• Title/Summary/Keyword: DI water

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Solubility Study of Graphene-oxide with Various Solvents (산화그래핀(Graphene oxide)의 솔벤트(solvent)별 Solubility에 대한 연구)

  • Jung, Su-Yeon;Choi, Sung-Woong
    • Composites Research
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    • v.35 no.1
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    • pp.18-22
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    • 2022
  • Dispersion is one of the most important factors in the manufacture of composite materials. In the manufacture of composite materials, solvents are used to better disperse the reinforcement, nano-filler in the matrix. Since dispersion is affected with solvents, it is necessary to study which solvent is adopted to get good dispersion. In this study, the dispersion behavior and solubility of graphene oxide(GO) were examined under various solvents (DMF, NMP, ethylene glycol, Acetone, DI water) to identify dispersion. As a result of UV-Vis spectroscopy absorbance measurement, it was found that DMF and ethylene glycol had the best dispersibility, whereas DI water showed the lowest dispersibility. In addition, as a result of visually observing the dispersion according to the surface tension and time, it was found that the dispersibility was excellent in the order of DI water, ethylene glycol, NMP, DMF, and acetone, which was consistent with the Hansen solubility parameter value.

Water Lubrication Characteristics and Effect of Nano Particles based on the Substrate (기판 종류에 따른 물 윤활 특성 및 나노 입자의 영향)

  • Kim, Hye-Gyun;Kim, Tae-Hyung;Kim, Jongkuk;Jang, Young-Jun;Kang, Yong-Jin;Kim, Dae-Eun
    • Tribology and Lubricants
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    • v.33 no.6
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    • pp.245-250
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    • 2017
  • In this work, we examine pure water and water with nanoparticles to investigate water lubrication characteristics and the effect of nanoparticles as lubricant additives for different substrates. We test carbon-based coatings and metals such as high-speed steel and stainless steel in pure deionized (DI) water and DI water with nanoparticles. We investigate water lubrication characteristics and the effect of nanoparticles based on the friction coefficient and wear rate for different substrates. The investigation reveals that nanoparticles enhance the friction and wear properties of high-speed steel and stainless steel. The friction coefficient and wear rate of both high-speed steel and stainless steel decreases in DI water with nanoparticles compared with the results in pure DI water. The presence of nanoparticles in water show good lubricating effect at the contact area for both high-speed steel and stainless steel. However, for carbon-based coatings, nanoparticles do not improve friction and wear properties. Rather, the friction coefficient and wear rate increases with an increase in the concentration of nanoparticles in case of water lubrication. Because carbon-based coatings already have good tribological properties in a water environment, nanoparticles in water do not contribute toward improving the friction and wear properties of carbon-based coatings.

Fabrication of Nickel Oxide Thin Film for Lithium Based Electrolyte by Sol-Gel Method and Electrochromic Properties in Lithium Based Electrolyte (Sol-Gel법을 통한 리튬 기반 전해질에 적합한 니켈 산화물 박막의 제조와 리튬 기반 전해질에서의 전기변색 특성)

  • Park, Sun-Ha;Yoo, Sung-Jong;Lim, Ju-Wan;Yun, Sung-Uk;Cha, In-Young;Sung, Yung-Eun
    • Journal of the Korean Electrochemical Society
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    • v.12 no.3
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    • pp.251-257
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    • 2009
  • In this study, we fabricated nickel oxide thin film for lithium based electrolyte using sol-gel method. This film was deposited by dip-coating method with mixed solvent of DameH (N,N-dimethylaminoethanol) and DI water. As changing the ratio between DmaeH and DI water, nickel oxide thin film was presented in different charge density and optical transmittance because they were shown various thickness. It was accounted for changing viscosity and density by the ratio of DmaeH and DI water. The thin film synthesized with 1 : 1 ratio of DmaeH and DI water was expressed best electrochromic performance in lithium based electrolyte, because of thick thickness but porous structures.

Reciprocating Wear Test of AISI 52100 Bearing Steel in h-BN-based Aqueous Lubricants

  • Gowtham Balasubramaniam;Dae-Hyun Cho
    • Tribology and Lubricants
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    • v.39 no.6
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    • pp.228-234
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    • 2023
  • In this study, reciprocating wear tests are performed on AISI 52100 bearing steel to investigate its tribological behavior in a hexagonal boron nitride (h-BN) water solution. The h-BN-based aqueous lubricant is prepared using an atoxic procedure called ultrasonic sonication in pure water. Ball-on-flat reciprocating sliding experiments are conducted, where the ball is slewed on a fixed flat at 50-㎛ displacement. The lubricating behavior of h-BN is compared with that of deionized (DI) water. Results show that the friction coefficient is higher in h-BN testing than that in DI tests, but the results are equalized as the friction coefficient reaches a stable level. Scanning electron microscopic images reveal significant material loss in the center and mild abrasion on the edge of the wear scar in h-BN tests. However, these effects are minor in DI water situations. The results of energy-dispersive X-ray spectroscopy show that considerable oxidation occurs in the central zone of the wear scar in h-BN cases with strong adhesion and material removal. These findings reveal the importance of determining ideal circumstances that can tolerate material friction and wear.

Sensitive determination of pendimethalin and dinoseb in environmental water by ultra performance liquid chromatography-tandem mass spectrometry

  • Lim, Hyun-Hee;Park, Tae-Jin;Lee, Soo-Hyung;Shin, Ho-Sang
    • Analytical Science and Technology
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    • v.30 no.4
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    • pp.194-204
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    • 2017
  • Direct injection (DI) and solid phase extraction (SPE) methods for the simultaneous determination of pendimethalin (PDM) and dinoseb (DNS) in environmental water have been optimized using the ultra performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS) method. The limits of quantification (LOQs) of PDM and DNS were $0.01{\mu}g/L$ using the DI method and $0.0001-0.0002{\mu}g/L$ using the SPE method. The precision by SPE UPLC-MS/MS was less than 11 % for intra-day and inter-day analyses. When the proposed SPE method was used to analyze two analytes in environmental water, PDM was detected in a concentration range of $0.0002-0.011{\mu}g/L$ in 31 samples of the 114 surface water samples, and DNS was detected in a concentration range of $0.0005-0.045{\mu}g/L$ in 17 samples of the 114 surface water samples analyzed. When the DI method was used to analyze target compounds in the same samples, the detected concentrations of the two analytes were within 21% in samples with concentrations above $0.01{\mu}g/L$. The DI UPLC-MS/MS method can thus be used for the routine monitoring of PDM and DNS in environmental water, and the SPE LC-MS/MS method can be used for the determination of the ultra-trace PDM and DNS residues in environmental water.

A Study on the Characteristics of the High Concentration Ozone Generator for the Semiconductor Wafer Cleaning with the Ozone Dissolved De-ionized Water (반도체 웨이퍼의 오존 수(水) 세정을 위한 고농도 오존발생장치 특성 연구)

  • 손영수;함상용;문세호
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.12
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    • pp.579-585
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    • 2003
  • Recently the utilization of the ozone dissolved de-ionized water(DI-O3 water) in semiconductor wet cleaning process to replace the conventional RCA methods has been studied. In this paper, we propose the water-electrode type ozone generator which has the ozone gas characteristics of the high concentration and high purity to produce the high concentration DI-O3 water for the silicon wafer surface cleaning process. The ozone generator has the dual dielectric tube structure of silent discharge type and the water is both used to electrode and cooling water. We investigate the performance of the proposed ozone generator which has the design goal of the concentration of 7[wt%] and ozone generation quantity of 6[g/hr] at flow rate of 1[$\ell$/min). The experiment results show that the water electrode type ozone generator has the characteristics of 8.48[wt%] of concentration, 8.08[g/hr] of generation quantity and 76.2[g/kWh] of yield and it's possible to use the proposed ozone generator for the DI-O3 water cleaning process of silicon wafer surface.

Decomposition of Microcystis sp. Cell and Formation of Chlorination Disinfection By-Products (Microcystis sp. Cell의 부패와 염소 소독부산물 생성)

  • Son, Hee-Jong;Yeom, Hoon-Sik;Jung, Jong-Mun;Choi, Jin-Taek
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.5
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    • pp.351-358
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    • 2012
  • Formation of disinfection by-products (DBPs) including trihalomethans (THM), haloacetic acid (HAA) and haloacetonitriles (HAN) from chlorination of extracellular organic matter (EOM) and cells + intracellular organic matter (IOM) of Microcystis sp., a blue-green algae, during decomposed period was investigated. Microcystis sp. cells + IOM and EOM of Microcystis sp. exhibited a high potential for DBP formation. HAAFP (formation potential) was higher than THMFP during decomposed period. In the variations of HAAFP species during decomposed period, the ratio of di-HAAFP species was gradually decreased and the ratio of tri-HAAFP species was gradually increased in the case of EOM during decomposed period, while the opposite result was in the case of cells + IOM during decomposed period. In the variations of HANFP species during decomposed period, the ratio of di-HANFP species was much higher than the ratio of tri-HAAFP species.

Preparation of $ZrO_2$ Coated Graphite Powders in Aqueous and Nonaqueous Solution (수계-비수계 용매를 이용한 흑연분말의 $ZrO_2$ 수열코팅)

  • 김정환;이태근;이기강;이석근
    • Korean Journal of Crystallography
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    • v.14 no.2
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    • pp.67-72
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    • 2003
  • Graphite powders were coated with ZrO₂ by the controlled hydrolysis of a DI water, ethanol and DI water+ethanol solutions. The hydrolysis process was carried out with temperature control because of the low wettability of Zr ions to the surface of the graphite. PVA was added to the solution for the enhancement of metal ion adsorption. The surface of the graphite powders coated with ZrO₂ was observed by SEM and TEM. There are two types of ZrO₂ particles with the condition of ZrOCl₂°§8H₂O aqueous solutions were used; (a) primary particles a few nm in size and (b) secondary particles with ∼0.1 ㎛ size were obtained. The graphite powders coated in 50% ethanol-50% DI water solution of Zr(SO₄)₂ㆍ4H₂O have the relatively uniform coating layer and the starting temperature of oxidation was 100℃ higher than the raw graphite.

Two-fluid modelling for poly-disperse bubbly flows in vertical pipes: Analysis of the impact of geometrical parameters and heat transfer

  • Andrea Allio ;Antonio Buffo ;Daniele Marchisio;Laura Savoldi
    • Nuclear Engineering and Technology
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    • v.55 no.3
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    • pp.1152-1166
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    • 2023
  • The bubbly flow of air or steam in subcooled water are investigated here in several test cases, characterized by different pipe sizes, bubble dimensions and flow rates, by means of CFD using a Eulerian-Eulerian approach. The performance of models that differ for the turbulence closure in the continuous phase, as well as for the description of the lift force on the dispersed phase, are compared in detail. When air is considered, the space of the experimental parameters leading to a reasonable performance for the selected models are identified and discussed, while the issues left in the modelling of the concurrent condensation are highlighted for the cases where steam is used.

Development of New Soft Contact Lens Materials Using Ester-Monomers of Itaconic Acid from Aspergillus itaconicus (Aspergillus itaconicus 유래 itaconic acid의 ester-monomer를 이용한 새로운 soft contact lens 소재 개발)

  • You, Young-Hyun;Nam, Joo-Hyeung;Kim, Bieong-Kil;Kim, Soon-Bok;Moon, Ik-Jae;Kim, Jong-Pil;Seu, Young-Bae
    • Journal of Life Science
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    • v.19 no.4
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    • pp.538-542
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    • 2009
  • In this study, we confirmed water content and oxygen permeability of new polymeric materials synthesized from itaconic acid used for soft contact lenses. In this study, we polymerized materials for soft contact lenses using HEMA (2-hydroxyethyl methacrylate), the based-monomer of soft contact lenses, EGDMA (ethylene glycol dimethacrylate) as a cross linkage agent, and the new additives mono-ester or di-ester derived from itaconic acid commercially produced by the fermentation of A. itaconicus. New polymer materials for contact lenses were synthesized with the mixture of HEMA and mono- or di-ester at different ratios and water content and oxygen permeability (Dk) was analyzed. In polymerizing HEMA and mono-ester (15%), the water content and oxygen permeability of contact lenses were found to be of good value at 57.7% and 28.6 Dk respectively. The mixture of HEMA and mono-ester is more excellent than HEMA/di-ester in regards to water content and oxygen permeability. The water content and oxygen permeability of soft contact lenses made by new polymeric materials were highly represented.