 260 fs reflects the dynamics of proton transfer. The decay component of 2 ps is assigned to an additional proton translocation process induced by the intramolecular vibrational relaxation, whereas the decay component of 18 ps is assigned to the vibrational cooling process, while the long component (200 ps) can be explained in terms of the relaxation from excited-state keto-tautomer to its ground state. Time-resolved anisotropy decay dynamics and isotope effects on the photodynamics reveals that the ESIPT from enol-tautomer to keto-one of 1-HAQ is barrierless reaction and coupled to a vibrational relaxation process.

• Nuclear Engineering and Technology
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• v.52 no.12
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• pp.2910-2917
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• 2020

Digital light processing three-dimensional (3D) printing technique is a powerful tool to rapidly manufacture plastic scintillators of almost any shape or geometric features. In our previous study, the main properties of light output and transmission were analyzed. However, a more detailed study of the other properties is required to develop 3D printed plastic scintillators with expectable and reproducible properties. The 3D printed plastic scintillator displayed an average decay time constants of 15.6 ns, intrinsic energy resolution of 13.2%, and intrinsic detection efficiency of 6.81% for 477 keV Compton electrons from the ¹³⁷Cs γ-ray source. The 3D printed plastic scintillator showed a similar decay time and intrinsic detection efficiency as that of a commercial plastic scintillator BC408. Furthermore, the presented estimates for the properties showed good agreement with the analyzed data.

• Bulletin of the Korean Chemical Society
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• v.9 no.1
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• pp.17-21
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• 1988

A mechanistic study on the chemiluminescence resulting from the reaction between bis(2,4,6-trichlorophenyl)oxalate(TCPO) and hydrogen peroxide in the presence of fluorescent polycyclic aromatic hydrocarbons in a viscous phthalate medium has been conducted. The rate determining step, decay rate constants, and relative quantum efficiencies yielded by varying the concentration of reagents generally support an existing mechanism. However, a reaction between TCPO and sodium salicylate was not observed.

• Geomechanics and Engineering
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• v.3 no.1
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• pp.61-81
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• 2011

In this paper, a complement to the Hoek-Brown criterion is proposed in order to derive the strength of anisotropic rock from strength of the corresponding truly intact rock. The complement is a decay function, which unlike other modifications or suggestions made in the past, is multiplied to the function of the original Hoek-Brown failure criterion for intact rock. This results in a combined and extended form of the criterion which describes the strength of anisotropic rock as a varying fraction of the corresponding truly intact rock strength. Statistical procedures and in particular regression analyses were conducted into data obtained in experiments conducted in the current research program and those collected from the literature in order to define the Hoek-Brown's criterion complement. The complement function was best described by a simple polynomial including only three constants to be empirically evaluated. Further investigations also showed that these constants can be related to the other readily available parameters of rock material which further facilitate determining the constants. A great and prime advantage of the proposed complement is that it is mathematically simple including the least possible number of empirical constants which are easily estimated with minimum experimental effort. Moreover, proposed concept does not suggests any change to the original Hoek-Brown criterion itself or its constants and serves whenever anisotropy does exist in the rock. This further implies on the possibility of using any other failure criterion for intact rock in conjunction with the compliment to reach the strength of anisotropic rock.

• Journal of Environmental Health Sciences
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• v.33 no.4
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• pp.255-263
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• 2007

Indoor air quality is the dominant contributor to total personal exposure because most people spend a majority of their time indoors. The purposes of this study were to evaluate the alternative method for improvement of indoor air quality in house after coating titanium dioxide ($TiO_2$) photocatalyst for interior part of the house using nitrogen dioxide ($NO_2$) multiple measurements. To evaluate the alternative method in indoor environment, daily indoor and outdoor $NO_2$ concentrations of an apartment and a detached house were daily measured for consecutive 21 days in winter and summer, respectively, Another daily 21 measurements were carried out after $TiO_2$ coating on wall paper of interior part in houses. All $NO_2$ concentrations were measured by passive filter badges. Indoor air quality models using mass balance are useful tool to quantify the relationship between indoor air pollution levels, ambient concentrations, and explanatory variables. Using a mass balance model and linear regression analysis, penetration factor (ventilation rate divided by sum of ventilation rate and decay rate) and source strength factor (emission rate divided by sum of ventilation rate and decay rate) were calculated. Subsequently, the decay constants were estimated. In this study. magnitude of improvement of indoor air quality could be evaluated by decay constant.

• Journal of Korean Society of Water and Wastewater
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• v.12 no.2
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• pp.90-98
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• 1998

The optimal rechlorination in water distribution systems was investigated by incorporating optimization techniques into a numerical water quality model. For a hypothetical system that consists of 10 junctions including a storage tank and 12 links, the bulk ($k_b$) and pipe-wall ($k_w$) decay-rate constants of chlorine residual are assumed to be 2.0 1/day and 1.5 m/day, respectively. It was also assumed that the lower and upper limits of chlorine residual in the network are 0.2 mg/L and 0.6 mg/L. When the chlorine source is only the storage tank (without rechlorination), the high levels of chlorine residual appear near the storage tank to maintain the chlorine residuals above the lower limit over the junctions. On the other hand, the chlorine residuals in the network are distribute within the desirable range (0.2 - 0.6 mg/L) after the optimal rechlorination through five injection sites including the storage tank. In case of a real water distribution system that comprises 28 junctions including a clear well and 27 links, the bulk and pipe-wall decay-rate constants are 0.3 1/day and 0.2 m/day, respectively. Before rechlorination, the required chlorine residual at the clearwell is 5.1 mg/L to keep the chlorine residuals above the minimum level (0.6 mg/L) over the junctions. By the optimal rechlorination at five injection sites, the chlorine residuals are distributed within a desirable range of 0.6 mg/L through 2.0 mg/L, which can avoid the excess of chlorine residuals near the clear well. Consequently, total chlirine doses are decreased by 81% in the hypothetical distribution network and 69 % in the real distribution network for satisfying the minimum chlorine residuals.

• Journal of Photoscience
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• v.9 no.2
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• pp.314-316
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• 2002

In halobacterial membrane, pharaonis phoborhodopsin (or pharaonis sensory rhdopsin II, psRII) forms a complex with its transducer pHtrII. Flash-photolyis of D75N mutant did not yield M-intermediate but an O-like intermediate is observed. We examined the interaction between D75N of ppR and t-Htr (truncated pHtrII). These formed a complex in the presence of n-dodecyl-$\beta$-D-maltoside, and the association accelerated the decay of the 0 of D75N from 15 to 56 s$\^$-1/. From the decay time constants under varying ratios of D75N and t-Htr, n, the molar ratio of D75N/t-Htr in the complex, and K$\_$D/, the dissociation constant, were estimated. The value of n was unity and K$\_$D/ was estimated to 146 nM. This K$\_$D/ value can be considered as the association between the photo-intermediate and t-Htr, which is deduced by the method of estimation. Previously we (Photochem. Photobiol. 74, 489-494 (2001)) reported K$\_$D/ of 15 $\mu$M for the interaction between the wild-type and t-Htr by means of the change of M-decay rates. Therefore, this value should be the K$\_$D/ value for the interaction between M of the wild-type and t-Htr.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.06a
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• pp.469-470
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• 2008

We have studied electro-optic characteristics as a function of splay elastic constants ($K_{11}$) in the fringe-field switching (FFS) mode using the LC with positive dielectric anisotropy. When $K_{11}$ is increased from 7.7pN to 11.7pN, a maximum transmittance is slightly increased and rising time become a little bit fast. However, operating voltage and threshold voltage is independent. In opposition to rising time, decay time is not affected by $K_{11}$. We already know that $K_{11}$ affects tilt angle of liquid crystals. Therefore, on the occasion of high $K_{11}$, liquid crystals are mainly affected by twist deformation because the higher $K_{11}$, the less tilt angle. In the FFS device, high $K_{11}$ is favorable to reduce tilt angle in on state and thus improve rising response time.