• Title/Summary/Keyword: DCB

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The effect of crosslinking and dry for the adsorption rate on the chitosan bead (키토산 비드의 교차결합(crosslinking)과 건조공정이 흡착속도에 미치는 영향)

  • Shin, Jeongwoo;Kim, Taehoon;Lee, Youngmin;An, Byungryul
    • Journal of Korean Society of Water and Wastewater
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    • v.35 no.4
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    • pp.301-309
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    • 2021
  • Chitosan, natural organic polymer, has been applied in water treatment as adsorbent due to non-toxic for human being. The amino group as functional group, can interacts with cation and anion at the same time. The prepared chitosan bead (HCB) was crosslinked to increase chemical stability (HCB-G) and both HCB and HCB-G were prepared to increase physical strength by drying referred to DCB and DCB-G, respectively. The adsorption effect for crosslinking and drying for four types of chitosan bead was tested using pseudo fist order (PFO), pseudo second order (PSO), and intraparticle diffusion model (ID). Regardless of PFO and PSO, the order of K, rate constant, is as followed: HCB > HCB-G > DCB > DCB-G for Cu(II) and phosphate. Drying leading to contraction of bead significantly reduced adsorption rate due to reduce the porosity of chitosan. In addition, crosslingking also negatively effect on adsorption rate. When compared with Cu(II) using hydrogel bead, phosphate showed higher value than Cu(II) for PFO and PSO. The application of ID showed that both hydrogel beads (HCB and HCB-G) obtained a very low R2 ranging to 0.37 to 0.81, while R2 can be obtained to over 0.9 for DCB and DCB-G, indicting ID is appropriate for low adsorption rate.

Study on Mode I Fracture Toughness and FEM analysis of Carbon/Epoxy Laminates Using Acoustic Emission Signal (음향 방출 신호를 이용한 탄소/에폭시 적층판의 Mode I 파괴 인성 및 유한요소해석에 관한 연구)

  • Cho, Hyun-jun;Jeon, Min-Hyeok;No, Hae-Ri;Kim, In-Gul
    • Composites Research
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    • v.35 no.2
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    • pp.61-68
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    • 2022
  • Composite materials have been used in aerospace industry and many applications because of many advantages such as specific strength and stiffness and corrosion resistance etc. However, it is vulnerable to impacts, these impact lead to formation of cracks in composite laminate and failure of structures. In this paper, we analyzed Mode I fracture toughness of Carbon/Epoxy laminates using acoustic emission signal. DCB test was carried out to analyze Mode I failure characterization of Carbon/Epoxy laminates, and AE sensor was attached to measure AE signal induced by failure of specimen. Fracture toughness was calculated using cumulative AE energy and measured crack length using camera. The calculated fracture toughness was applied in FE model and the result of FE analysis compared with DCB test results. The results show good agreement with between FEM and DCB test results.

Generation of Korean Ionospheric Total Electron Content Map Considering Differential Code Bias (Differential Code Bias를 고려한 한반도 전리층 총전자수 지도 생성)

  • Lee, Chang-Moon;Kim, Ji-Hye;Park, Kwan-Dong
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.29 no.3
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    • pp.293-301
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    • 2011
  • The ionospheric delay is the largest error source in GPS positioning after the SA effect has been turned off in May, 2000. In this study, we used 44 permanent GPS stations being operated by National Geographic Information Institute (NGII) to estimate Total Electron Content (TEC) based on pseudorange measurements phase-leveled by a linear combination with carrier phases. The Differential Code Bias (DCB) of GPS satellites and receivers was estimated and applied for an accurate estimation of the TEC. To validate our estimates of DCB, changes of TEC values after DCB application were investigated. As a result, the RMS error went down by about an order of magnitude; from 35~45 to 3~4 TECU. After the DCB correction, ionospheric TEC maps were produced at a spatial resolution of $1^{\circ}{\times}1^{\circ}$. To analyze the effect of the number of sites used for map generation on the accuracy of TEC values, we tried 10, 20, 30, and 44 stations and the RMS error was computed with the Global Ionosphere Map as the truth. While the RMS error was 5.3 TECU when 10 sites are used, the error reduced to 3.9 TECU for the case of 44 stations.

Prediction of Adsorption Isotherms and Diffusivity on Activated Carbon for Persistent Organic Pollutant(2,3,7,8-TCDD) (활성탄 위에서 잔류성 유기 오염물질(2,3,7,8-TCDD)의 등온 흡착식 및 확산계수 예측)

  • Lim, Young-Il;Son, Hae-Jeong;Lee, Ohsung;Nam, Kyong-Soo;Yoo, Kyoung-Seun
    • Korean Chemical Engineering Research
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    • v.47 no.6
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    • pp.747-754
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    • 2009
  • In this study, adsorption isotherms of o-DCB(ortho-dichlorobenzene) on an activated carbon heated at $1000^{\circ}C$ for 24 hours were obtained by experiment and were predicted by using molecular simulation. The initial molecular structure of the activated carbon was designed on the basis of its molecular formula and functional groups ratio measured experimentally. Then, the molecular structure was optimized using the COMPASS(condensed-phase optimized molecular potentials for atomistic simulation studies) force field. The particle porosity, specific surface area, and particle density obtained from the optimized molecular structure of activated carbon were compared with those experimental data. The errors between experimental data and simulation results of the particle porosity, specific surface area, and particle density were shown as 7.6, 3.8, and 2.8%, respectively. Adsorption isotherms constants of o-DCB are calculated by the GCMC(grand canonical Monte Carlo) method in the optimized molecular structure of activated carbon. The simulation result of the adsorption isotherms showed an error of under 3%, compared to that of experimental data. Adsorption isotherms, adsorption heat and pore diffusivity of 2,3,7,8-TCDD(tetrachlorodibenzo-p-dioxin) was finally obtained in the same molecular structure of the activated carbon as used for o-DCB. Thus, adsorption characteristics of persistent organic pollutants on activated carbon, which are not easy to experimentally evaluate, are predicted by the molecular simulation.

Wide Area Augmentation System Estimating C1P1 DCB (C1P1 DCB를 추정하는 광역보강항법 시스템)

  • Bu, Sung-Chun;So, Hyoung-Min;Kim, Kap-Jin;Lee, Chul-Soo;Kim, Do-Kyoung;Ko, Yo-Han
    • Journal of Advanced Navigation Technology
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    • v.22 no.5
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    • pp.400-408
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    • 2018
  • Wide area augmentation system is a system that generates and transmits correction and Integrity information for use in wide area. Typical system is SBAS. In the United States, it operates under the name WAAS, EGNOS in Europe, MSAS in Japan, SDCM in Russia, GAGAN in India. it is developing Korean SBAS which named KASS by 2022 in Korea. SBAS is a standard System that is operated as civil aviation service base and set as international standards by ICAO. So the correction data can only is used for civil SPS receiver. In this paper, we discuss C1P1 DCB estimation which need to use SPS correction service for PPS receiver. Then we analyze C1P1 DCB correction effect under standalone Satellite Navigation and method to use PPS receiver under SPS DGPS. Finally we organize wide area augmentation system for PPS receiver and analysis performance.

Bench-scale Experiment on Catalytic Decomposition of 1,2 Dichlorobenzene by Vanadia-Titania Catalyst

  • Jeong, Ju-Young;Chin, Sung-Min;Jurng, Jong-Soo
    • Journal of Environmental Science International
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    • v.18 no.7
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    • pp.709-714
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    • 2009
  • Catalytic activities of $V_2O_5/TiO_2$ catalyst were investigated under reaction conditions such as reaction temperature, catalyst size, inlet concentration and space velocity. A 1,2-dichlorobenzene(1,2-DCB) concentrations were measured in front and after of the heated $V_2O_5/TiO_2$ catalyst bed, and conversion efficiency of 1,2-DCB was determined from it's concentration difference. The conversion of 1,2-DCB using a pellet type catalyst in the bench-scale reactor was lower than that with the powder type used in the micro flow-scale reactor. However, when the pellet size was halved, the conversion was similar to that with the powder type catalyst. The highest conversion was shown with an inlet concentration of 100 ppmv, but when the concentration was higher or lower than 100 ppmv, the conversion was found to decrease. Complete conversion was obtained when the GHSV was maintained at below 10,000 $h^{-1}$, even at the relatively low temperature of $250^{\circ}C$. Water vapor inhibited the conversion of 1,2-DCB, which was suspected to be due to the competitive adsorption between the reactant and water for active sites.

A Study on the Surface Treatment of Prepreg with $Ar^+$ Ion to Increase Mode I Fracture Characteristics of Fiber-Reinforced Composites (섬유강화 적층복합재의 열림모드 파괴특성 향상을 위해 $Ar^+$ 이온도움반응법을 적용한 프리프레그의 표면처리 연구)

  • Lee, Gyeong-Yeop;Ji, Chang-Heon;Yang, Jun-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.11
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    • pp.2771-2776
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    • 2000
  • In this work, the effect of surface treatment of prepreg on the mode I fracture behavior was studied. Unidirectional (0-deg) double cantilever beam (DCB) specimens were used for fracture tests. Two groups of DCB specimens were made: the first group was made of prepregs surface-treated by Ar(sup)+ ion beam under oxygen environment and the second group was made of regular prepregs. For both groups, fracture resistance curve (R-curve) was determined and compared to each other, Results showed that resistance behavior of the first group is better than that of the second group. That is, mode I fracture toughness, G(sub)Ic of the first group is 24% larger than that of the second group. SEM examination shows that the improvement of G(sub)Ic is due to the increase of interfacial strength between plies.

Experimental investigation of interlaminar mechanical properties on carbon fiber stitched CFRP laminates

  • Iwahori, Yutaka;Ishikawa, Takashi;Watanabe, Naoyuki;Ito, Akira;Hayashi, Yoichi;Sugimoto, Sunao
    • Advanced Composite Materials
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    • v.16 no.2
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    • pp.95-113
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    • 2007
  • Experimental investigations of interlaminar mechanical properties for carbon fiber reinforced plastic (CFRP) laminates were carried out using aramid fiber ($Kevlar^{(R)}$-29 1000d) and carbon fiber (TR40-1K 612d, Mitsubishi Rayon) stitching. Various carbon fiber (CF) stitch densities were used to prepare a number of CF stitched CFRP laminates for double cantilever beam (DCB) tests. An insert tongue-type loading fixture, developed by the Japan Aerospace Exploration Agency (formerly the National Aerospace Laboratory of Japan), was also employed in the DCB test. Interlaminar tension tests were carried out under an out-of-plane directional loading using a single CF stitch thread in the CFRP laminates. The DCB test results clarified that the relationship between the volume fractions of the CF stitch thread ($V_{ft}$) and mode I critical energy release rate ($G_{Ic}$) showed a mostly linear function with a higher gradient than that of the $Kevlar^{(R)}$ stitched CFRP laminates. The CF stitched CFRP tension test results indicated that the consumption energy per unit area ($E_i$) was larger than that of $Kevlar^{(R)}$ stitched CFRP laminates.

Study on Fatigue Analysis of DCB Specimen Bonded (접착제로 접합된 DCB 시험편의 피로 해석에 관한 연구)

  • Choi, Hae-Kyu;Hong, Soon-Jik;Kim, Sei-Hwan;Cho, Jae-Ung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.7
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    • pp.2865-2871
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    • 2012
  • In this study, the fracture behaviour of DCB(double cantilever beam) specimen with aluminum foam composite materials is analyzed by simulation. By comparing the analysis results with two models of 25 mm and 40 mm, the model with thickness of 25 mm is weaker than 40 mm at fatigue life and damage. Two models are unfavorable at 'SAE Transmission' in case of nonuniform fatigue load and rainflow matrices are weakest at 'SAE Bracket history'. In damage matrices, the model with 25 mm of thickness is weaker than the model with 40 mm of thickness but the model with 40 mm of thickness relative damage possibility is higher than in case of 25 mm. As two models are safest at 'SAE Transmission', the relative damage becomes the lowest value from 1.1 to 1.8 %. The mechanical property can be investigated by applying these analyses results with the real composite structure bonded with adhesive and analyzing fracture behaviour.

A comparative study for beams on elastic foundation models to analysis of mode-I delamination in DCB specimens

  • Shokrieh, Mahmood Mehrdad;Heidari-Rarani, Mohammad
    • Structural Engineering and Mechanics
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    • v.37 no.2
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    • pp.149-162
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    • 2011
  • The aim of this research is a comprehensive review and evaluation of beam theories resting on elastic foundations that used to model mode-I delamination in multidirectional laminated composite by DCB specimen. A compliance based approach is used to calculate critical strain energy release rate (SERR). Two well-known beam theories, i.e. Euler-Bernoulli (EB) and Timoshenko beams (TB), on Winkler and Pasternak elastic foundations (WEF and PEF) are considered. In each case, a closed-form solution is presented for compliance versus crack length, effective material properties and geometrical dimensions. Effective flexural modulus ($E_{fx}$) and out-of-plane extensional stiffness ($E_z$) are used in all models instead of transversely isotropic assumption in composite laminates. Eventually, the analytical solutions are compared with experimental results available in the literature for unidirectional ($[0^{\circ}]_6$) and antisymmetric angle-ply ($[{\pm}30^{\circ}]_5$, and $[{\pm}45^{\circ}]_5$) lay-ups. TB on WEF is a simple model that predicts more accurate results for compliance and SERR in unidirectional laminates in comparison to other models. TB on PEF, in accordance with Williams (1989) assumptions, is too stiff for unidirectional DCB specimens, whereas in angle-ply DCB specimens it gives more reliable results. That it shows the effects of transverse shear deformation and root rotation on SERR value in composite DCB specimens.