• Bulletin of the Korean Chemical Society
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• v.32 no.6
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• pp.1997-2002
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• 2011

The nucleophilic substitution reactions of dicyclohexyl phosphinic chloride [3; $cHex_2$P(=O)Cl] with substituted anilines ($XC_6H_4NH_2$) and deuterated anilines ($XC_6H_4ND_2$) are investigated kinetically in acetonitrile at 60.0 $^{\circ}C$. The anilinolysis rate is too slow to be rationalized by the stereoelectronic effects. The rate is contrary to expectations for the electronic influence of the two ligands and exhibits exceptionally great negative deviation from the Taft's eq. The deuterium kinetic isotope effects (DKIEs) involving deuterated anilines invariably change from primary normal ($k_H/k_D$ > 1; max $k_H/k_D$ = 1.10 with X = 4-MeO) with the strongly basic anilines (X = 4-MeO, 4-Me, 3-Me) to secondary inverse ($k_H/k_D$ < 1; min $k_H/k_D$ = 0.673 with X = 3-Cl) with the weakly basic anilines (X = H, 4-F, 4-Cl, 3-Cl). A concerted $S_N2$ mechanism is proposed on the basis of both secondary inverse and primary normal DKIEs. The obtained DKIEs imply that the fraction of a frontside attack increases as the aniline becomes more basic. A hydrogen-bonded, four-center-type transition state is suggested for a frontside attack, while the trigonal bipyramidal pentacoordinate transition state is suggested for a backside attack.

• Korean Journal of Computational Design and Engineering
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• v.13 no.1
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• pp.45-57
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• 2008

A submarine good military weapon because of its confidentiality and intimidating power. Therefore, training warfighters how to maneuver submarine is very important. Because submarine is very expensive and has regional and temporal limitations, M&S(Modeling and Simulation) can be a good alternative. However, as the existing M&S systems of submarine generally use expensive commercial software and dedicated hardware, which cause the warfighters to take troubles to visit the secured places, and then to train themselves during limited time slots. Also, many M&S systems have only one-channel display system which reduces the sense of immersiveness. Another problem is that many heterogeneous simulators can hardly be used as an integrated system. To solve these problems, X3D, a platform-independent and open standard graphic file format, is used with the general-purpose PCs. To increase immersiveness, multi-channel display system and a motion chair are used. Finally, HLA/RTI is used to integrate individual components of the simulator. All of these are verified through experiments.

• Bulletin of the Korean Mathematical Society
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• v.39 no.3
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• pp.479-484
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• 2002

Let I be an ideal in a Gorenstein local ring A with the maximal ideal m and d = dim A. Then we say that I is a good ideal in A, if I contains a reduction $Q=(a_1,a_2,...,a_d)$ generated by d elements in A and $G(I)=\bigoplus_{n\geq0}I^n/I^{n+1}$ of I is a Gorenstein ring with a(G(I)) = 1-d, where a(G(I)) denotes the a-invariant of G(I). Let S = A[Q/a$_1$] and P = mS. In this paper, we show that the following conditions are equivalent. (1) $I^2$ = QI and I = Q:I. (2) $I^2S$ = $a_1$IS and IS = $a_1$S：sIS. (3) $I^2$Sp = $a_1$ISp and ISp = $a_1$Sp ：sp ISp. We denote by $X_A(Q)$ the set of good ideals I in $X_A(Q)$ such that I contains Q as a reduction. As a Corollary of this result, we show that $I\inX_A(Q)\Leftrightarrow\IS_P\inX_{SP}(Qp)$.

• Journal of the Institute of Electronics Engineers of Korea TC
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• v.47 no.2
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• pp.62-66
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• 2010

In this article, a oscillator at X-band with a double H-shape metamaterial resonator (DHMR) based on high-Q is proposed with metamaterial structure to improve Ihe phase noise and output power. The proposed oscillator is required low phase noise and high output power for the high performance frequency synthesizer. DHMR is designed to be high-Q at resonance frequency through strong coupling of E-field. This character makes phase noise excellent. The oscillator using DHMR is oscillated in X-band so as to apply frequency synthesizer of radar systems. The output power is 4.33 dBm and the phase noise is -108 dBc/Hz at 100 kHz offset of carrier frequency.

• Journal of the Institute of Electronics Engineers of Korea TC
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• v.46 no.2
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• pp.126-133
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• 2009

In this paper, The planar waveguide slotted antenna is presented for a satellite communication of vehicles. In stead of the microstrip patch array antenna having a dielectric loss and a feeding loss, the proposed antenna has the 3-layered waveguide feeding network structure for assembling easily. Also this antenna can receive mechanically both RHCP and LHCP transmitted from a satellite using a polarizer made from a thin single layer film. The Gain of the proposed 4X8 array antenna is 27.5dB and the gain of 8X16 array antenna is 32dB.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.16 no.4 s.95
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• pp.345-350
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• 2005

An X-band push-push VCO for low cost applications is proposed. The designed push-push oscillator achieves a wide tuning range in the X-band by the collector bias tuning instead of extra varactor diodes. The measurement shows a wide tuning bandwidth of $900\;\cal{MHz}\;from\;10.9\;\cal{GHz}\;to\;11.8\;\cal{GHz}$ with a drain bias voltage varying from 4 to 9 V, excellent fudamental suppression of $-30\;\cal{dBc}$ and good phase noise of $-115\;\cal{dBc/Hz}\;@\;1\;\cal{MHz}$ offset.

• The Journal of the Korea institute of electronic communication sciences
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• v.8 no.9
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• pp.1277-1283
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• 2013

In this paper, a novel voltage controlled oscillator(VCO) using CSRR loaded microstrip line for X-band RADAR is proposed. Using the microstrip line loaded CSRR inserted between the oscillator and buffer to the filter, the harmonic suppression has been improved. The measured results of the fabricated oscillator shows that its oscillation frequencies are from 9.28 to 9.39GHz according to the tuning voltage 0~10V, its output power level are about 16.6dBm at 9.35GHz. Compared with VCO using the conventional VCO, VCO using CSRR loaded microstirp, the harmonic suppression characteristic has been improved in 10.4dB

• Journal of the Korean Society of Radiology
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• v.17 no.5
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• pp.651-662
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• 2023

In this study, we designed and fabricated an ultra-compact CT that automatically calibrates the detector's center axis and verified its performance. The three-dimensional reconstruction performance was evaluated using 3D CAD data and X-ray data acquired by manually calibrating the center axis of the CT detector. The results showed that tilting the center axis by more than 0.25° causes circle break phenomenon, which rapidly degrades the quality of the 3D reconstructed image. By applying the automatic calibration device of a detector center axis, the 3D reconstruction performance was enhanced by calibrating the detector center axis to match the specimen rotation axis.

• The Korean Journal of Nuclear Medicine Technology
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• v.18 no.1
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• pp.69-75
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• 2014

Purpose: The aim of this study was to evaluate changes of quantitative and semi-quantitative myocardial perfusion indices and image quality by image reconstruction methods in $^{13}N$-ammonia ($^{13}N-NH_3$) myocardial perfusion PET/CT. Materials and Methods: Data of 14 (8 men, 6 women) patients underwent rest and adenosine stress $^{13}N-NH_3$ PET/CT (Biograph TruePoint 40 with TrueV, Siemens) were collected. Listmode scans were acquired for 10 minutes by injecting 370MBq of $^{13}N-NH_3$. Dynamic and static reconstruction was performed by use of FBP, iterative2D (2D), iterative3D (3D) and iterative TrueX (TrueX) algorithm. Coronary flow reserve (CFR) of dynamic reconstruction data, extent(%) and total perfusion deficit (TPD) (%) measured in sum of 4-10 minutes scan were evaluated by comparing with 2D method which was recommended by vendor. The image quality of each reconstructed data was compared and evaluated by five nuclear medicine physicians through a blind test. Results: CFR were lower in TrueX 18.68% (P=0.0002), FBP 4.35% (P=0.1243) and higher in 3D 7.91% (P<0.0001). As semi-quantitative values, extent and TPD of stress were higher in 3D 3.07%p (P=0.001), 2.36%p (P=0.0002), FBP 1.93%p (P=0.4275), 1.57%p (P=0.4595), TrueX 5.43%p (P=0.0003), 3.93%p (P<0.0001). Extent and TPD of rest were lower in FBP 0.86%p (P=0.1953), 0.57%p (P=0.2053) and higher in 3D 3.21%p (P=0.0006), 2.57%p (P=0.0001) and TrueX 5.36%p (P<0.0001), 4.36%p (P<0.0001). Based on the results of the blind test for image resolution and noise from the snapshot, 3D obtained the highest score, followed by 2D, TrueX and FBP. Conclusion: We found that quantitative and semi-quantitative myocardial perfusion values could be under- or over-estimated according to the reconstruction algorithm in $^{13}N-NH_3$ PET/CT. Therefore, proper dynamic and static reconstruction method should be established to provide accurate myocardial perfusion value.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.23 no.9
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• pp.806-813
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• 2013

For the past years, higher power rating 2 stroke super long stroke diesel engines having more than 8 cylinders and larger cylinder bore are installed mainly on very large containerships to save on fuel consumption. However, these engines are prone to X-mode vibration due to 2nd node torsional vibration or the X-type moment, particularly because of the increase in total length and height. Recently, cases of excessive X-mode vibration often occurred on engine's major components. This vibration is manifested also as secondary vibration causing failure in engine-mount large structures. This study investigated the excitations caused by the 2nd node propulsion shafting torsional vibration that influence X-mode vibration of the main engine and practical countermeasures are proposed. An 8RT-flex82T 8 cylinder engine and 11S90ME-C 11 cylinder engine for a container ship was used as research model.