• Title/Summary/Keyword: Cyclic treatment

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The Effects of Heat-treatment on the Mechanical Properties of High Chromium Cast Irons (고크롬 주철의 기계적 특성에 미치는 열처리 영향)

  • Kim, Sug-Won;Kim, Ki-Kon;Park, Jin-Sung;Kim, Dong-Keun;Yoon, Young-Gap
    • Journal of Korea Foundry Society
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    • v.25 no.1
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    • pp.23-29
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    • 2005
  • Mechanical characteristics of Hi-Cr cast irons containing 16.8%Cr and 3.0%C were studied with various heat treatments. After as-cast Y-block ingots were annealed fully, the ingots were machined into cylinderical specimens with the size of 9mm in diameter and 20mm in length in order to investigate the effect of heat-treatments on mechanical characteristics of high Cr cast irons. All specimens were heat-treated by quenching- tempering, austempering and cyclic heat at the various temperatures(950, 1000, 1050 and $1100^{\circ}C$) respectively. The wear amount was measured for each heat-treated specimens against the counterpart of a hardened SKD11 steel at the following conditions; wearing velocity: 0.7 m/s, load: 100N and sliding distance: 70 km. After as-cast specimens were annealed, fine $M_{3}C$ carbides were formed, which affected the hardness and the wear resistance of Hi-Cr specimens. High hardness and good wear resistance were appeared on the specimens treated at 950 and $1000^{\circ}C$ and the austempered specimens show excellent wear resistance as well as high hardness.

Electrochromic Properties on $\textrm{MoO}_3$ Thin Films with Heat Treatment ($\textrm{MoO}_3$ 박막의 열처리 효과에 따른 일렉트로크로믹 특성)

  • Jo, Bong-Hui;Kim, Yeong-Ho
    • Korean Journal of Materials Research
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    • v.9 no.11
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    • pp.1144-1147
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    • 1999
  • The effect of the heat treatment on electrochromic properties of $\textrm{MoO}_3$ thin films is investigated by studing optical modulation, optical density, response time, and cyclic voltammetry. From the results of XRD analysis, heat-treated at $450^{\circ}C$ in air for 1 hour Moo3 thin films are found to be crystalline while as-deposited and heat- treated at low temperature ($\leq\;300^{\circ}C$) film are amorphous. The electrochromic devices using as-deposited $\textrm{MoO}_3$ films exhibit good electrochromic properties compared to those using the heat treated $\textrm{MoO}_3$ films. It has shown that the heat-treatment affected the reversible color change and the electrochromic properties of $\textrm{MoO}_3$ films.

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Estrous Response and Fertility in Postpartum Suckled Female Yaks (Bos grunniens) Treated with an Intravaginal Device Containing Progesterone(CIDR), Pregnant Mares' Serum Gonadotrophin and Prostaglandin Analogue

  • Zi, X.D.;Chang, S.;Lu, H.;Wang, X.
    • Asian-Australasian Journal of Animal Sciences
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    • v.18 no.4
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    • pp.470-474
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    • 2005
  • The efficiency of a short-term treatment with an intravaginal device containing progesterone (CIDR) combined with pregnant mares' serum gonadotrophin (PMSG) and prostaglandin analogue ($PGF_{2\alpha}$) was evaluated for the induction of estrus, initiation of cyclic activity, and fertility in postpartum suckled yak cows. Seventy-five postpartum suckled yak cows were assigned to three treatments: (1) insertion of a CIDR intravaginal progesterone (1.9 g) (day 0), an administration of $PGF_{2\alpha}$ (0.2 mg i.m.) on day 6 and PMSG (1,000 IU i.m.) at the time of CIDR withdrawal on day 7 (CPP group, n=28); (2) an administration of $PGF_{2\alpha}$ (0.2 mg i.m.) on day 6 and PMSG (1,000 IU i.m.) on day 7 (PP group, n=21); (3) untreated animals served as the control (CG group, n=26). Seven yak bulls were placed in pastures with the cows for natural mating. Estrus rate in the CPP group (28/28) was higher (p<0.01) than in the PP group (6/21) and in the CG group (0/26) within 96 h after the end of treatment. The first service conception rate in the CPP group (21/28) was higher (p<0.01) compared with in the PP group (2/9) as judged by serum $P_4$ concentration $\geq$2.35 ng/ml on day 21 after breeding. It is concluded that a short-term progesterone treatment combined with PMSG and prostaglandin increased the proportion of yak cows that exhibited behavioral estrus with more synchronized estrus response and satisfactory conception rate in postpartum suckled yak cows.

Hydraulic Cleaning Effect on Fouling Mechanisms in Pressurized Membrane Water Treatment (가압식 멤브레인 수처리에서 수리학적 세정이 파울링 기작에 미치는 영향)

  • Charfi, Amine;Jang, Hoseok;Kim, Jeonghwan
    • Membrane Journal
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    • v.27 no.6
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    • pp.519-527
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    • 2017
  • Membrane fouling is the main issue hindering the expansion of low pressure membrane processes for surface water treatment. Therefore, applying periodic hydraulic cleaning for fouling control should be well optimized. Better understanding of membrane fouling associated with periodic hydraulic cleaning would be useful to optimize membrane cleaning strategies. By comparing experimental permeability data with the classical Hermia blocking laws, this study aims at analyzing membrane fouling and understanding dominant fouling mechanisms occurring when filtering a synthetic surface water solution with a pressurized membrane process during six filtration cycles of 30 min each, separated with cyclic cleaning of 1 min by backwashing and forward flushing separately and combined. When applying single cleaning technique, membrane fouling during the first cycles was controlled by complete blocking mechanism while the last cycles were dominated by cake formation. Nevertheless, when combining cleaning technique better membrane regeneration was obtained and fouling was mainly due to cake formation.

Charge-Discharge Characteristics of Carbonaceous Materials for a Negative Electrode in Lithium-Ion Batteries (리튬이온전직용 카본계부극재료의 충방전 특성)

  • 김정식;박영태;김상열;장영철
    • Journal of the Microelectronics and Packaging Society
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    • v.6 no.2
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    • pp.69-74
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    • 1999
  • Graphite and carbonaceous materials intercalate and deintercalate Li-ion reversibly into their layered structures. These materials show an excellent capacity for using a negative electrode in Li-ion batteries, because the electrochemical potential of Li-ion intercalated carbon is almost identical with that of lithium metal. Carbon used in this study was obtained by the pyrolysis of petroleum pitch, and heat-treated at the several temperatures between $700^{\circ}C$ and $1300^{\circ}C$. XRD analysis revealed that crystallization of carbon increased with increasing the heat treatment temperature. Charge/discharge properties were studied by a constant-current step at the rate of 0.1C, and the interfacial reaction between the electrolyte and the surface of carbon electrode was studied by cyclic voltammetry. Cell capacities were investigated in terms of the heat treatment temperature and the cycle number. Reversible capacity increased with the heat treatment temperature up to $1000^{\circ}C$, thereafter decreased continuously. Also, charge capacity decreased with the cycle number, while the reversibility improved with it.

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Alpha-linolenic acid enhances maturation and developmental competence via regulation of glutathione, cAMP and fatty acid accumulation during in vitro maturation of porcine oocytes

  • Jeon, Ye-Eun;Hwangbo, Yong;Kim, Sun-Young;Park, Choon-Keun
    • Journal of Animal Reproduction and Biotechnology
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    • v.35 no.4
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    • pp.357-365
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    • 2020
  • The aim of present study was to investigate regulatory mechanism of alpha-linolenic acid (ALA) during in vitro maturation (IVM) on nuclear and cytoplasmic maturation of porcine oocytes. Basically, immature cumulus-oocyte complexes (COCs) were incubated for 22 h in IVM-I to which hormone was added, and then further incubated for 22 h in IVM-II without hormone. As a result, relative cumulus expansion was increased at 22 h after IVM and it was enhanced by treatment of ALA compared with control group (p < 0.05). During IVM process within 22 h, cAMP level in oocytes was decreased at 6 h (p < 0.05) and it was recovered at 12 h in ALA-treated group, while oocytes in control group recovered cAMP level at 22 h. In cumulus cells, it was reduced in all time point (p < 0.05) and ALA did not affect. Treatment of ALA enhanced metaphase-I (MI) and MII population of oocytes compared with oocytes in control group at 22 and 44 h, respectively (p < 0.05). Intracellular GSH levels in ALA group was increased at 22 and 44 h after IVM (p < 0.05), whereas it was increased in control group at 44 h after IVM (p < 0.05). In particular, the GSH in ALA-treated oocytes during 22 h of IVM was higher than control group at 22 h (p < 0.05). Lipid amount in oocytes from ALA group was higher than control group (p < 0.05). Treatment of ALA did not influence to absorption of glucose from medium. Cleavage and blastocyst formation of ALA-treated oocytes were enhanced compared with control group (p < 0.05). These findings suggest that supplementation of ALA could improve oocyte maturation and development competence through increasing GSH synthesis, lipid storage, and regulation of cAMP accumulation during early 22 h of IVM, and these might be mediated by cumulus expansion.

Alkaline induced-cation crosslinking biopolymer soil treatment and field implementation for slope surface protection

  • Minhyeong Lee;Ilhan Chang;Seok-Jun Kang;Dong-Hyuk Lee;Gye-Chun Cho
    • Geomechanics and Engineering
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    • v.33 no.1
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    • pp.29-40
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    • 2023
  • Xanthan gum and starch compound biopolymer (XS), an environmentally friendly soil-binding material produced from natural resources, has been suggested as a slope protection material to enhance soil strength and erosion resistance. Insufficient wet strength and the consequent durability concerns remain, despite XS biopolymer-soil treatment showing high strength and erosion resistance in the dried state, even with a small dosage of soil mass. These concerns need to be solved to improve the field applicability and post-stability of this treatment. This study explored the utilization of an alkaline-based cation crosslinking method using calcium hydroxide and sodium hydroxide to induce non-thermal gelation, resulting in the enhancement of the wet strength and durability of biopolymer-treated soil. Laboratory experiments were conducted to assess the unconfined compressive strength and cyclic wetting-drying durability performance of the treated soil using a selected recipe based on a preliminary gel formation test. The results demonstrated that the uniformity of the gel structure and gelling time varied depending on the ratio of crosslinkers to biopolymer; consequently, the strength of the soil was affected. Subsequently, site soil treated with the recipe, which showed the best performance in indoor assessment, was implemented on the field slope at the bridge abutment via compaction and pressurized spraying methods to assess feasibility in field implementation. Moreover, the variation in surface soil hardness was monitored periodically for one year. Both slopes implemented by the two construction methods showed sufficient stability against detachment and scouring, with a higher soil hardness index than the natural slope for a year.

Electrochemical Behaviors of Platinum Catalysts Deposited on the Plasma Treated Carbon Blacks Supports (플라즈마 처리된 카본블랙 담지체에 담지된 백금 촉매의 전기화학적 거동)

  • Kim, Seok;Cho, Mi-Hwa;Lee, Jae-Rock;Ryu, Ho-Jin;Park, Soo-Jin
    • Korean Chemical Engineering Research
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    • v.43 no.6
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    • pp.756-760
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    • 2005
  • In this study, the effect of $N_2$-plasma treatment on carbon blacks (CBs) was investigated by analyzing acid-base surface values and surface functional groups of CBs. The surface characteristics of the CBs were determined by fourier transformed-infrared (FT-IR) spectrometer, X-ray photoelectron spectroscopy (XPS), and Boehm's titration method. Electrochemical properties of the plasma-treated CBs-supported Pt (Pt/CBs) catalysts were analyzed by cyclic voltammetry (CV) experiments. From the results of FT-IR and acid-base values, $N_2$-plasma treatment at 300 W intensity on the CBs led to the formation of the free radical. The peak intensity was increased with increasing the treatment time due to the formation of new basic functional groups(such as C-N, C=N, $-NH_3{^+}$, -NH, and =NH) by the free radical. Accordingly, the basic values were increased by the basic functional groups. However, after a specific reaction time, $N_2$-plasma treatment could hardly influence change of surface functional groups of CBs, due to the disappearance of free radical. Consequently, it was found that optimal treatment time was 30 second for electro activity of Pt/CBs catalysts.

Effect of Nitrogen Plasma Surface Treatment of Rice Husk-Based Activated Carbon on Electric Double-Layer Capacitor Performance (질소 플라즈마 표면처리가 쌀겨 기반 활성탄소의 전기 이중층 커패시터 성능에 미치는 영향)

  • Lee, Raneun;Kwak, Cheol Hwan;Lee, Hyeryeon;Kim, Seokjin;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.33 no.1
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    • pp.71-77
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    • 2022
  • To increase biomass utilization, rice husk-based activated carbon (RHAC) followed by nitrogen plasma surface treatment was prepared and the electric double-layer capacitor performance was investigated. Through nitrogen plasma surface treatment, up to 2.17% of nitrogen was introduced to the surface of RHAC, and in particular the sample reacted for 5 min with nitrogen plasma showed dominant formation of pyrrolic/pyridine N functional groups. In addition, mesopores were formed on the RHAC material by the removal of silica, and the surface roughness of the carbon material increased by nitrogen plasma surface treatment, resulting in the formation of many micropores. As a result of cyclic voltammetry measurement, at a scan rate of 5 mV/s, the specific capacitance of the RHAC treated with nitrogen plasma increased up to 200 F/g, showing an 80.2% improvement compared to that of using untreated RHAC (111 F/g). This is attributed to the synergetic effect of the introduction of pyrrolic/pyridine-based nitrogen functional groups and the increase of the micropore volume on the surface of the carbon material. This study has a positive effect on the environment in terms of recycling waste resources and using plasma surface treatment.

Influence of Textural Structure by Heat-treatment on Electrochemical Properties of Pitch-based Activated Carbon Fiber (열처리 온도에 의한 피치계 활성탄소섬유의 기공구조 변화가 전기화학적 특성에 미치는 영향)

  • Kim, Kyung Hoon;Park, Mi-Seon;Jung, Min-Jung;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.26 no.5
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    • pp.598-603
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    • 2015
  • In this study, electrochemical properties of pitch-based activated carbon fibers (ACFs) were investigated by different heat-treatment temperature of the pitch-based ACFs in order to improve the specific capacitance of electric double-layer capacitor (EDLC). The ACFs were prepared by different heat-treatment temperatures of 1050 and $1450^{\circ}C$, after activation with 4 M KOH at $800^{\circ}C$ using stabilized pitch fiber. The specific surface area of prepared ACFs increased from $828m^2/g$ to $987m^2/g$, also the micropore and mesopore volumes of prepared ACFs were increased. These results because pore was produced by desorbing oxygen and hydrogen elements within the ACFs, and pore size was increased by contraction ACFs by heat-treatment process. Because of the porous properties, the specific capacitance was increased from 73 F/g to 119 F/g using cyclic voltammetry with 1 M $H_2SO_4$ at scan rates of 5 mV/s.