• Title/Summary/Keyword: DOC

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Decomposition Characteristics of Dissolved Organic Compounds in the Landfill Leachate by Ozone Oxidation (오존산화에 의한 매립지 침출수내 용존성 유기화합물의 분해 특성)

  • 정승현;이헌모;정병곤
    • Journal of environmental and Sanitary engineering
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    • v.18 no.1
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    • pp.23-29
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    • 2003
  • The effect of ozone oxidation on bio-degradability of leachate was studied. Ozone oxidation process was used as pre-treatment process to enhance performance of biological process in treating landfill leachate. Optimum ozone injection rate and contact time in this experiment was $160{\;}mg{\;}O_/{\ell}{\cdot}hr$ and 45 minutes, respectively. Bio-degradability was enhanced 5.08% by ozone oxidation. The ratio of ozone demand/DOC concentration was $0.049~0.091{\;}mg{\;}O_3/mg{\;}DOC$. The increase of bio-degradability depending on ozone injection rate(D) and contact time(T) can be expressed as follows ; The rate of bio-degradation of DOC was increased proportionally with the increase of ozone injection rate and contact time irrespective of landfill site age. The increase of bio-degradability by ozone addition was not satisfactory. It is hard to expect significant increase in bio-degradability by ozone treatment only. Thus, it is evaluated that ozone oxidation can not increase biodegradability significantly in concentrated wastewater composed of complex organic compound such as leachate.

Optimization of the Lowry Method of Protein Precipitation from the H. influenzae Type b Conjugate Vaccine Using Deoxycholic Acid and Hydrochloric Acid

  • Kim, Hyun-Sung;Kim, Sang-Joon;Kim, Hui-Jung;Kim, Han-Uk;Ahn, Sang-Joem;Hur, Byung-Ki
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.11 no.3
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    • pp.215-222
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    • 2006
  • The Lowry method was used in this study to measure protein in Haemophilus influenzae type b (Hib) conjugate vaccines (polyribosylibitol phosphate-tetanus toxoid; PRP-TT) using deoxycholic acid (DOC) to induce protein precipitation. Trichloroacetic acid (TCA) did not induce precipitation adequately from the Hib conjugate bulk and the freeze-dried Hib conjugate product. Its yield was approximately 50%. The matrix structure of Hib conjugate inhibits precipitation by TCA. Although the Lowry method can be carried out without precipitation in Hib conjugate bulk when no residual impurities (adipic acid dihydrazide [ADH], 1-ethyl-3-(3-dimethylamino-propyl) carbodiimide-HCI [EDAC], phenol and cyanogens bromide [CNBr], etc.) are present, it cannot be used for Hib conjugate products that contain sucrose 8.5%, because 8.5% concentration of sucrose enhanced the protein concentration. DOC- and HCl-induced precipitation is an alternative method for evaluating the protein content of the Hib conjugate bulk and the Hib conjugate product. The precipitation was optimal with a final concentrate of 0.1% for DOC at $4^{\circ}C$ and pH 2. This Lowry method, using DOC/HCI precipitation to induce protein precipitation, was confirmed a consistent, reproducible, and valid test for proteins in Hib conjugate bulk and its freeze-dried product.

The Characteristics of Soil Organic Matter

  • You Sun-Jae;Kim Jong-gu;Cho Eun-Il
    • Journal of Environmental Science International
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    • v.15 no.1
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    • pp.1-7
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    • 2006
  • The purpose of this study is to illustrate the characteristics of soil organic matter (SOM) and partition coefficient $(K_{DOC})$. Humic substances (HS) from eight soils of varying properties were extracted by two different methods. The dissolved organic carbon (DOC) concentration was stabilized in 22hrs. The ratio of UV absorbance at 465nm and 665nm (E4/E6 ratio) for HS were similar pattern for 8 soils. The extraction with increasing pH increased dissolution of SON. The ratio of organic carbon (OC) associated with HA and FA (the HA:FA ratio) was varied widely in accordance with the soils and was highly correlated to OC $content(\%)$ of the soils. in modeling metal speciation in soils and soil solutions, assumptions that all DOC in soil solution is associated with FA and that HA:FA ratio in SOM is constant have been made. The results of this study indicate that the validity of these assumptions is questionable. By sequential pH extraction, the $K_{DOC}$ showed in a linear correlation with pH.

Effect of Ozone Oxidation on Biodegradability of Dissolved Organic Compounds in the Landfill Leachate (오존산화가 매립지 침출수내 용존성 유기화합물의 생분해도에 미치는 영향)

  • Jeong, Seung-Hyun;Jeong, Byung-Gon
    • Journal of Korean Society on Water Environment
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    • v.21 no.1
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    • pp.1-6
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    • 2005
  • The effect of ozone oxidation on biodegradability of leachate was studied. Ozone oxidation process was used as pre-treatment process to enhance performance of biological process in treating landfill leachate. Optimum ozone dosing rate and contact time in this experiment was $160mg\;O_3/L$ hr and 45 minutes, respectively. Biodegradability was enhanced 5.08% by ozone oxidation. The ratio of ozone demand/DOC concentration was $0.049{\sim}0.091mg\;O_3/mg$ DOC. The increase of biodegradability depending on ozone dosing rate(D) and contact time(T) can be expressed as follows ; ${\Delta}E=0.00479{\cdot}D^{0.773}{\cdot}T^{0.800}$ The biodegradation rate of DOC was increased proportionally with the increase of ozone dosing rate and contact time irrespective of landfill site age. The increase of biodegradability by ozone addition was not satisfactory. It is hard to expect significant increase in biodegradability by ozone treatment only. Thus, it is evaluated that ozone oxidation can not increase biodegradability significantly in concentrated wastewater composed of complex organic compound such as leachate.

Characteristics of Biodegradation of Organic Matters in the Nakdong River Watershed (낙동강 수계 내 유기물 시료에 따른 생분해 특성)

  • Kim, Jung Sun;Kang, Lim Seok
    • Journal of Korean Society on Water Environment
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    • v.30 no.6
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    • pp.605-611
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    • 2014
  • This research was carried out to examine the concentration and fate of dissolved organic matter due to the increased detention time in middle and down stream of the Nakdong River. Aldo the characteristics of biodegradation of DOM were investigated according to the various water sources. The approaches used to characterize DOM biodegradability include the changes in DOC concentration and DOM fraction. Long-term biodegradation test for each organic source was also conducted. As the result, maximum 50% of DOC was reduced during the first 30 days of biodegradation tests. After 30 days, biodegradation of organic matter was continuously progressed, as showing continuous reduction of DOC. While DOC concentration was reduced, SUVA values for the organic matters were increased. Properties of dissolved organic matter by water sources also showed decreasing hydrophilic components while showing increased hydrophobic components. The more rapid reduction of the hydrophilic components than hydrophobic components might be due to the preferential degradation of the hydrophilic components by microorganisms during biodegradation process.

EFFECT OF KOREAN RED GINSENG POWDER (GP), ADMINISTERED ORALLY, ON BLOOD PRESSURE IN HYPERTENSIVE RATS (홍삼분말이 고혈압 쥐에 미치는 영향)

  • Sokabe Hirofumi;Kishi Koichiro;Watanabe Takushi X.
    • Proceedings of the Ginseng society Conference
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    • 1984.09a
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    • pp.127-132
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    • 1984
  • 이미 발표된, 혈압에 미치는 인삼의 효과에 관한 연구들의 보고는 서로 상반된 견해들이 많이 있다. 인삼에는 혈압상승작용과 혈압을 내려주는 효과가 모두 있다고 보고하였다. 본 저자들은 고혈압 쥐에 미치는 인삼의 급${\cdot}$만성효과를 연구하기 위해 일련의 2가지 실험을 하였으며, 실험재료로 사용한 홍삼은 일한홍삼주식회사에서 구입하였다. (실험 1) 홍삼분말을 일반 쥐사료에 혼합하여 (5g/kg), 임의로 사료를 섭취하게 하여 11주간 쥐를 사육하였으며, 하루에 섭취한 인삼의 양은 체중 kg당 $250{\~}750$mg이었다. 홍삼분말의 투여는 DON쥐, SHR쥐, 그리고 한개의 신장을 협자시킨 고혈압 쥐의 경우 혈압에 영향을 미치지 않았다. 홍삼분말의 투여는 DOC 쥐에 있어 혈압을 약간 상승시켰다. (실험 2) 홍삼분말을 체중 kg당 350mg씩 경구투여한 후 복대동맥에 카뉼제를 삽입하여 혈압을 24시간 직접 측정하였다. 그 결과 DOC쥐와 SHRSP쥐에 있어 혈압에 영향이 없었다. 이 실험에서는 마취를 시키지 않았으며, 자유로이 풀어 놓았다. 실험 1과 같이 매일 체중 kg당 $300{\~}500$mg씩 11주간 홍삼분말을 만성적으로 투여하였을 때, SHRSP쥐의 혈압에 영향이 없었다. DOC 고혈압 쥐의 경우 약간의 혈압 강하가 있었으며, DOC 고혈압의 정도는 (실험 2)에서 약간 낮았다.

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Fate and Characteristics of Dissolved Organic Matters in a Water Reclamation Facility, Korea (하수처리수 재이용시설의 공정별 용존유기물질 거동 및 특성)

  • Kwon, Eun-Kwang;Lee, Wontae
    • Journal of Korean Society on Water Environment
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    • v.37 no.5
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    • pp.355-362
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    • 2021
  • This study investigated the fate of dissolved organic matter (DOM) in a water reclamation facility (WRF) in Korea. The WRF consists of coagulation, sedimentation, microfiltration, and reverse osmosis (RO) components. The production capacity of WRF is 90,000 m3/day. The reclaimed water is reused as industrial water. We also characterized DOM in raw, processed, and finished waters based on analysis of dissolved organic carbon (DOC), ultraviolet absorbance at 254 nm (UVA254), fluorescence excitation emission matrix (FEEM), and DOC fractions via liquid chromatography-organic carbon detection (LC-OCD). Based on the results of DOC, UVA254, and FEEM analyses, neither the coagulation/sedimentation nor the microfiltration at the WRF effectively removed DOM. The RO process removed more than 94% of DOM. The raw water (i.e., secondary treated effluent obtained from a wastewater treatment plant) exhibited tryptophan-like peaks, which are a promising marker of wastewater, in the FEEM analysis. Coagulation and microfiltration failed to eliminate the wastewater marker, whereas RO completely removed it. The raw water also carried high levels (89.4%) of hydrophilic and low-molecular weight substances, which are difficult to remove via coagulation-sedimentation or microfiltration. Humic substance was a major component of the hydrophilic fractions. Based on the LC-OCD analysis, RO effectively removed the humic and polymeric materials from DOM.

Treatment Performance and Microbial Community Structure in BAC-process Treating Contaminated Groundwater by Water-soluble Cutting Oil (생물활성탄을 이용한 절삭유로 오염된 지하수의 처리특성과 미생물군집구조 해석)

  • Lim Byung-Ran;Bae Ci Ae;Lim Ho-Ju;Cho Chang-Ho
    • Journal of Environmental Health Sciences
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    • v.32 no.1 s.88
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    • pp.71-76
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    • 2006
  • Treatment performance and microbial community structure were investigated in water-soluble cutting oil treatment process using biological activated carbon. DOC removal in BACI column at $15^{\circ}C$ was higher than at $25^{\circ}C$, but those of BAC3 column after 60days was high at$25^{\circ}C$. Also, quinone content of first-step reactors at $25^{\circ}C$ and $15^{\circ}C$ was much the same, but those of the third-step reactor at $25^{\circ}C$ was higher than at $15^{\circ}C$. The dominant type of two apparatus was ubquinone (UQ)-l 0 followed by UQ-8. Menaquinones were detected from $25^{\circ}C$ apparatus and effluent. This suggested that DOC removal at $25^{\circ}C$ was advanced degradation by attached microorganisms on the activated carbon surface. The DOC removal in long-term activated carbon apparatus increased with going in BAC3 column. This indicated the influent of POC was a result of DOC removal efficiency decrease. Integrated DOC removal from start point in experiment to break point and quinone content were showed a tendency of increasing with going last-step activated carbon apparatus. Therefore, the biological activated carbon apparatus used by this study was effective treatment process in contaminated groundwater by water-soluble cutting oil.

Self Introduction Essay Classification Using Doc2Vec for Efficient Job Matching (Doc2Vec 모형에 기반한 자기소개서 분류 모형 구축 및 실험)

  • Kim, Young Soo;Moon, Hyun Sil;Kim, Jae Kyeong
    • Journal of Information Technology Services
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    • v.19 no.1
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    • pp.103-112
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    • 2020
  • Job seekers are making various efforts to find a good company and companies attempt to recruit good people. Job search activities through self-introduction essay are nowadays one of the most active processes. Companies spend time and cost to reviewing all of the numerous self-introduction essays of job seekers. Job seekers are also worried about the possibility of acceptance of their self-introduction essays by companies. This research builds a classification model and conducted an experiments to classify self-introduction essays into pass or fail using deep learning and decision tree techniques. Real world data were classified using stratified sampling to alleviate the data imbalance problem between passed self-introduction essays and failed essays. Documents were embedded using Doc2Vec method developed from existing Word2Vec, and they were classified using logistic regression analysis. The decision tree model was chosen as a benchmark model, and K-fold cross-validation was conducted for the performance evaluation. As a result of several experiments, the area under curve (AUC) value of PV-DM results better than that of other models of Doc2Vec, i.e., PV-DBOW and Concatenate. Furthmore PV-DM classifies passed essays as well as failed essays, while PV_DBOW can not classify passed essays even though it classifies well failed essays. In addition, the classification performance of the logistic regression model embedded using the PV-DM model is better than the decision tree-based classification model. The implication of the experimental results is that company can reduce the cost of recruiting good d job seekers. In addition, our suggested model can help job candidates for pre-evaluating their self-introduction essays.

Application of Practical Immobilizing Agents for Declining Heavy Metal (loid)s Accumulation by Agricultural Crop (Allium wakegi Araki)

  • Seo, Byoung-Hwan;Kim, Hyun-Uk;Lwin, Chaw Su;Kim, Hyuck Soo;Kim, Kwon-Rae
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.4
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    • pp.226-234
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    • 2017
  • In order to reduce the accumulation of toxic metals (As, Cd and Pb) in the chives, various immobilizing agents such as a soil pH change-inducing immobilizing agent (lime), sorption agent (compost, spent mushroom compost), soil pH change and sorption agent (biochar) and, dissolved organic carbon (DOC) coagulator (gypsum) and uncontaminated soil were applied to the contaminated soils in isolation and in combination. Then chives were grown and determined for As, Cd and Pb concentrations accumulated in the edible part at harvest. The Cd and Pb concentrations of the chive plant grown in the contaminated soil (no treatment) exceeded the legislated Korean guideline values (Cd: $0.05mg\;kg^{-1}$, Pb $0.1mg\;kg^{-1}$) and As concentration ($21mg\;kg^{-1}$) was 1,000 times higher than chives plant grown in uncontaminated environment in Korea. Application of lime and gypsum significantly reduced As, Cd and Pb concentrations in all chives examined, due to the increased soil pH and decreased soil DOC. Also, application of combination treatments involving DOC coagulator such as gypsum together with lime decreased As, Cd and Pb concentrations from 21, 1.3 and $9.7mg\;kg^{-1}$ to 2.1, 0.1 and $1.1mg\;kg^{-1}$, respectively. Consequently, it was concluded that pH change-inducing immobilizing agent (lime) which was already well known and DOC coagulator such as gypsum could be used as a promising immobilizing agent for safer chives plant production.