• Journal of the Korean Magnetic Resonance Society
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• v.27 no.4
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• pp.35-41
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• 2023

From a marine sponge Dysidea species, four new furanosesquiterterpenoids were isolated and characterized. Their structural elucidation was achieved through an extensive analysis employing NMR, MS data, and DFT method. Notably, all compounds shared as identical molecular formula. Compound 2 was identified as a derivative of compound 1, while compounds 3 and 4 exhibited an identical planar structure. Determination of the configurations of chiral centers in compounds 1 and 2 involved a comparative analysis between measured and calculated ECD spectra, along with the application of DP4+ probability analysis. Distinctly, the configurations of isomers 3 and 4 were established by scrutinizing proton chemical shifts based on the NOE correlation.

• Journal of the Korean Institute of Intelligent Systems
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• v.14 no.6
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• pp.759-763
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• 2004

In this paper, real-time voice change method using pitch change technique is proposed to change one's voice to the other voice. For this purpose, sampling rate change method using DFT (Discrete Fourier Transform) method and time scale modification method using SOLA (Synchronized Overlap and Add) method is combined to change pitch. In order to evaluate the performance of the proposed method, voice transformation experiments were conducted. Experimental results showed that original speech signal is changed to the other speech signal in which original speaker's identity is difficult to find. The system is implemented using TI TMS320C6711DSK board to verify the system runs in real time.

• Journal of the Institute of Electronics Engineers of Korea SP
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• v.41 no.3
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• pp.231-238
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• 2004

This paper presents the high speed noise reduction processing system using the modified discrete fourier transform(MDFT) on the frequency domain. The proposed filter uses the linear prediction coefficients of the adaptive line enhance(ALE) method based on the Sign algorithm The signals with a random noise tracking performance are examined through computer simulations. It is confirmed that the fast adaptive digital filter is realized by the high speed adaptive noise reduction(HANR) algorithm with rapid convergence on the frequency domain(FD).

• The Transactions of the Korean Institute of Electrical Engineers P
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• v.58 no.2
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• pp.136-141
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• 2009

An AC generator is an important components in producing a electric power and so it requires highly reliable protection relays to minimize the possibility of demage occurring under fault conditions. Conventionally, a DFT based RDR has been used for protecting the generator stator winding. However, when DFTs based on Fourier analysis are used, it has been pointed out that defects can occur during the process of transforming a time domain signal into a frequency domain one which can lead to loss of time domain information. This paper proposes the internal fault detection and fault type discrimination for the stator winding by applying the detailed coefficients by Daubechies Wavelet Transform to overcome the defects in the DFT process. For the case studies reported in the paper, a model system was established for the simulations utilizing the ATP, and this verified the effectiveness of the proposed technique through various off-line tests carried out on the collected data. The propose method is shown to be able to rapidly identify internal fault and did not operate a miss-operation for all the external fault tested.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.22 no.4
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• pp.462-469
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• 2011

In this paper, we propose a novel hybrid codebook design method which combines DFT matrix based codebook for Rayleigh fading and LOS codebook for direct path. Link-level performances employing hybrid codebook outperform the ones employing the conventional codebooks when K-factor of Rician distribution is 0.28 to 0.99. Moreover hybrid codebook shows good performances over not only Rayleigh channel but also high K's Rician channels.

• Bulletin of the Korean Chemical Society
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• v.30 no.5
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• pp.1061-1066
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• 2009

Two fluoro-substituted 2-pyrazoline derivatives, 1-phenyl-3-(4-methoxyphenyl)-5-(4-fluorophenyl)-2-pyrazoline (1) and 1-phenyl-3-(4-methoxyphenyl)-5-(2-fluoro-phenyl)-2-pyrazoline (2) have been synthesized and characterized by elemental analysis, IR, UV-Vis and fluorescence spectra. The crystal structure of 1 has been determined by X-ray single crystal diffraction. For the two compounds, density functional theory (DFT) calculations of the structures and natural population atomic charge analysis (NPA) have been performed at B3LYP/6-311G** level of theory. By using TD-DFT method, electron spectra of 1 and 2 have been predicted, which are very approximate with the experimental ones. Comparative studies on 1 and 2 indicate that the location change of fluorine atom in 5-position phenyl ring of 2-pyrazoline does not make significant change of geometries and electronic transition bands, but it leads to evident change of atomic charge distributions and peak intensities of UV and fluorescence spectra.

• Bulletin of the Korean Chemical Society
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• v.30 no.4
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• pp.837-845
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• 2009

We have performed DFT calculations to investigate the conformational characteristics and hydrogen bonds of the calix[6]arene (1) and p-tert-butylcalix[6]arene (2). The structures of various conformers of 1 were optimized by using the B3LYP/6-31G(d,p) and /6-31+G(d,p) methods followed by single point calculation of MPW1PW91/ 6-31G(d,p). The relative stability of the conformers of 1 is in the following order: cone (pinched: most stable) > partial-cone > cone (winged) $\sim$ 1,2-alternate $\sim$ 1,2,3-alternate > 1,4-alternate > 1,3-alternate > 1,3,5-alternate. The structures of different conformers of 2 were optimized by using the B3LYP/6-31G(d,p) method followed by single point calculation of MPW1PW91/6-31G(d,p). The relative stability of the conformers of 2 is in the following order: cone (pinched) > 1,2-alternate > cone (winged) > 1,4-alternate $\sim$ partial-cone > 1,2,3-alternate > 1,3,5alternate > 1,3-alternate. One of the important factors affecting the relative stabilities of the various conformers of the 1 and 2 is the number and strength of the intramolecular hydrogen bonds.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.8 no.2
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• pp.379-385
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• 2004

Medical images are being managed more by PACS in general medical institutions. It is important to protect patients from being invaded their privacy related to the images. It is also necessary to confirm the ownership, the right of property of the medical images and notice whether the data are modified. In this paper, we propose a robust watermarking against RST attacks in medical images on the PACS. The proposed scheme modifies and improves Log-Polar Mapping and Fourier Mellin Transform in order to realize and recover serious image degradation and watermark data loss caused by the conversion between cartesian coordinate and log-polar coordinate. We used the radius and theta Look Up Table to solve the realization of the Fourier Mellin Transform, and inserted a watermark into 2D-DFT magnitudes using Spread Spectrum. Experimental results shows that this method are robust to rotation attack.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.310-310
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• 2010

Electronic and photovoltaic characteristics of two sensitizers (TA-BTD-CA and TA-BTD-St-CA), composed of a different $\pi$-conjugation in the linker group, have been investigated by theoretical and experimental methods. The electronic structure, transition dipole moment and oscillator strengths of two sensitizers have been scrutinized by using density functional theory (DFT) and time-dependent DFT (TD-DFT) method. The LUMO level and the oscillator strength of TA-BTD-St-CA was higher than that of TA-BTD-CA, which may facilitate the electron injection process as well as increase the absorption coefficient. The relative efficiencies of the electron injection from the excited sensitizer to nanocrystalline TiO2 and SnO2 films have also been investigated by nanosecond transient absorption spectroscopy. The relative electron injection efficiency of TA-BTD-St-CA exhibited similar injection efficiency for two different semiconductors. However, in the case of TA-BTD-CA sensitizer, electron injection into SnO2 was approximately three times larger than that into TiO2. This enhancement of electron injection of TA-BTD-CA for the SnO2 is due to the increment of the driving force caused by positive shift of conduction band of semiconductor, which was also confirmed from the investigation for the photovoltaic characteristics according to the electrolyte additive, such as LiI additive.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.22 no.3
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• pp.513-519
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• 2018

OFDM modulation has been used for a transmission scheme in 4G LTE (Long Term Evolution) and Wi-Fi systems to mitigate the effects of frequency selective fading channels. An OFDM modulation is a block transmission scheme because an OFDM symbol consists of multiple subcarriers with narrow bandwidth. Therefore, all OFDM symbols in a frame should be filled out with data and padding bits. Depending on the amount of data, more padding bits than information bits can occupy the last OFDM symbol. Such inefficiency causes the loss of throughput. To overcome this problem, an efficiency padding method is proposed by using the property of DFT (Discrete Fourier Transform). In the proposed method, symbol duration of the last symbol is changed depending on the number used data subcarriers in the last symbol. With numerical evaluation, it is examined that throughput enhancement achieved by the proposed method can be about 20% depending a transmission scheme and data length.