• Title/Summary/Keyword: Debye

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Generation of Maxwell Displacement Current Across Single monolayers due to Phase transition

  • Mitsumasa Iwamoto;Wu, Chen-Xu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.05a
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    • pp.6.1-10
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    • 1996
  • Starting from the Debye theory of rotational Brownian motion equation, we derive an expression for explaining the generation of Maxwell displacement current (MDC) across single monolayers on a material surface. The orientational order parameter and the dielectric relaxation the of monolayers are derived. Based on fille analyses developed here, we examine the MDC across phospholipid monolayers with thermal stimulation due to the change in the spontaneous polarization, and the generation of MDC from 4-cyano-4\`-5-alkayl-biphenyl(5CB) Langmuir-film at the onset of transition by monolayer compression

Electrical Transport Properties of $La_{0.7}Sr_{0.3}FeO_{3}$ ($La_{0.7}Sr_{0.3}FeO_{3}$ 세라믹스의 전기전도 특성)

  • 정우환
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.5
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    • pp.376-382
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    • 2001
  • Magnetic and transport properties in the ceramic specimen of L $a_{0.7}$S $r_{0.3}$Fe $O_3$ with orthohombic structure has been investigated. Weak ferromagnetism has been observed in a ceramic sample of L $a_{0.7}$S $r_{0.3}$Fe $O_3$. Large dielectric relaxation of Debye type is observed in paramagnetic states within the temperature range of 130K~200K. From the temperature dependence of the characteristic frequency, we concluded that the elementary process of the dispersion is related to holes hopping between F $e^{3+}$ and F $e^{4+}$ ions. The temperature dependencies of thermoelectric power and Dc conductivity suggest that the charge carrier responsible for the conduction are strongly localized. These experimental results have been interpreted in terms of a hopping process involving small polaron.n.laron.n.

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Generation of Open Circuit Voltage in LB Ultra Thin Films (LB 초박막의 전압발생)

  • Kwon, Young-Soo;Kang, Dou-Yol
    • Proceedings of the KIEE Conference
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    • 1988.07a
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    • pp.796-798
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    • 1988
  • Langmuir-Blodgett(LB) films of arachic acid and TCNQ(tetracyanoquinodimethane) were prepared in the sample of Al/LB film/Al type where Al are electrodes, and polarization in LB film and dipolar moment of molecules in the films were measured by themally stimulated current(TSC). It is ascertaind in our experiments that dipolar mament of $C_{12}$TCNQ molecule was about 13-15 debye and the moment was directed from the alkyle chain toward TCNQ. Generation of the open circuit voltage was investigated on the z-type and Hetero structure of LB films.

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Partial molal volume and viscosity of anilinium chloride in water at various temperatures (여러온도에서 염화아닐린늄의 수용액중에서의 분몰랄부피 및 점도에 관한 연구)

  • Byung-Rin Cho;Young-Ja Lee;Kwang-Ho Kim
    • Journal of the Korean Chemical Society
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    • v.15 no.2
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    • pp.85-93
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    • 1971
  • Apparent molal valumes ${\phi}_v$ and relative viscosities ${\eta}_r$ of aqueous solutions of anilinium chloride have been determined at two degree intervals from 20 to $50^{\circ}C$ in the molar concentration range 0.003 < C < 0.4. The results are discussed in terms of partial molal volumes $\={V}^{\circ}$, deviations from the Debye-H$\''{u}$ckel limiting law, partial molal expansibilities $\={E}^{\circ}$, viscosity B coefficients calculated from the Jones-Dole equation, and energy of activation for viscous flow. In aqueous solution, anilinium chloride was found to be a weak structure-maker due to its hydrophobic group.

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Dielectric Characterization of Unsaturated Polyester Curing (불포화 폴리에스터의 경화에 따른 유전특성 연구)

  • 오경성;김홍경;김명덕;남재도
    • Polymer(Korea)
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    • v.26 no.6
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    • pp.728-736
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    • 2002
  • The thermal and dielectric properties of unsaturated polyester resin system during cure were analyzed under Isothermal conditions. Both $varepsilon$′ and $varepsilon$" decreased and dipole relaxation was observed under isothermal conditions during cure. The ionic conductivity decreased linearly with the conversion according to the Kienle-Rate equation (ln($varepsilon$"$_{ionic}$we$_{0}$)=C$_{r}$$alpha$+C$_{0}$) up to $alpha$=0.15, after which it aparted from the relationship due to the entanglement of polymer chains. The effect of ionic conductivity was revealed to be larger than that of dipole motion during the whole cure through the electrical modulus analysis. Although dielectric motion was analyzed with Debye model, it was observed only at a narrow time region of middle stage of cure. In order to estimate the dielectric properties during the whole cure, the Havriliak-Negami model was considered and modified with the strong effect of ionic conductivity. The changes of $varepsilon$′ and $varepsilon$" were well estimated with this modified Havriliak-Negami model.

Mossbauer Study of EuxFe2-xO3 (x0.8 and 0.7)

  • Kim, J. G.;Kim, E. C.
    • Journal of Magnetics
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    • v.2 no.2
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    • pp.42-45
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    • 1997
  • The microscopic physical properties of nonstoichiometric garnet EuxFe2-xO3 (x=0.8 and 0.7) have been studied by the methods of X-ray diffraction at room temperature and M ssbauer spectroscopy within the temeperature range of 12-560 K. The X-ray diffraction patterns of the samples show coexistence of dominant garnet and a small portion of unknown crystal phase. But the M ssbauer spectra for the sample of EF08 and EF07 near N el temperature determined to be equally 549$\pm$5K show that there are no any other extra crystal phases within the experimental error. The results of which the temperature dependence of M ssbauer parameters was anlyzed by the spin-wave theory and Debye model are in good agreement with the fact that the sample of EF08 has some vacancies at a-and/or d-sites.

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A Partition Function for Liquid Metals (液體金屬의 常態和)

  • Kim, Wan-Kyue
    • Journal of the Korean Chemical Society
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    • v.6 no.1
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    • pp.36-46
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    • 1962
  • The author assumes that pure liquid metal is composed of molecular oscillators whose energy states are classified into two subgroups, i.e., A and B states, each being accesible to either one of the two sorts of lattice sites. The partition function involves constants characteristic of substance, which are obtainable from the Debye characteristic temperature assigned to its solid state. Calculation has been made for the various thermodynamic properties such as the vapor pressure, the entropy, and the heat capacity of liquid metals of GroupⅠelements over the temperature range from the melting points to the boiling points. The theoretical values thus obtained are in good accordances with those observed, within experimental error, although a slight derivation is observed in the atomic heat capacity.

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Temperature Compensation of Complex Permittivities of Biological Tissues and Organs in Quasi-Millimeter-Wave and Millimeter-Wave Bands

  • Sakai, Taiji;Wake, Kanako;Watanabe, Soichi;Hashimoto, Osamu
    • Journal of electromagnetic engineering and science
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    • v.10 no.4
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    • pp.231-236
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    • 2010
  • This study proposes a temperature compensation method of the complex permittivities of biological tissues and organs. The method is based on the temperature dependence of the Debye model of water, which has been thoroughly investigated. This method was applied to measured data at room temperature for whole blood, kidney cortex, bile, liver, and heart muscle. It is shown that our method can compensate for the Cole-Cole model using measured data at 20 $^{\circ}C$, given the Cole-Cole model based on measured data at 35 $^{\circ}C$, with a root-mean-squared deviation of 3~11 % and 2~6 % for the real and imaginary parts of the complex permittivities, respectively, among the measured tissues.

Numerical Analysis of Electroosmotically Enhanced Microchannel Heat Sinks (전기삼투를 이용한 미세열방출기의 수치해석)

  • Husain, Afzal;Kim, Kwang-Yong
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.2544-2547
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    • 2008
  • A micro channel heat sink has been studied and optimized for mixed pressure driven and electroosmotic flows through three-dimensional numerical analysis. The effects of ionic concentration represented by zeta potential and Debye thickness are studied with the various steps of externally applied electric potential. Optimization of the micro channel heat sink has been performed considering two design variables related to the micro channel width, depth and fin width. The surrogate-based optimization is performed using a search algorithm taking overall thermal resistance as objective function. The thermal resistance is found to be more sensitive to channel width-to-depth ratio than fin width-to-depth of channel ratio.

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M ssbauer Study and Atomic Migration in MgFe2O4

  • Lee, Seung Wha;Yoon, Sung Hyun;An, Sung Yong;Kim, Woo Chul;Kim, Chul Sung
    • Journal of Magnetics
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    • v.4 no.4
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    • pp.115-118
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    • 1999
  • $MgFe_2O_4$ has been studied with X-ray diffraction, M ssbauer spectroscopy and vibration sample magnetometer (VSM). The crystal structure of the sample is found to have a cubic spinel structure with a lattice constant of $a_0=8.390$\pm$0.005$\AA$.$ The iron ions at both A (tetrahedral) and B (octahedral)sites are found to be in ferric high-spin states. Its Neel temperature TN is found to be 710$\pm$3 K. The Debye temperature for the A and B sites found to be 417$\pm$5 K and 331$\pm$5 K., respectively. Atomic migation from the A to the B sites starts near 425 K and increases rapidly with increasing temperature to such a degree that 31% of the ferric ions at the A sites have moved over to the B sites by 600 K.

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