• Journal of Hydrogen and New Energy
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• v.15 no.4
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• pp.301-308
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• 2004

The methane reforming with $CO_2$ and steam for manufacture of synthesis gas over $Ni/ZrO_2$ catalyst was investigated. Mixed reforming carried out $CO_2$ dry reforming with $O_2$ and steam for development of DME process in pilot plant. To improve a catalyst deactivation by coke formation, the mixed reforming added carbon dioxide and steam as a oxidizer of the methane reforming was suggested. The result of experiments over commercial catalyst in $CO_2$ dry reforming has shown that the catalyst activity decrease rapidly after 20 hours. In case of $NiO-MgO/Al_2O_3$ catalyst, the deactivation of 20 percent after 30 hours was occurred. The activity of Ni/C catalyst still was not decreased dramatically after 100 hours. The effect of $H_2$ reforming with steam over $Ni/CO_2$ catalyst obtained the optimal conversion of methane and carbon dioxide, and could be produced synthesis gas at ratio of $H_2/CO$ under 1.5.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.12
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• pp.1043-1050
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• 2010

Fuel stratification and thermal stratification occur in the HCCI combustion chamber on a microscopic scale. They affect the ignition and combustion processes. In this study, the effect of the inhomogeneity in the mixture gas on the HCCI combustion process was investigated. Two-dimensional chemiluminescence images were captured using a framing camera to evaluate the flame structure. DME was used as the test fuel. First, the effect of inhomogeneity in the fuel distribution in the premixture was investigated for the four-stroke optically accessible engine. Then, by comparing the combustion of the homogeneous mixture in the rapid compression machine, which does not contain any residual gas, with the combustion in the four-stroke engine, the effect of inhomogeneity in temperature due to the residual gas was analyzed. The results showed that a time lag appears spatially in combustion under inhomogeneous conditions in the four-stroke engine. The spatial variation in the combustion without the residual gas in the rapid compression machine is less than that in the combustion in the four-stroke engine.

• Journal of Hydrogen and New Energy
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• v.26 no.5
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• pp.477-483
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• 2015

LFG (Land-Fill Gas) includes components of $CH_4$, $CO_2$, $O_2$, $N_2$, and water. The preparation of synthesis gas from LFG as a DME (Dimethyl Ether) feedstock was studied by methane reforming of $CO_2$, $O_2$ and steam over $NiO-MgO-CeO_2/Al_2O_3$ catalyst. Our experiments were performed to investigate the effects of methane conversion and syngas yield on the amount of LFG components over $NiO-MgO-CeO_2/Al_2O_3$ catalyst. Results were obtained through the methan reforming experiments at the temperature of $900^{\circ}C$ and GHSV of 8,800. The results were as following; it has generally shown that syngas yield increase with the increase of oxygen and steam amounts and then decrease. Highly methane conversion of above 98% and syngas yield of approximately 60% were obtained in the feed of gas composition flow-rate of 243ml/min of $CH_4$, 241ml/min of $CO_2$, 195ml/min of $O_2$, 48ml/min of $N_2$, and 450ml/min of steam, respectively, under reactor pressure of 1 bar for 200 hrs of reaction time. Also, it was shown that catalyst deactivation by coke formation was reduced by excessively adding oxygen and steam as an oxidizer of the methane reforming.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.40 no.1
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• pp.32-42
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• 2015

In this paper, we considered the scenario that one cellular link and muti-D2D links share the same frequency resource which can improve the spectrum efficiency during uplink communication in LTE (Long Term Evolution)-Advanced network. In order to reduce the interference caused to the D2D users, we set DME (Discovery and Management Entity) which can send the area information to eNB(evolved Node B). We proposed a resource allocation scheme by using these assistant devices to reduce the interference that CUE (Cellular User Equipment) causes to DUE Rx (D2D UE Receiver). Basing on the area information, in order to mitigate the interference among the D2D pairs which share the same frequency resource, a power control scheme has been proposed. The simulation results prove that by using the DMEs, the proposed schemes improve the stability of D2D communication and bring the highest performance of the communication system when comparing to the other different schemes.

• Applied Chemistry for Engineering
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• v.9 no.5
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• pp.749-753
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• 1998

Methoxy polyoxyethylene dodecanoates, kinds of nonionic surfactants, could be obtained from addition of ethylene oxide (5, 7, 9, and 12mol) with fatty acid methyl ester utilizing solid catalyst, metal oxide. Because ethylene oxide (EO) couldn't react directly in acid or alkali catalyst with dodecanoic acid methyl ester (DME) that had no active hydrogen, the reaction to add EO was carried out using active solid catalyst. By using IR, HPLC and $^1H$ NMR analysis, structural confirmation of methyl polyoxy ethylene dodecanate showed high yield ranging from 93 to 97%. EO unit mol number of reacted products was 5.2, 7.1, 9.2 and 12.1 mol respectively. Also, EO adduct distrobution of ethoxylated methyl laurate (MPD) had normal distribution curve like polyoxyethylene alkyl ether (AE).

• Korean Chemical Engineering Research
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• v.50 no.4
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• pp.684-689
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• 2012

Poly(acrylic acid) (PAA) microspheres is one of the widely-used polymeric materials for the bio-field application and the electric materials. For the synthesis of PAA microspheres, the polymerization technique using surfactants is applied. After the synthesis, the purification and separation processes are required for the removal of surfactant. When general organic solvents were used, many problems, such as huge amount of waste solvent, additional separation processes, and the possibility of residual media, were occurred. Thus, High-pressure Soxhlet extraction using liquid $CO_2$ was developed to solve these problems. In this study, High-pressure Soxhlet extraction of the synthesized PAA microspheres using liquid $CO_2$ was conducted for the removal of Monasil PCA which is used for the dispersion polymerization of acrylic acid in compressed liquid Dimethyl ether (DME). The morphology of the extracted PAA particles was checked by field emission scanning electron microscopy (FE-SEM) and the residual concentration of Monasil PCA was analyzed by inductively coupled plasma - Optical Emission Spectrometer (ICP-OES). For studying the effect of the solvent effect, Soxhlet extraction was conducted using n-hexane, liquid DME, and liquid $CO_2$. In case of n-hexane, some extracted PAA microspheres were produced. However, deformation was also occurred due to the high thermal energy of n-hexane vapor. Liquid DME could not remove Monasil PCA. When using liquid $CO_2$, the extracted PAA microspheres which were free for the residual solvent were produced without deformation. For finding the optimum operating condition, high-pressure Soxhlet extraction was conducted for 8 hours with changing the temperature of reboiler and condenser. When the extractor temperature is $19.6{\pm}0.2^{\circ}C$ and the pressure is $51.5{\pm}0.5$ bar, the best removal efficiency was obtained.

• 한국가스학회:학술대회논문집
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• 2005.10a
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• pp.131-134
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• 2005

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2009.06a
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• pp.589-590
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• 2009

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.2962-2962
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• 2008

• LP가스
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• s.104
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• pp.4-5
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• 2006

2006.7.14일(금) 협회 회의실에서는 재적이사 38명중 17명(위임21명)이 참석한가운데 "제52차 이사회 및 36차 공제운영위원회"가 개최되었다. 이날 이사회에 앞서 한국가스공사 백영순박사의 DME현황설명도 있었다. 관련내용을 게재한다.