• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2016년도 추계학술논문요약집
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• pp.93-94
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• 2016

• 전기화학회지
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• 제1권1호
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• pp.8-13
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• 1998

This work presents the way how to evaluate the degree of reversibility of the discharging process undergone by the nickel hydroxide film cathodically deposited on pure nickel as a positive electrode for electrochemical capacitor using the combined cyclic voltammetry and potential drop method, supplemented by galvanostatic discharge and open-circuit potential transient methods. The time interval necessary just to establish the current reversal of anodic to cathodic direction from the moment just after applying the potential inversion of anodic to cathodic direction, was obtained on cyclic voltammogram. The cathodic charge density passed upon dropping the applied potential, was calculated on potentiostatic current density-time curve. Both the time interval and the cathodic charge density in magnitude can be regarded as being measures of the degree of reversibility of the discharging process undergone by the positive active material for supercapacitor, i.e. , the longer the time interval is, the lower is the degree of reversibility and the greater the cathodic charge density is, the higher is the degree of reversibility. From the applied potential dependences of the time interval and cathodic charge density, discharge at $0.42 V_{SCE}$ was determined to be the most reversible.

• 한국응용과학기술학회지
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• 제34권2호
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• pp.376-381
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• 2017

지방산 혼합물 단분자층 LB막의 전기화학적 특성을 통하여 그 안정성을 순환전압전류법으로 조사하였다. 지방산혼합물 LB막은 ITO glass에 LB법을 사용하여 제막하였다. 전기화학적 특성은 0.01N $KClO_4$ 용액에서 3 전극 시스템으로 순환전압전류법에 의해 측정하였다. 측정범위는 연속적으로 1650 mV로 산화시키고, 초기 전위인 -1350 mV로 환원시켰다. 주사속도는 각각 50, 100, 150, 200 및 250 mV/s로 설정하였다. 그 결과 지방산혼합물 LB막은 순환전압전류곡선으로부터 산화전류로 인한 비가역 공정으로 나타났다. 지방산혼합물 LB막은 전해질농도가 0.01 N $NaClO_4$ 용액에서 확산계수(D)는 각각 $7.9{\times}10^{-2}cm^2s^{-1}$을 얻었다.

• 한국응용과학기술학회지
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• 제29권2호
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• pp.311-316
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• 2012

우리는 순환전압전류법에 의한 LB 필름에 대한 전기화학적 특성을 조사하였다. 인지질 화합물은 ITO glass에 Langmuir-Blodgett법을 사용하여 제막하였다. 0.5, 1.0, 1.5 및 2.0 N $NaClO_4$ 용액에서 3 전극 시스템 (Ag/AgCl 기준전극, 백금선 카운터 전극 및 LB 필름이 코팅된 ITO 작업전극)으로 순환전압전류법을 사용하여 전기화학적 측정을 시도하였다. 측정 범위는 연속적으로 1650 mV로 산화시키고, 초기전위인 -1350 mV로 환원시켰다. 그 결과, 인지질 화합물의 LB 필름은 순환전압전류도표로부터 오직 산화전류로 인한 비가역공정으로 나타났다. LB 필름의 확산계수(D) 효과는 인지질 화합물 양의 증가로 인하여 감소하였다.

• 한국응용과학기술학회지
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• 제31권3호
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• pp.352-358
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• 2014

포화지방산(C12, C14, C16, C18) 단분자층 LB막의 전기화학적 특성을 통하여 그 안정성을 순환전압전류법으로 조사하였다. 포화지방산 단분자층 LB막은 ITO glass에 LB법을 사용하여 제막하였다. 전기화학적 특성은 0.1 N $NaClO_4$ 용액에서 3 전극 시스템으로 순환전압전류법에 의해 측정하였다. 측정범위는 연속적으로 1650 mV로 산화시키고, 초기 전위인 -1350 mV로 환원시켰다. 주사속도는 각각 50, 100, 150, 200 및 250 mV/s로 설정하였다. 그 결과 포화지방산 LB막은 순환전압전류곡선으로부터 산화전류로 인한 비가역공정으로 나타났다. 포화지방산 LB막의 확산계수(D)를 산출한 결과 각각 라우르산, $2.223{\times}10^{-3}cm^2/s$, 미리스트산, $2.461{\times}10^{-4}cm^2/s$, 팔미트산, $7.114{\times}10^{-4}cm^2/s$ 및 스테아르산, $2.371{\times}10^{-4}$을 얻었다.

• 한국응용과학기술학회지
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• 제28권1호
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• pp.15-21
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• 2011

Threelectrodes systems were used in stripping voltammetry (SW) and cyclic voltammetry (CV) instead of the expensive platinum and Ag/AgCl reference electrodes. Moreover, the electrolyte solution was used with deep seawater, which can reduce water pollution, is more eco-friendly, and has a lower cost. The analytical optimum parameters measured via CV and SW and with working ranges were obtained from 10 to 80 ug/L using fluorine immobilized on a graphite pencil electrode (FE). Under the optimum conditions, the analytical detection limit of 6.30 ug/LAu was obtained. The results of the study can be applied to diagnostic assay for natural minerals and human finger tissue.

• 한국응용과학기술학회지
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• 제29권4호
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• pp.626-630
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• 2012

Diagnosis with an ex-vivo gold sensor was done using a modified fluorine-doping sensor, and cyclic voltammetry (CV) redox potentials of 0.4 V anodic and -0.2 V cathodic were obtained. Both peak currents were optimized using square-wave (SW) stripping voltammetry, and an analytical working range of 10-80 ug/L SW was attained. The precision of the 10-mg/L Au was 0.765 (n=8) RSD under the optimum conditions, and the analytical detection limit approached 0.006 ug/L (S/N=3) with only a 60 sec accumulation time. The developed method was used to examine the mouse droppings for medicinal diagnosis.

• Bulletin of the Korean Chemical Society
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• 제23권3호
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• pp.427-431
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• 2002

A screen printed graphite electrode has been developed for a simple and sensitive determination of phenolic compounds in an aqueous solution. The electrode developed uses a simple and effective screen printing technique with ${\alpha}-Cyclodextrin({\alpha}-CD)$ modified graphite ink. Phenols were captured on the surface of the ${\alpha}-CD$ modified electrode through complex formation. The phenol/ ${\alpha}-CD$ complex was deposited and quantified electrochemically using cyclic voltammetry (CV), differential pulse voltammetry (DPV) and square wave voltammetry (SWV). The optimization of the experimental parameters was performed in regard to electrode composition, pH, temperature, sample preconcentration time. Interferences from other organic compounds were investigated. The detection limit for phenols was 500 ${\pm}7$ nM for DPV, with the linear range of 0.5 ${\mu}M$ -25.0 ${\mu}M$ and 30 ${\pm}2$ nM for SWV, with the linear range of 30 nM - $50{\mu}M$, respectively.

• Journal of Electrochemical Science and Technology
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• 제13권3호
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• pp.347-353
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• 2022

Agarose hydrogel, a solid electrolyte, was investigated voltammetrically in terms of transport properties and natural convection effects using a ferrocenyl compound as a redox probe. To confirm the diffusion properties of solute on the agarose interface, the diffusion coefficients (D) of ferrocenemethanol in agarose hydrogel were determined by cyclic voltammetry (CV) according to the concentration of agarose hydrogel. While the value of D on the agarose interface is smaller than that in the bulk solution, the square root of the scan rate-dependent peak current reveals that the mass transport behavior of the solute on the agarose surface shows negligible convection or migration effects. In order to confirm the reduced natural convection on the gel interface, scan rate-dependent CV was performed in the solution phase and on the agarose surface, respectively. Slow scan voltammetry at the gel interface can determine a conventional and reproducible diffusion-controlled current down to a scan rate of 0.3 mV/s without any complicated equipment.

• 대한화학회지
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• 제51권5호
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• pp.412-417
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• 2007

DNA를 고정한 탄소나노튜브 페이스트 전극으로 옥시테트라싸이클린 항생제의 분석조건을 연구하였다. 사각 파형 벗김 전압전류법과 순환 전압 전류법을 사용하여 최적조건에서 1-10 ngL?1의 정량 가능 범위에 도달하였다. 벗김법 0.1 mgL?1 농도에서 15번 반복 측정하여 0.068%의 상대표준편차였으며, 벗김법 최적 분석 조건에서 0.4 ngL?1의 검출 한계를 얻었다. 개발된 결과를 양식어류의 세포에서 응용하였다.