• 폴리머
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• 제27권4호
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• pp.323-329
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• 2003

기능성 도핑제인 di(2-ethylhexyl) sulffsuccinate sodium salt (NaDEHS)을 사용하여 화학적, 전기화학적 방법에 의한 연신성 폴리피롤을 합성하였다. 화학적, 전기화학적 방법에 의해 제조된 폴리피를 필름은 구역 연신 방법을 사용하여 1.0∼2.5배 연신시킬 수 있었으며, 연신된 폴리피를 필름의 전기 전도도를 측정하였다. 연신율이 증가함에 따라 필름의 전기 전도도는 증가함을 볼 수 있었다. 이러한 현상은 연신율에 따른 결정성 증가로 설명할 수 있었다. 온도변화에 따른 전하 이동 경로는 1.0-2.0배 연신된 폴리피롤의 경우 3차원 variable range hopping모델, 2.5배 연신된 폴리피롤의 경우 1차원 VHR모델에 적합함을 볼 수 있었다.

• 한국자동차공학회논문집
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• 제10권4호
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• pp.51-59
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• 2002

In this study, cycle simulation was performed to investigate the effect of EGR on combustion characteristics and emissions including NO and soot using a two-zone model in a DI diesel engine. The NO formation was well predicted for different EGR rate and temperature using a two-zone model. The oxygen in the inlet charge was replaced by CO$_2$ and H$_2$O with EGR. The reduction in the inlet charge oxygen resulted in very large reduction in NO level at the same inlet charge temperature. The effect of EGR was to reduce the burned gas temperature. When EGR was increased from 0% to 15%, the peak flame temperature was decreased by 50$\^{C}$ and it caused about 57% NO reduction. EGR caused increase of the overall inlet charge temperature which offset some of benefit of lower flame temperature resulting from O$_2$ displacement. Cooling the EGR was confirmed to provide additional benefits by lowering NO emission. It also reduced soot emission.

• Advances in environmental research
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• 제6권4호
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• pp.301-315
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• 2017

An Amberlite XAD-4 resin impregnated with di(2-ethylhexyl)phosphoric acid was prepared and its adsorption-desorption behaviors with Sr(II) ions under various conditions was examined. The resin was characterized by fourier transform infrared and thermal analysis techniques. The effects contact time, temperature, pH, interfering ions and eluants were studied. Results showed that adsorption of Sr (II) well fitted with pseudo-second-order kinetic model. The equilibrium adsorption data of Sr (II) on the impregnated resin were analyzed by Jossens, Weber-van Vliet, Redlich-Peterson and Fritz-Schlunder models to find out desirable equilibrium condition. Among them, the Fritz-Schlunder model best fitted to the experimental data. The maximum sorption capacity of impregnated resin amounted to 0.45 mg/ g at pH 8.0 and $20^{\circ}C$.

• 한국환경과학회지
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• 제24권3호
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• pp.267-274
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• 2015

The feasibility of PS-D2EHPA/TBP beads prepared by immobilizing two extractants D2EHPA and TBP in polysulfone to remove Sr(II) from aqueous solution was investigated in batch system. Batch experiments were carried out to study equilibrium isotherms, kinetics, and thermodynamics. Equilibrium data were fitted using Langmuir, Freundlich, Redlich-Peterson, and Dubinin-Radushkevich equation models at temperatures of 298 K, 313 K, and 328 K. The removal capacity of Sr(II) by PS-D2EHPA/TBP beads obtained from Langmuir model was 2.41 mg/g at 298 K. The experimental data were well represented by pseudo-second-order model. The removal process of Sr(II) by PS-D2EHPA/TBP beads prepared in this study was found to be feasible, endothermic, and spontaneous.

• International Journal of Aeronautical and Space Sciences
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• 제14권4호
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• pp.310-323
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• 2013

In this paper, the aeroelastic static response of flexible wings with arbitrary cross-section geometry via a coupled CUF-XFLR5 approach is presented. Refined structural one-dimensional (1D) models, with a variable order of expansion for the displacement field, are developed on the basis of the Carrera Unified Formulation (CUF), taking into account cross-sectional deformability. A three-dimensional (3D) Panel Method is employed for the aerodynamic analysis, providing more accuracy with respect to the Vortex Lattice Method (VLM). A straight wing with an airfoil cross-section is modeled as a clamped beam, by means of the finite element method (FEM). Numerical results present the variation of wing aerodynamic parameters, and the equilibrium aeroelastic response is evaluated in terms of displacements and in-plane cross-section deformation. Aeroelastic coupled analyses are based on an iterative procedure, as well as a linear coupling approach for different free stream velocities. A convergent trend of displacements and aerodynamic coefficients is achieved as the structural model accuracy increases. Comparisons with 3D finite element solutions prove that an accurate description of the in-plane cross-section deformation is provided by the proposed 1D CUF model, through a significant reduction in computational cost.

• Journal of the Korean Statistical Society
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• 제26권1호
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• pp.131-146
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• 1997

In this paper the problem of measuring the stochastic dependence among sets fo random variates is considered, and attention is specifically directed to forming a single well-defined measure of the dependence among sets of normal variates. A new information theoretic measure of the dependence called dependence index (DI) is introduced and its several properties are studied. The development of DI is based on the generalization and normalization of the mutual information introduced by Kullback(1968). For data analysis, minimum cross entropy estimator of DI is suggested, and its asymptotic distribution is obtained for testing the existence of the dependence. Monte Carlo simulations demonstrate the performance of the estimator, and show that is is useful not only for evaluation of the dependence, but also for independent model testing.

• Computers and Concrete
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• 제9권5호
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• pp.357-374
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• 2012

The aim of this paper is to develop a procedure able to calculate the long-term stress and strain patterns in modern prestressed composite structures which are largely influenced by creep and shrinkage and whose final static configuration is the result of many phases of loading and restraints conditions. The introduction of equivalent moduli, depending on the viscous and elastic features of materials, can guarantee a significant simplification of the problem presented above. The proposed calculation model has been used to design the "Quattroquercie Viaduct" located on the highway "A3" Salerno-Reggio Calabria, Italy.

• Wind and Structures
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• 제15권3호
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• pp.247-261
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• 2012

Some numerical investigations are presented concerning the response of a given plate under turbulence driven excitations. Three different input loads are simulated according to the wall pressure distributions derived from the models proposed by Corcos, Efimtsov and Chase, respectively. Modal solutions (finite element based) are used for building the modal stochastic responses in the sub-critical aerodynamic frequency range. The parametric investigations concern two different values of the structural damping and three values of the boundary layer thickness. A final comparison with available experimental data is also discussed. The results demonstrate that the selection of the adequate TBL input model is still the most critical step in order to get a good prediction.

• Advances in aircraft and spacecraft science
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• 제1권1호
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• pp.27-41
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• 2014

An active flow control technique based on "smart-tabs" is proposed to delay flow separation on a circular cylinder. The actuators are retractable and orientable multilayer piezoelectric tabs which protrude perpendicularly from the model surface. They are mounted along the spanwise direction with constant spacing. The effectiveness of the control was tested in pre-critical and in post-critical regime by evaluating the effects of several control parameters of the tabs like frequency, amplitude, height, angular position and plate incidence with respect to the local flow. Measurements of the mean static pressure distribution around the cylinder were used to estimate the pressure drag coefficient. The maximum drag reduction achieved in the pre-critical regime was of the order of 30%, whereas in the post-critical regime was about 10%, 3% of which due to active forcing. Furthermore, pressure fluctuation measurements were performed and spectral analysis indicated an almost complete suppression of the vortex shedding in active forcing conditions.

• Nuclear Engineering and Technology
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• 제43권6호
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• pp.477-488
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• 2011

A formulation is proposed for modelling the process of intra-granular diffusion of fission gas during irradiation of $UO_2$ under both normal operating conditions and power transients. The concept represents a simple extension of the formulation of Speight, including an estimation of the contribution of bubble motion to fission gas diffusion. The resulting equation is formally identical to the diffusion equation adopted in most models that are based on the formulation of Speight, therefore retaining the advantages in terms of simplicity of the mathematical-numerical treatment and allowing application in integral fuel performance codes. The development of the new model proposed here relies on results obtained by means of molecular dynamics simulations as well as finite element computations. The formulation is proposed for incorporation in the TRANSURANUS fuel performance code.