• Journal of the Korean Ceramic Society
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• v.39 no.8
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• pp.721-727
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• 2002

In order to overcome trade-off among compositions, process and properties of the glasses with high PbO-base composition for PDP Rib, we studied glass crystallization and crystallization kinetics by Differential Thermal Analysis(DTA). Glass powder was obtained through melting/cooling/grinding, with 3 wt%TiO2 addition for the crystal nucleation and growth in $62PbO-19B_2O_3-10SiO_2-9(Al_2O_3-K_2O-BaO-ZnO)$(in wt%) composition glass. This powder was heat-treated for 1 to 10 h at $445^{\circ}C$ for nucleation. DTA measurements were performed to obtain the crystallization peak with $5∼25^{\circ}C/min$ heating rates. DTA crystallization peak temperature increased with increasing the heating rate and decreased with increasing the heating time. Because the Avrami parameter (n) was approximately 1, the surface crystallization occurred. The maximum nucleation time was 2 h.

• Journal of the Korean Wood Science and Technology
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• v.35 no.6
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• pp.31-42
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• 2007

To investigate the pyrolytic and anatomical characteristics of Korean softwood, Pinus densi-flora, Pinus rigida and Larix leptolepis, and hardwood, Acer palntatum, Fraxinus rhynchophylla and Quercus variabilis, chemical components analysis, TG-DTA (Thermogravimetric Analysis & Differential Thermal Analysis), MBA (Methylene Blue Adsorption) test and SEM observation were carried out. For TG-DTA, samples were carbonized up to $800^{\circ}C$ at the heating rate of $10^{\circ}C$/min under $N_2$ flows 1 l/min using thermogravimetric analyzer. Chemical component analysis of all samples resulted in typical contents of major wood component. In TG-DTA results, softwood showed higher char yield than hardwood, and lignin displayed the highest char yield among the major wood components. All samples showed typical TGA, DTG and DTA curves for wood pyrolysis except a few differences between softwood and hardwood. Content of lignin influenced its pyrolysis characteristics, while molecular structure of lignin affected not only the weight loss but also the yield of char. In MBA test results, MBA of softwoods was higher than that of hardwoods. Char of Pinus densiflora showed the highest MBA, but its degree was lower than activated carbon or fine charcoal about 23 and 4 times, respectively. SEM observation showed carbonization process preserves wood structure and retain the micro-structure of wood fibers.

• Journal of Korean Society of Transportation
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• v.19 no.3
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• pp.101-113
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• 2001

Since late 1970s. one of the principal research areas in transportation problem is dynamic traffic assignment (DTA). Although many models have been developed regarding DTA, yet they have some limits of describing real traffic patterns. This reason comes from the fact that DTA model has the time varying constraints such as state equation, flow propagation constraint, first in first out(FIFO) rule and queuing evolution. Thus, DTA model should be designed to satisfy these constraints as well as dynamic route choice condition, dynamic user equilibrium. In this respect, link-based DTA models have difficulty in satisfying such constraints because they have to satisfy the constraints for each link, while path-based DTA models may easily satisfy them. In this paper we develop a path-based DTA model. The model includes point queue theory to describe the queue evolution and simulation loading method for depicting traffic patterns in more detail. From a numerical test, the model shows promising results.

• Journal of the Korean Chemical Society
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• v.39 no.4
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• pp.275-280
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• 1995

The electron transfer reactions between cis-[Co(en)2(NO2)2]+ and rac-[Co(Y)]2-(Y=EDTA, PDTA, CyDTA) have been investigated in the presence of hydrogen ion. From the kinetic data, it has been found that electron transfer reactions between cis-[Co(en)2(NO2)2]+ and rac-[Co(Y)]2- proceed via inner-sphere pathway by catalysis of hydogen ion. The stereoselectivity in the electron transfer reactions between optically active △-cis-[Co(en)2(NO2)2]+ and rac-[Co(Y)]2- produced 6.0, 2.9, 3.0% e.e.(e.e.=enantiomeric excess) of △-[Co(EDTA)]-, △-[Co(PDTA)]- and △-[Co(CyDTA)]-, respectively. Based upon this observation, it seems that △-cis-[Co(en)2(NO2)2]+ is associated with rac-[Co(Y)]2- at first, and followed by the electron transfer reaction. Therefore, it was suggested that stereoselective electron transfer reaction between △-cis-[Co(en)2(NO2)2]+ and rac-[Co(Y)]2- proceed through both inner-sphere by the proton catalysis and outer-sphere with ionic association.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.26 no.7
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• pp.795-805
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• 2016

Nonlinear normal modes(NNMs) is a branch of periodic solution of nonlinear dynamic systems. Determination of stable periodic solution is very important in many engineering applications since the stable periodic solution can be an attractor of such nonlinear systems. Periodic solutions of nonlinear system are usually calculated by perturbation methods and numerical methods. In this study, numerical method is used in order to calculate the NNMs. Iteration of the solution is presented by multiple shooting method and continuation of solution is presented by pseudo-arclength continuation method. The stability of the NNMs is analyzed using Floquet multipliers, and bifurcation points are calculated using indirect method. Proposed analyses are applied to two nonlinear numerical models. In the first numerical model nonlinear spring-mass system is analyzed. In the second numerical model Jeffcott rotor system which has unstable equilibria is analyzed. Numerical simulation results show that the multiple shooting method can be applied to self excited system as well as the typical nonlinear system with stable equilibria.

• Journal of the Korean Ceramic Society
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• v.35 no.11
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• pp.1162-1170
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• 1998

Applicability of crystallization kinetics on thermal analysis was investigated for PbO-TiO2-B2O3-BaO glass systems together with theoretical background of kinetics and electron microscopic observations on nu-cleation and crystallization. Kissinger equation can be used on DTA under the assumption that the nucleus density is fixed during DTA runs. Crystallization mechanism affected on the activation energy Ek obtained from powder samples which is used for domination of surface crystallization. Avrami parameter n that was obtained from Ozawa equation represented closely the crystallization mechanisms observed by an electron microscope. The modified Kissinger equation takes into account crystallization mechanism thereby pro-ducing the true activation energy of crystallization.

• Journal of Korean Society for Quality Management
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• v.44 no.3
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• pp.473-486
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• 2016

Purpose: Although the price reduction policy is established for military supplies, it is more focused on general military items. Therefore, it is hard to apply the current price reduction policy directly to the major weapon system. The purpose of this study is to develop an evaluation model which generates appropriate outputs for price reduction of military supplies. Methods: To improve the current policy, we first analyze the relevant policies of price reduction of similar organizations. We gather the opinions of related organization through survey including DAPA, Logistics Command, DTaQ and Defense industry companies. Then, we develop a price reduction model based on the analytic hierarchical process(AHP) method to find out important factors for price reduction. Results: The results of AHP analysis show that the important factors when applying price reduction of military supplies. From the analysis, the proposed method effectively generates the amounts of price reduction for the nonconformance items. Conclusion: The results of this research will be used as guidelines to improve military supplies policy of price reduction.

• Journal of Soil and Groundwater Environment
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• v.18 no.5
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• pp.1-6
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• 2013

This study was performed to develop a method for quantitative analysis obtaining the amount of calcium carbonate minerals formed when Ca salts biomimetically reacted with carbon dioxide. There were two methods compared; 1) volumetric calcimeter method that determining the amount of released carbon dioxide after calcium carbonate minerals were acidified by 4N HCl and 2) Thermogravimetry-Differential Thermal Analysis (TG-DTA) adopting differential decomposition temperature breaking-up the structural link within calcium carbonate minerals. The comparisons were made by batch experiment (i.e., biocalcification process) along with control (i.e., nominal concentration of $CaCO_3$ prepared). For the control, TG-DTA took a minor root mean square deviation (RMSD) of 1.1~5.9 mg, whereas volumetric calcimeter exposed a greater RMSD of 28.3 mg. For the biocalcification, the amount of $CaCO_3$ was more precisely obtained for TG-DTA rather than that of volumetric calcimeter. It was decided that TG-DTA was more successfully used for quantitative analysis to observe the amount of calcium carbonate minerals derived from biocalcification.

• Journal of the Korea Institute of Military Science and Technology
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• v.14 no.5
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• pp.760-767
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• 2011

To strategically select the technology priority based on the understanding of technology development trends and prospects is very important. To provide such guidance for autonomous driving technology in unmanned ground combat vehicles, this report deals with followings; 1) The core technologies for autonomous driving are reviewed. 2) And domestic and foreign policies for relevant technology development are investigated. 3) Then, to estimate the technology development trend, the published patents and research papers are analyzed. 4) Based on those analyses, domestic technology level and development prospects are expected.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.11 no.1
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• pp.7-12
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• 2012

Chemical mechanical polishing(CMP) technology is faced with the challenge of processing new electronic materials. This paper focuses on the balance between chemical and mechanical reactions in the CMP process that is required to cope with a variety of electronic materials. The material properties were classified into the following categories: easy to abrade(ETA), difficult to abrade(DTA), easy to react(ETR) and difficult to react(DTR). The chemical and mechanical balance for the representative ETA-ETR, DTA-ETR, ETA-DTR and DTA-DTR materials was considered for defect-free surfaces. This paper suggests the suitable polishing methods and examples for each electronic material.