• 한국대기환경학회지
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• 제15권4호
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• pp.457-461
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• 1999

Recently, increasing usage of diesel vehicle, many countries try to reduce the pollutant materials by emission regulation standard. Particularly, in our country, the supplement ratio of diesel vehicle is high, and air pollution by particulate matter(PM) is very serious. So, in theoretical study wer analyzed the formation principle of gaseous emission and PM, the characteristics of CVS-75 mode. In experimental study, we tested exhaust gas reduction of emission and PM, the characteristics of CVS-75 mode. In experimental study, we tested exhaust gas reduction of disel oxidation catalyst(DOC) by CVS-75 mode in light duty diesel vehicle. In case of an automobiletest with the 2,956cc diesel engine which DOC was equipped, CVS-75 mode which is similar to driving conditions on the road was chosen as the restrictive mode of light duty diesel automobile in our country. According to the Pt, the reduction rate of exhaust emission was estimated with using 0.1% high sulfur fuel and 0.05% low sulfur fuel.

• 한국대기환경학회지
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• 제14권3호
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• pp.261-266
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• 1998

Recently, air pollution is increased according to increase of vehicle. So many countries are studying about DOC for diesel emission decrease. However, there are many difficulty in applying to DOC . In this study, SOx exhaust gas equipped with DOC was studied and we obtained several test results as following. First, in diesel oxidation catalyst, additives such as Pt is very effective for 503 and sulfate. Second, the oxidative activity for 502 has decreased to add such as Pt and the decrease of 502 is effect for the reduction of PM in high temperature . And finally, in high temperature, concentration of SOx is increased and temperature is affected by process from SOB to 503, whereas engine performance and fuel consumption are not affected by equipped DOC.

• 청정기술
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• 제16권4호
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• pp.265-271
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• 2010

경유차 매연저감장치에서 비활성화된 디젤산화촉매(DOC)를 대상으로 여러 가지 조건에서 재제조한 후, 재제조된 DOC의 일산화탄소(CO)와 탄화수소화합물(THC)의 저감효율과 촉매물성 특성을 분석하여 비활성화된 DOC 촉매에 대한 재제조 효과를 관찰하였다. 재제조된 DOC촉매에 대한 오염물질 저감성능 평가는 디젤엔진 다이나모 장치를 이용, 배기가스를 일부 우회시켜 온도와 공간속도조절이 가능한 촉매반응장치로 수행하였으며, 촉매물성 분석은 광학현미경, EDX, ICP, TGA 그리고 porosimeter를 이용하였다. 연구수행 결과 비활성화된 DOC 촉매를 본 연구에서 적용된 고온배소세정, 산성/염기성용액에 의한 초음파세정, 세정 후 촉매활성성분 재함침에 의한 재제조를 수행할 경우, 재제조된 DOC 촉매의 성능이 신품 성능의 90% 이상으로 회복되는 것을 확인하였으며, 광학현미경, EDX, TGA와 ICP등의 분석을 통해 본 연구조건에서의 재제조 과정으로, 촉매의 활성 저하 원인이 되었던 각종 불순 성분 대부분이 비활성화된 DOC 촉매로부터 제거되는 것을 확인하였다.

• International Journal of Automotive Technology
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• 제7권5호
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• pp.527-534
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• 2006

Modern passenger cars with diesel engines are equipped with DOC(diesel oxidation catalyst) for the purpose of reducing HC and CO in the exhaust stream. Cold start exhaust emissions pose troubles here as on gasoline engine vehicles. As a result, some of the diesel passenger cars roll off todays the assembly lines with WCC(warm-up catalytic converter). Oxidation characteristics of the particulates in WCC is analyzed in this study by EEPS(engine exhaust particulate size spectrometer). The maximum number of PM is found to come out of WCC in sizes near 10nm when an HSDI diesel engine is operated under the conditions of high speed and medium to heavy load. When the temperature of the WCC exceeds $300^{\circ}C$, the number of PM smaller than 30 nm in diameter sharply increases upon passing through the WCC. Total mass of emitted PM gets reduced downstream of the WCC under low speed and light load conditions due to adsorption of PM onto the catalyst. Under conditions of high speed and medium to heavy load, the relatively large PM shrink or break into fine particles during oxidation process within the WCC, which results in more mass fraction of fine particles downstream of the WCC.

• 한국자동차공학회논문집
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• 제7권7호
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• pp.15-23
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• 1999

In recent years, environmental damage to urban area becomes serious problem due to the exhaust emissions by increasing the number of vehicle . Especially, diesel particulate matters(DPM) are hazardous air pollutant s to human health and environment. The reduction technologies of exhaust emissions from diesel engines are improvement of engine combustion, fuel quality and development of diesel exhaust aftertreatment. In this study, a diesel oxidation catalyst(DOC) that is one of diesel exhaust aftertreatments was made for performance evaluation . It was tested for NA and turbocharged engine by D-13 mode that currently be used for regulation driving test mode in Korea Scanning mobility particle sizer (SMPS) was used for the analysis of the particle size distribution with and w/o DOC. As the results , for NA and tubochartged engine, CO, THC, DPM was respectively reduced 85.7, 40.7,3.3% and 79.1, 53.1, 11.6% by DOC. Test results of particle size distribution was showed that particle number is 107 ~108per ㎤ , 2 $\times$105 ~5$\times$105$\mu\textrm{g}$/㎥ for weight concentration and 100~200nm for particle mean size in diesel engine and there is no effect to reduce the particle concentration by the DOC.

• 한국자동차공학회논문집
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• 제7권8호
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• pp.34-42
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• 1999

In late 1997, the portion of registered light-duty diesel vehicle was 25.3% and its emission rate was 17.1% in Korea. Especially, diesel particulate matters(DPM) and NOx are hazardous air pollutants to human health and environment in urban area. The reduction technologies of exhaust emissions from diesel engines are improvement of engine combustion, fuel quality and development of diesel exhaust after treatment , In this study , a light-duty diesel oxidation catalyst(DOC) that is one of the diesel exhaust after treatment was made for performance evaluation and the emission characteristics were tested on CVS-75 mode. And the analysis of the particle size distribution with scanning mobility particle 100, 67.6% and 66.7, 10.0% for Pt and Pt-V catalyst .And for Pt catalyst, the PM increased 7.8% because of increasing sulfate but Pt-V catalyst reduced the PM to 23.0% . Test results of particle size distribution showed that peak values of number and mass densities are respectively 100∼200nm their distribution trend independent of vehicle speed.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2012년도 제45회 KOSCO SYMPOSIUM 초록집
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• pp.37-38
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• 2012

Two catalyst systems with different content of precious metal coated on DOC are carefully tested in a diesel engine to investigate the emission characteristics of $NO_2$. Three types of experiment methods ($NO_2$ conversion test, ETC mode test, and BPT test) are applied to compare the performance of the two catalyst systems. All the experimental results consistently indicate that it is possible to satisfy $NO_x$ regulation by properly lowering the content of precious metal without the loss of PM removal performance.

• 동력기계공학회지
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• 제5권2호
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• pp.13-21
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• 2001

Diesel emission control is being addressed worldwide to help preserve the global environment. This paper mainly deals with the effects of oxidation catalysts to reduce emissions from the automotive heavy-duty diesel engine. Two types of the oxidation catalyst with different kinds of precious material were used. An 11 litter displacement diesel engine with turbocharger was operated to evaluate DOC with various engine speed, load conditions under D-13 mode cycle. We could propose the detail emission data of an automotive heavy-duty diesel engine and the characteristics of the conversion efficiency of the DOC under the D-13 mode. It was found that the mean conversion efficiencies of CO and THC were 49.7% and 61% under the D-13 mode test, respectively.

• 한국대기환경학회지
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• 제16권5호
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• pp.529-537
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• 2000

Several Pt-based oxidation catalysts with different loading were prepared with various metal precursor solutions and characterized with H$_2$ chemisorption and TEM for Pt particle size. V was added to Pt-based catalyst for inhibiting SO$_2$oxidation reaction, as result, Pt-V/Ti-Si catalyst prepared by ERMS(Free Reduced Metal in Solution) method showed high enough activity and better inhibition on SO$_2$oxidation than Pt only catalyst. Optimum Pt particle size for diesel oxidation reaction turned out to be the size of around 20 nm. A prototype catalyst was prepared for light=duty diesel passenger car, and teated for the emission reduction performance with Korean regulation test mode(CVS-75 mode) on chassis dynamometer. The catalyst shows the performance reduction of 75~94% for CO, 53~67% for HC and 10~31% for PM. In the case of heavy-duty diesel catalyst, the domestic formal regulation teat mode D-13 was adopted for both Na engine and Turbo engine. The conversions of CO and THC are high enough(86% and 41%) while the reductions of NOx and PM are relatively low(3~11%).

• Journal of Mechanical Science and Technology
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• 제20권1호
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• pp.1-12
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• 2006

This work reviews the effects of catalyst formulation and exhaust gas composition on soot oxidation in CDPF (Catalytic Diesel Particulate Filter). DOC's (Diesel Oxidation Catalysts) have been loaded with Pt catalyst (Pt/$Al_{2}O_3$) for reduction of HC and CO. Recent CDPF's are coated with the Pt catalyst as well as additives like Mo, V, Ce, Co, Fe, La, Au, or Zr for the promotion of soot oxidation. Alkali (K, Na, Cs, Li) doping of metal catalyst tends to increase the activity of the catalysts in soot combustion. Effects of coexistence components are very important in the catalytic reaction of the soot. The soot oxidation rate of a few catalysts are improved by water vapor and NOx in the ambient. There are only a few reports available on the mechanism of the PM (particulate matter) oxidation on the catalysts. The mechanism of PM oxidation in the catalytic systems that meet new emission regulations of diesel engines has yet to be investigated. Future research will focus on catalysts that can not only oxidize PM at low temperature, but also reduce NOx, continuously self-cleaning diesel particulate filters, and selective catalysts for NOx reduction.