• Bulletin of the Korean Chemical Society
• /
• v.27 no.2
• /
• pp.255-265
• /
• 2006

The oxidation of hydrazobenzene by molecular oxygen in the polar solvent methanol is catalysed by a Schiff's base complex Co(3MeOsalen) which is a synthetic oxygen carrier. The products are trans-azobenzene and water. The rate of the reaction has been studied spectrophotometrically and the rate law established. A mechanism involving a ternary complex of catalyst, hydrazobenzene and molecular oxygen has been proposed. The kinetic studies show that a ternary complex $CoL{\cdot}H_2AB{\cdot}O_2$ is involved in the rate determining step. The reactions are summarised in a catalytic cycle. The kinetic data suggest that a ternary complex involving Co(3MeOsalen), triphenyl-phosphine and molecular oxygen is catalytically acive species but at higher triphenylphosphine concentrations the catalyst becomes inactive. The destruction of the catalytic activity could be due to the catalyst becoming coordinated with triphenyl phosphine at both z axis sites of the complex e.g. Co (3MeOsalen)$(PPh_3)_2$.

• Structural Engineering and Mechanics
• /
• v.29 no.1
• /
• pp.77-89
• /
• 2008

Presence of high degree of orthotropy enhances shear lag phenomenon in laminated composite box-beams and it persists till failure. In this paper three key parameters governing shear lag behavior of laminated composite box beams are identified and defined by simple expressions. Uniqueness of the identified key parameters is proved with the help of finite element method (FEM) based studies. In addition to this, for the sake of generalization of prediction of shear lag effect in symmetrical laminated composite box beams a feed forward back propagation neural network (BPNN) model is developed. The network is trained and tested using the data base generated by extensive FEM studies carried out for various b/D, b/tF, tF/tW and laminate configurations. An optimum network architecture has been established which can effectively learn the pattern. Computational efficiency of the developed ANN makes it suitable for use in optimum design of laminated composite box-beams.

• Proceedings of the Korean Nuclear Society Conference
• /
• 2002.10a
• /
• pp.155.2-155
• /
• 2002

A visual environment for system analysis codes (hereinafter called "ViSA") has been developed to support code users in their input preparations, code executions, and output interpretations. ViSA provides a more convenient way for base input data generation and modification on a user-friendly basis. It also provides on-line graphical displays to give an in-depth understanding of transient thermal-hydraulic behaviors in nuclear power plants. This paper presents the main features of ViSA.

• Journal of Biosystems Engineering
• /
• v.33 no.3
• /
• pp.186-195
• /
• 2008

In this paper, a prototype tele-operative system with a mobile base was developed in order to automate cultivation of house melon. A man-machine interactive hybrid decision-making system via tele-operative task interface was proposed to overcome limitations of computer image recognition. Identifying house melon including position data from the field image was critical to automate cultivation. And it was not simple especially when melon is covered partly by leaves and stems. The developed system was composed of 5 major modules: (a) main remote monitoring and task control module, (b) wireless remote image acquisition and data transmission module, (c) three-wheel mobile base mounted with a 4 dof articulated type robot manipulator (d) exchangeable modular type end tools, and (e) melon storage module. The system was operated through the graphic user interface using touch screen monitor and wireless data communication among operator, computer, and machine. Once task was selected from the task control and monitoring module, the analog signal of the color image of the field was captured and transmitted to the host computer using R.F. module by wireless. A sequence of algorithms to identify location and size of a melon was performed based on the local image processing. Laboratory experiment showed the developed prototype system showed the practical feasibility of automating various cultivating tasks of house melon.

• Journal of KIISE:Computing Practices and Letters
• /
• v.10 no.4
• /
• pp.309-318
• /
• 2004

This paper proposes the H.264-based selective fine granular scalable (FGS) coding scheme that selectively uses the temporal prediction data in the enhancement layer. The base layer of the proposed scheme is basically coded by the H.264 (MPEG-4 Part 10 AVC) visual coding scheme that is the state-of-art in codig efficiency. The enhancement layer is basically coded by the same bitplane-based algorithm of the MPEG-4 (Part 2) fine granular scalable coding scheme. In this paper, we introduce a new algorithm that uses the temproal prediction mechanism inside the enhancement layer and the effective selection mechanism to decide whether the temporally-predicted data would be sent to the decoder or not. Whenever applying the temporal prediction inside the enhancement layer, the temporal redundancies may be effectively reduced, however the drift problem would be severly occurred especially at the low bitrate transmission, due to the mismatch bewteen the encoder's and decoder's reference frame images. Proposed algorithm selectively uses the temporal-prediction data inside the enhancement layer only in case those data could siginificantly reduce the temporal redundancies, to minimize the drift error and thus to improve the overall coding efficiency. Simulation results, based on several test image sequences, show that the proposed scheme has 1∼3 dB higher coding efficiency than the H.264-based FGS coding scheme, even 3∼5 dB higher coding efficiency than the MPEG-4 FGS international standard.

• The Journal of Korean Institute of Communications and Information Sciences
• /
• v.38A no.3
• /
• pp.277-288
• /
• 2013

3GPP LTE-Advanced (Third Generation Partnership Project Long Term Evolution-Advanced) as a next generation mobile communication standard introduced small base stations such as femto cells or pico cells, and D2D (Device-to-Device) communications between mobiles in the proximity in order to satisfy the needs of rapidly growing wireless data traffic. A diverse range of topics has been studied to solve various interference situations which may occur within a single cell. In particular, an introduction of a small base station along with D2D communication raises important issues of how to increase the channel capacity and frequency efficiency in HetNets (Heterogeneous Networks). To this end, we propose in this paper methods to manage the interference between the macro cell and other small cells in the HetNet to improve the frequency efficiency. The proposed CCN (Cluster Coordinator Node)-assisted ICI (Inter-Cell Interference) avoidance methods exploit the CCN to control the interference in HetNet comprising of an MeNB (Macro enhanced Node-B) and a large number of small cells. A CCN which is located at the center of a number of small cells serves to avoid the interference between macro cell and small cells. We propose methods of resource allocation to avoid ICI for user equipments within the CCN coverage, and evaluate their performance through system-level computer simulations.

• Journal of the Korean Society for Precision Engineering
• /
• v.14 no.11
• /
• pp.17-24
• /
• 1997

Despite the increasing demands for improved product design, a limited number of works have been reported in the field of sheet metal forming. In the present study, introducing the Taguchi method, an otpimal and robust combination of parameters in found and a data base management system is utilized for knowledge acquisition. Analysis data, estimation rules of formability and graphical representation of the analysis have been employed for the dewigner's understanding and evaluation. The developed system is applied to a deep drawing process. Through the present study, it is shown that the developed systerm is useful for the design and the formability estimation of sheet metal forming processes.

• Journal of Broadcast Engineering
• /
• v.23 no.2
• /
• pp.316-319
• /
• 2018

When a terrestrial UHD broadcasting service and a mobile HD broadcasting service are provided using the PLP function provided by ATSC 3.0 and domestic UHD broadcasting standard, a small amount of data may be additionally transmitted to further provide high quality UHD-3D broadcasting service. The left and right images of the stereoscopic image are input, one view image is encoded by the SHVC method, and the other view images are encoded by the SHVC method of the two-view cross-referencing method. However, since the base layers (BL) of the two encoders are mutually common, the two encoders correspond to encoders that generate one BL stream and two enhancement layer (EL) streams. The average encoding efficiency is 16% more efficient compared to the third independent HEVC encoding for the UHD-3D broadcast service. The proposed scheme reduces the fluctuation of PSNR per image frame and increases the image quality of minimum PSNR frame by 0.6dB.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
• /
• v.15 no.1
• /
• pp.1-7
• /
• 1997

In the digital mapping for data base contruction, the positional information is used as an important tool in LIS/GIS(Land Information System/Geographic Information System) that is used for a facility management, urban/cadastral management as well as in spatial analysis. In this paper, for an error analysis of X, Y coordinates data on digital map, test area was classified by topography, density, and slope. The coordinates on topographic map were assumed as true values and they were compared with the coordinates on digital map. A result of the numerical test show that a vector data of line type had more gross error than vector data of polygon type. And, SME(stanadrd mean error) of urban or intermountain area had small values compared to that of suburban area in topography analysis. The SME of dense and middle zone had small values compared to that of loose zone in density analysis. In another slope analysis. the SME of steep of gentle slope had small values compared to that of flatland.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
• /
• v.8 no.4
• /
• pp.390-402
• /
• 1997

The ignition noises from the vehicle are measured and the measurement data are statistically treated for modeling. The low-noise amplifier and band-pass filter are added between the receiver and the three axes antenna for low noise level measurement and the APD and PSD are measured in 800 MHz frequency range. The measured APD curves can be expressed in terms of sensitivity study of each model through 3(class A) or 6(Class B) parameters variation, and these optimal parameter can easily be calculated by using the Composite Approximation Algorithm. The selected APD parameter can be used for making the Data Base EM-environments and also applied to determine the output and sensitivity margin for the transmitter and receiver. 'Digital microwave transmission systems are equipped with equalizer against fading during multipath fading. In this paper, we proposed variable reference tap position equalizer that varies the reference tap according to fading type to archive better performance. We got the perf？mance improvement about 4~5 dB in MP condition and 2~3 dB in NMP condition from simulation results.