• 제목/요약/키워드: D (Donor)

검색결과 358건 처리시간 0.024초

EuIII-1-Naphthoate Complex with N-Donor Ligand as a New White Luminescent Single Molecular Material

  • Eom, Yu Kyung;Biju, Silvanose;Kim, Hwan Kyu
    • Rapid Communication in Photoscience
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    • 제2권1호
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    • pp.34-37
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    • 2013
  • Two novel antenna complexes of $Eu^{III}$ with 1-naphthoic acid (NA) as primary ligand and two aromatic N-donor ligands namely N-hexyl-N-(pyridin-2-yl) pyridin-2-amine (1) and 4-((dipyridin-2-ylamino)methyl)benzoic acid (2) have been synthesized and characterized by various spectroscopic techniques. The room-temperature (298 K) photoluminescence spectrum of $Eu^{III}$ complexes composed of typical line like emissions, assigned to transitions between the first excited state $^5D_0$ to the $^7F_J$ (J = 0-4), resulting in red emission along with the residual emission from the 1-naphthoic acid moiety in the blue region. The determined CIE color coordinate value for the complex 2 is (x = 0.36, y = 0.34), which is in white region.

레이저 가열을 이용한 LCD 컬러 필터 프린팅 공정에 관한 연구 (A Study on LCD Color Filter Printing Process Using Localized Laser Heating)

  • 나성준;이재학;유중돈
    • 한국레이저가공학회지
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    • 제10권2호
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    • pp.5-15
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    • 2007
  • A new printing process for LCD color filter is proposed in this work by using the localized laser heating, which is called laser-induced spray printing (LISP) process. The LISP is a non-contact process, which injects the ink from the donor substrate to the glass substrate by the bubble pressure induced by laser heating. The temperature distribution of the donor substrate is calculated numerically to explain the ink ejection phenomena. The composition of the ink was includes the red pigment, n-butanol, xylene, BCA and epoxy. Experiments were conducted by using the fiber laser system, and the color filter patterns were deposited successfully under the proper laser heating conditions.

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Influence of Oocyte Nuclei on Demethylation of Donor Genome in Cloned Bovine Embryos

  • Y.K. Kang;D.B Koo;Park, J.S.;Park, Y.H.;Lee, K.K.;Y.M. Han
    • 한국동물번식학회:학술대회논문집
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    • 한국동물번식학회 2001년도 춘계학술발표대회
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    • pp.15-15
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    • 2001
  • We recently demonstrated that satellite regions exhibit an aberrant DNA methylation in cloned bovine embryos. Here, we examined, using bisulfite -sequencing technology, whether the inefficient demethylation of cloned donor genomes could be rescued by the presence of oocytic nuclei. Both AciI digestion and sequencing analyses showed that satellite sequence was demethylated more efficiently in cloned tetraploid blastocysts than in diploid clones. When methyl -CpG density (the number of methyl-CpG sites per string) was scored, a significant decrease was observed In tetraploids (P<0.001). These results suggest that unknown mechanisms provided by oocytic nuclei could assist the demethylation of satellite sequences in tetraploid clones.

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Vascularized Bone Graft Reconstruction for Upper Extremity Defects: A Review

  • Ava G. Chappell;Matthew D. Ramsey;Parinaz J. Dabestani;Jason H. Ko
    • Archives of Plastic Surgery
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    • 제50권1호
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    • pp.82-95
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    • 2023
  • Upper extremity reconstruction may pose clinical challenges for surgeons due to the often-critical, complex functional demands of the damaged and/or missing structures. The advent of vascularized bone grafts (VBGs) has aided in reconstruction of upper extremity (UE) defects due to their superior regenerative properties compared with nonvascularized bone grafts, ability to reconstruct large bony defects, and multiple donor site options. VBGs may be pedicled or free transfers and have the potential for composite tissue transfers when bone and soft tissue are needed. This article provides a comprehensive up-to-date review of VBGs, the commonly reported donor sites, and their indications for the treatment of specific UE defects.

하천에서 분리한 비소 내성세균의 유전적 특성 (Genetic Characteristics of Arsenic Compounds-Resistant Bacteria Isolated from Stream Water)

  • 정미경;이호자
    • 미생물학회지
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    • 제29권1호
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    • pp.63-68
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    • 1991
  • Several arsenic compound-resistant bacteria were isolated from Jung-Rang stream. The isolates, D-3, D-12, and D-14 were characterized phenotypically and genetically, and identified as Serratia liquefaciens, Klebsiella oxytoca, and Klebsiella pneumoniae, respectively. A plasmid of 67kb was found in Klebsiella oxytoca D-12 and designated as pMH12. Transfer of this plasmid from D-12 to E. coli HB101 was occurred, and the resulting transconjugant strains expressed the same level of heavy metal resistance as the donor strain. The physical presence of this plasmid in transconjugant was detected with agarose gel electrophoresis. Arsenite-sensitive derivatives of isolate D-12 were obtained with Mitomycin C treatment which cured pMH12. Antibiotics and heavy metal resistances were also examined to be used as a proper marker for the isolates in gene cloning. Isolate D-12 has resistance to several heavy metal ions such as $Cd^{2+}$ , $Zn^{2+}$ and $Hg^{ 2+}$ Also, all the other arsenite resistant isolates showed resistance to several heavy metal ions and antibiotics.

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Study of the Kinetics and Mechanisms of Alkoxy Radical Reactions in the Gas Phase (I). Arrhenius Parameters for t-Butoxy Radical Reactions with Isobutane and Cyclohexane

  • Song, Se-Ahn;Choo, Kwang-Yul
    • Bulletin of the Korean Chemical Society
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    • 제5권1호
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    • pp.16-21
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    • 1984
  • The relative Arrhenius parameters for t-butoxy radical decomposition (log $A_d$, $E_d$) and hydrogen abstraction of t-butoxy radical from hydrogen donor (log $A_d$, $E_d$) by competitive method were obtained as follows: for cyclohexane; log $A_a/A_d$ = -4.17 mole/l and $E_d-E_a$ = 9.01 kcal/mole, for isobutane; log $A_a/A_d$ = -5.70 mole/l and $E_e-E_a$= 11.0 kcal/mole. From the reported Arrhenius parameters for t-Butoxy radical decomposition reactions the parameters for t-Butoxy radical reactions with isobutane and cyclohexane are estimated to be log $A(l/mol{\cdot}sec)$ = 8.4, $E_a$ = 4.3 kcal/mol and $log A (l/mol{\cdot}sec)= 9.9,\;E_a$ = 6.3 kcal/mol, respectively.

메타구조 기반의 흡수체를 이용한 높은 격리도 특성의 WCDMA 댁내형 중계기 안테나 설계 (Design of WCDMA Indoor Repeater Antenna for High Isolation using the Absorber based on Metamaterial Structure)

  • 김형준;윤나내;서철헌
    • 대한전자공학회논문지TC
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    • 제49권6호
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    • pp.57-62
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    • 2012
  • 본 논문에서는 안테나 간 격리도 개선을 위해 메타구조 기반의 흡수체를 이용한 WCDMA 댁내형 중계기 안테나를 제안하였다. 제안된 안테나는 메타구조 흡수체가 배열된 메인패치와 대역폭을 위한 기생패치로 이루어져 있다. WCDMA 대역폭을 만족하기 위해 메인패치와 기생패치 사이의 커플링을 이용하였다. 메타구조 기반의 흡수체의 크기는 $13mm{\times}13mm$ 이며, 흡수율은 2.18 GHz 대역에서 약 94 % 의 특성을 갖고 있다. 송신 안테나와 수신 안테나 사이의 격리도는 메타구조 기반의 흡수체를 이용하여 개선하였다. 제안된 WCDMA 댁내형 중계기 안테나는 1.92 GHz부터 2.17 GHz 대역에서 6 dBi 이상의 안테나 이득과 2 이하의 VSWR 특성을 가지고 있으며, 송수신 안테나 사이의 격리도는 85 dB 이하의 특성을 나타내고 있다. 제안된 안테나의 크기는 $75mm{\times}75mm$ 이다.

EFFECTS OF SODIUM NITROPRUSSIDE ON THE FORMATION AND ACTIVATION OF THE OSTEOCLAST IN CULTURE

  • Yoo, Young-Jae;Kim, Jung-Kun;Cha, Kyung-Suk
    • 대한치과교정학회지
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    • 제25권6호
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    • pp.705-714
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    • 1995
  • Due to the great deal of effort that has gone into the study of osteoclastic differentiation and activation over the last few decades, the mechanisms of these two events have been discovered gradually. Nitric oxide($NO^-$), which is produced from arginine by a nitric oxide synthase, opened up a new area of biological research. Recently, it has been reported that $NO^-$ is produced by osteoblasts stimulated by lipopolysaccharide and several other cytokines. In this study, the effect of sodium nitroprusside(SNP), a donor of nitric oxide($NO^-$), on osteoclast-like cell formation and on mature osteoclast function was examined. To determine the mechanism of the inhibitory effects of SNP decreased not only the basal $^{45}Ca$ release but also thee bone resorption induced by PTH and 1,25-dihydroxyvitamin $D_3\;(1,25[OH]_{2}D_3)$. The inhibitory effect of SNP on bone resorption induced by PTH appeared 2 dyas after treatment, whereas SNP effect on inhibiting bone resorption induced by $1,25[OH]_{2}D_3$ appeared at the thhird days. When chicken and rat osteeoclasts were cultured on dentin slices, treatment of $300{\mu}M$ SNP resulted in a significant decrease in dentin resorption by osteoclasts in terms of total resolution area and average individual area. We also examind the effect of SNP on formation of osteoclast-like cells that is TRAP-positive multinucleated cells from chicken and rat bone marrow cells in the presence or absence of $10^{-8}\;M\;1,25[OH]_{2}D_3$. The addition of $300{\mu}M$ SNP inhibiteed the formation of TRAP-positive multinucleated cells. The present data suggest that SNP, possibly as a $NO^-$ donor, inhibits the osteoclastic differentiation and osteoclastic activity.

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A Series of Transition-metal Coordination Complexes Assembled from 3-Nitrophthalic Acid and Thiabendazole: Synthesis, Structure and Properties

  • Xu, Wen-Jia;Xue, Qi-Jun;Liang, Peng;Zhang, Ling-Yu;Huang, Yan-Feng;Feng, Yu
    • Bulletin of the Korean Chemical Society
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    • 제35권1호
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    • pp.218-224
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    • 2014
  • In order to explore new coordination frameworks with novel designed 3-nitrophthalic acid and the same N-donor ancillary ligand, a series of novel coordination complexes, namely, $[Cd_2(3-NPA)_2(TBZ)_2(H_2O)_2]{\cdot}2H_2O$(1), $[Zn_2(3-NPA)_2(TBZ)_2]$(2), $[Zn_2O(3-NPA)(TBZ)(H_2O)]_n$(3), $[Co(3-NPA)(TBZ)(H_2O)]_n$(4) (3-$NPAH_2$ = 3-nitrophthalic acid), have been hydrothermally synthesized through the reaction of 3-nitrophthalic acid with divalent transition-metal salts in the presence of N-donor ancillary coligand (TBZ = thiabendazole). As a result of various coordination modes of the versatile 3-$NPAH_2$ and the coligand TBZ, these complexes exhibit structural diversity. X-ray structure analysis reveals that 1 and 2 are 0D molecular rings, while 3 and 4 are one-dimensional (1D) infinite chain polymers. And the weak O-H${\cdots}$O hydrogen bonds and C-H${\cdots}$O nonclassical hydrogen bonds as well as ${\pi}-{\pi}$ stacking also play important roles in affecting the final structure where complexes 1, 3 and 4 have 3D supramolecular architectures, while complex 2 has a 2D supramolecular network. Also, IR spectra, fluorescence properties and thermal decomposition process of complexes 1-4 were investigated.

PBXN-109가 장전된 155 mm 고폭탄의 순폭현상 해석 (Sympathetic Detonation Modeling of PBXN-109)

  • 김보훈;김민성;양승호;오세안;김진석;최상경;여재익
    • 한국추진공학회지
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    • 제18권5호
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    • pp.1-11
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    • 2014
  • 하나의 탄약이 폭발하였을 경우 에너지가 다른 탄약으로 전달되어 폭발을 야기해 최종적으로 연쇄적인 폭발에 이를 수 있다. 본 연구에서는 PBXN-109가 충전된 155 mm 고폭탄의 동조폭발에 대한 2차원 하이드로 시뮬레이션을 수행하여 여폭약과 수폭약간 거리 및 중간 완충제에 따른 순폭 여부를 예측하였다. 계산 결과, 가까운 거리의 화약 간 순폭은 충격 점화로 인해 발생하며, 상대적으로 먼 거리의 경우에는 케이스의 파손으로 발생한 파편과의 충돌이 주요 원인으로 나타났다. 완충제는 폭굉파와 파편의 효과를 억제하여 동조폭발의 발생 확률을 낮출 수 있는 것으로 예측되었다.