• Title/Summary/Keyword: DEGRADATION

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A Study on the Physical Characteristics of the Low-voltage Circuit Breaker Based on the Accelerated Degradation Test (가속 열화 시험에 따른 저압용 차단기의 물리적 특성에 관한 연구)

  • Sin dong, Kang;Jae-Ho, Kim
    • Journal of the Korean Society of Safety
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    • v.37 no.6
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    • pp.1-8
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    • 2022
  • This study analyzed the characteristics of insulation resistance and operating time based on an accelerated degradation test of a low-voltage circuit breaker. The experimental sample used a molded case circuit breaker (MCCB) and an earth leakage circuit breaker (ELCB). After measuring the insulation resistance of the circuit breakers, the leakage current was affected by an external rather than an internal structure. Furthermore, the insulation resistance of the circuit breakers with accelerated degradation was measured using a Megger insulation tester. In the accelerated degradation test, aging times of five, ten, 15, and 20 years were applied according to a temperature derived using the Arrhenius equation. Circuit breakers with an equivalent life of ten, 15, and 20 years had increased insulation resistance compared to those with less degradation time. In particular, the circuit breaker with an equivalent life of ten years had the highest insulation resistance. Component analysis of the circuit breaker manufactured through an accelerated degradation test confirmed that the timing of the increase in insulation resistance and the time of additive loss were the same. Finally, after analyzing the operating time of the circuit breakers with degradation, it was confirmed that the MCCB did not change, but the ELCB breaker failed.

A Scientific Analytical on the Ancient Shipwrecks Degradation Products Excavated from Underwater: Focused on Sulfur and Iron Degradation Products

  • Ji-Seon SONG;Yong-Hee YOON;Chang-Hyun PARK
    • Journal of the Korean Wood Science and Technology
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    • v.52 no.3
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    • pp.243-261
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    • 2024
  • In this study, samples were collected from various ancient wooden shipwrecks, including the Shinan shipwreck and Jindo shipwreck that used iron nails, the Yeongheungdo shipwreck carrying iron artifacts, as well as the Sibidongpado shipwreck and Wando shipwreck where degradation products were not observed, all of which were salvaged by the National Research Institute of Maritime Heritage. The aim was to analyze the characteristics of degradation products generated by iron (Fe) within the salvaged wooden shipwreck materials and establish fundamental data on degradation products in waterlogged archaeological wood. The analysis revealed that sulfur (S) is generally accumulated in wood obtained from marine environments. It was observed that the content of inorganic substances such as iron and sulfur was significantly higher in the Shinan shipwreck, Jindo shipwreck, and Yeongheungdo shipwreck compared to Sibidongpado shipwreck and Wando shipwreck, which used wooden nails. This indicates that the presence of iron affects the accumulation of degradation products and suggests that iron is a factor in the corrosion of wood. Furthermore, crystallin compounds were observed within the cell walls, and higher concentrations of iron and sulfur were found in the resin ducts, rays, and radial tissues. This suggests that during desalination and consolidation treatments, warm water or polyethylene glycol (PEG) may move degradation factors into resincanals, rays, radial tissues, etc.

Degradation of Salicylic Acid by Free and Immobilized Cells of Pseudomonas sp. Strain NGK1

  • Patil, Neelakanteshwar-K.;Sharanagouda, U.;Niazi, Javed-H.;Kim, Chi-Kyung;Karegoudar, Timmanagouda-B.
    • Journal of Microbiology and Biotechnology
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    • v.13 no.1
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    • pp.29-34
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    • 2003
  • A Pseudomonas sp. strain NGK1 (NCIM 5120) capable of utilizing salicylate was immobilized in alginate and polyurethane foam (PUF). The degradation rate of salicylate by freely suspended cells was compared with the degradation rate by immobilized cells. In an initial 20 and 40 mM salicylate, free cells ($2{\times}10^{11}\;cfu\;ml^{-1}$) degraded to 16 and 14 mM, alginate-entrapped cells degraded to 18 and 26 mM, and PUF-entrapped cells degraded to 20 and 32 mM salicylate, respectively, in batch cultures. The alginate-and PUF-entrapped cells were used in repeated batch and continuous culture systems. The efficiency of both the immobilized systems f3r the degradation of salicylate was compared. It has been observed that the PUF-entrapped cells could be reused for more than 20 cycles whereas alginate-entrapped cells could be reused for a maximum of only 12 cycles, after which a decrease in degradation rat was observed with the initial 20 and 40 mM salicylate. The continuous degradation of sallcylate by freely suspended cells showed a negligible degradation rate of salicylate when compared with immobilized cells. With the immobilized cells in both alginate and polyurethane foam, the degradation rate increased with an increase in the dilution rate up to $2\;h^{-1}$ for 20 mM, and $1.5\;h^{-1}$ for 40 mM salicylate. The results revealed that PUF-entrapped cells were more efficient for the degradation of salicylate than alginate-entrapped cells and freely suspended cells.

Species identification and microscopic structure of ancient wood excavated from the remains( II ) -Degradation of ancient woods- (출토고목재의 수종과 조직구조에 관한 연구( II ) -출토고목재의 부후형태-)

  • KANG, A. K.;PARK, S. J.
    • Journal of Conservation Science
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    • v.2 no.2 s.2
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    • pp.15-24
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    • 1993
  • To understand the morphological change of ancient woods, samples classified by cell type, burial environment and species were collected and observed using microscopy. Decay of wood by cell type could classified into two types. First, degraded secondary wall was formed granular residues in $S_2$ layer and was remained $S_3$ layer and compound middle lamella. Second, the cell wall was slightly degraded and cracked in secondary wall. A gradual thinning of cell wall was occured. The compound middle lamella was separated from secondary wall. The resistance of degradation is increased at vessels, parenchyma, and tracheid and wood fiber in the order named. The type of degradation by species could be classified into four types. Overall degradation type; the degradation of cell wall is usually heavy and the extent of degradation Varies by part of the same sample. Partial degradation type ; this type shows severely different decay type by part of the sample. Nondegraded cells were mixed with degraded cells on the same sample. Erose degradation type ; thinning of the cell wall was occoured and the degradation type was different by part. Slight degradation types ; secondary wall was slightly degraded, cracked and separated from compound middle lamella. Considering different type of burial environment, dry wood was similiar to sound wood and slightly decayed. Waterlogged and peat burial wood was heavilydecayed. Between species of under the same environment, decay type and extent were diferentiated from each other.

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Measurement of Hydrogen Crossover by Gas Chromatograph in PEMFC (고분자전해질 연료전지에서 기체 크로마토그래프에 의한 수소투과도 측정)

  • Jeong, Jaejin;Jeong, Jaehyeun;Kim, Saehoon;Ahn, Byungki;Ko, Jaijoon;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.52 no.4
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    • pp.425-429
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    • 2014
  • Until a recent day, degradation of PEMFC MEA(membrane and electrode assembly) has been studied, separated with membrane degradation and electrode degradation, respectively. But membrane and electrode were degraded coincidentally at real PEMFC operation condition. During simultaneous degradation, there was interaction between membrane degradation and electrode degradation. Hydrogen permeability was used often to measure degradation of electrolyte membrane in PEMFC. In case of hydrogen permeability measured by LSV(Linear Sweep Voltammetry) method, the degradation of electrode decrease the value of hydrogen crossover current due to LSV methode's dependence on electrode active area. In this study hydrogen permeability was measured by gas chromatograph(GC) when membrane and electrode degraded at the same time. It was showed that degradation of electrode did not affect the hydrogen permeability measured by GC because of GC methode's independence on electrode active area.

Control of Hydrolytic Degradation of Polylactide Mixtures Using Optical Isomers (광학이성질체를 이용한 폴리락타이드 혼합물의 가수분해성 조절)

  • Lee, Won-Ki
    • Polymer(Korea)
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    • v.36 no.3
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    • pp.309-314
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    • 2012
  • To control degradation rate of biodegradable poly(lactide)s (PLA), the stereochemical PLAs with different ratios of $d$-lactide and $l$-lactide units were synthesized by the ring open polymerization and a degradation behavior was measured by a Langmuir film balance. Degradation rates of mixture monolayers on alkaline subphase were investigated as a function of optical purity of mixture component, 100, 99, 97 and 95%. As increasing their optical purity, melting temperatures of mixtures from stereocomplexation increased. The degradation rate of mixture monolayer with 100% optical purity was much slower than that of each homopolymer one and the others showed 2 step degradation behaviors. In the first step, the degradation which is faster than that of each homopolymer occurs in the uncomplexed region, and secondly, the degradation occurred in the complexed region which showed similar degradation rate to that of 100% optical purity. These results indicate that the alkaline degradation of stereochemical PLAs could be controlled by stereochemistry and stereocomplexation between enantiomer PLAs.

Hot-Carrier-Induced Degradation of Lateral DMOS Transistors under DC and AC Stress (DC 및 AC 스트레스에서 Lateral DMOS 트랜지스터의 소자열화)

  • Lee, In-Kyong;Yun, Se-Re-Na;Yu, Chong-Gun;Park, J.T.
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.44 no.2
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    • pp.13-18
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    • 2007
  • This paper presents the experimental findings on the different degradation mechanism which depends on the gate oxide thickness in lateral DMOS transistors. For thin oxide devices, the generation of interface states in the channel region and the trapped holes in the drift region is found to be the causes of the device degradation. For thick devices, the generation of interface states in the channel region is found to be the causes of the device degradation. We confirmed the different degradation mechanism using device simulation. From the comparison of device degradation under DC and AC stress, it is found that the device degradation is more significant under DC stress than one under AC stress. The device degradation under AC stress is more significant in high frequency. Therefore the hot carrier induced degradation should be more carefully considered in the design of RF LDMOS transistors and circuit design.

Study on stiffness deterioration in steel-concrete composite beams under fatigue loading

  • Wang, Bing;Huang, Qiao;Liu, Xiaoling;Ding, Yong
    • Steel and Composite Structures
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    • v.34 no.4
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    • pp.499-509
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    • 2020
  • The purpose of this paper is to investigate the degradation law of stiffness of steel-concrete composite beams after certain fatigue loads. First, six test beams with stud connectors were designed and fabricated for static and fatigue tests. The resultant failure modes under different fatigue loading cycles were compared. And an analysis was performed for the variations in the load-deflection curves, residual deflections and relative slips of the composite beams during fatigue loading. Then, the correlations among the stiffness degradation of each test beam, the residual deflection and relative slip growth during the fatigue test were investigated, in order to clarify the primary reasons for the stiffness degradation of the composite beams. Finally, based on the stiffness degradation function under fatigue loading, a calculation model for the residual stiffness of composite beams in response to fatigue loading cycles was established by parameter fitting. The results show that the stiffness of composite beams undergoes irreversible degradation under fatigue loading. And stiffness degradation is associated with the macrobehavior of material fatigue damage and shear connection degradation. In addition, the stiffness degradation of the composite beams exhibit S-shaped monotonic decreasing trends with fatigue cycles. The general agreement between the calculation model and experiment shows good applicability of the proposed model for specific beam size and fatigue load parameters. Moreover, the research results provide a method for establishing a stiffness degradation model for composite beams after fatigue loading.

Degradation Characteristics of Aqueous MEA Solution by Corrosion Products and Absorption Conditions (흡수 조건 및 부식 생성물에 의한 MEA 수용액의 변성 특성)

  • NAM, SUNGCHAN;SONG, YOONAH;BAEK, ILHYUN;YOON, YEOIL;YOU, JEONGKYUN;LEE, CHANGHA
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.3
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    • pp.290-297
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    • 2016
  • The absorbent loss due to degradation in $CO_2$ capture process using aqueous alkanol amine solution has adverse effect on the economics of overall process. The degradation causes absorbent loss, equipment corrosion, foaming, adhesive material producing and viscosity increase in operation. In this study, the degradation characteristics of $CO_2$ capture process using MEA (monoehtanolamine) under various conditions such as $O_2$ partial pressure, $CO_2$ loading and absorbent temperature. The effects of iron, which generated from the equipment corrosion, on absorbent degradation were studied using $Fe_2SO_4$ containing MEA solution. The produced gases were analyzed by FT-IR(Fourier Transform Infrared Spectrophotometer) and the specifically measured $NH_3$ concentration was used as a degradation degree of aqueous MEA solution. The experiments showed that the higher $CO_2$ loadings (${\alpha}$), $O_2$ fraction ($y_{O2}$) and reaction temperature enhanced the more degradation of aqueous MEA solution. Comparing other operation parameters, the reaction temperature most affected on the degradation. Therefore, it could be concluded that the above parameters affects on degradation should be considered for the selections of $CO_2$ absorbent and operating conditions.

Degradation of Chlorinated Hydrocarbons via a Light-Emitting Diode Derived Photocatalyst

  • Jo, Wan-Kuen;Lee, Joon Yeob
    • Environmental Engineering Research
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    • v.18 no.1
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    • pp.21-28
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    • 2013
  • In this study, the applicability of visible light-emitting-diodes (LEDs) to the photocatalytic degradation of indoor-level trichloroethylene (TCE) and perchloroethylene (PCE) over N-doped $TiO_2$ (N-$TiO_2$) was examined under a range of operational conditions. The N-$TiO_2$ photocatalyst was calcined at $650^{\circ}C$ (labeled N-650) showed the lowest degradation efficiencies for TCE and PCE, while the N-$TiO_2$ photocatalysts calcined at $350^{\circ}C$, $450^{\circ}C$, and $550^{\circ}C$ (labeled as N-350, N-450, and N-550, respectively) exhibited similar or slightly different degradation efficiencies to those of TCE and PCE. These results were supported by the X-ray diffraction patterns of N-350, N-450, N-550, and N-650. The respective average degradation efficiencies for TCE and PCE were 96% and 77% for the 8-W lamp/N-$TiO_2$ system, 32% and 20% for the violet LED/N-$TiO_2$ system, and ~0% and 4% for the blue LED/N-$TiO_2$ system. However, the normalized photocatalytic degradation efficiencies for TCE and PCE for the violet LED-irradiated N-$TiO_2$ system were higher than those from the 8-W fluorescent daylight lamp-irradiated N-$TiO_2$ system. Although the difference was not substantial, the degradation efficiencies exhibited a decreasing trend with increasing input concentrations. The degradation efficiencies for TCE and PCE decreased with increasing air flow rates. In general, the degradation efficiencies for both target compounds decreased as relative humidity increased. Consequently, it was indicated that violet LEDs can be utilized as energy-efficient light sources for the photocatalytic degradation of TCE and PCE, if operational conditions of N-$TiO_2$ photocatalytic system are optimized.