• Title/Summary/Keyword: Cyclic resistance ratio

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Fabrication of Supercapacitors using Silver Nano Paste and Gel Electrolyte (은 나노 페이스트와 젤 전해질을 이용한 슈퍼캐패시터 제작)

  • Yoon, Seong Man;Jang, Hyunjung;Kim, Dae Won;Jang, Yunseok;Jo, Jeongdai;Go, Jeung Sang
    • Clean Technology
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    • v.19 no.4
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    • pp.410-415
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    • 2013
  • The supercapacitors were fabricated using silver (Ag) nano paste and activated carbon paste on the polyimide (PI) film and 5% potassium polyacrylate (PAAK) was used for gel electrolyte. In this paper, the current collector film and the electrode film were fabricated using screen printing. The thickness of printed silver paste was $7.3{\mu}m$ and the sheet resistance has the range of $5-7m{\Omega}/square$. An activated carbon with a surface area of $1,968m^2/g$, an electronic conducting agent (SUPER P, TIMCAL) and poly (4-vinylphenol) were mixed in 2-(2-buthoxyethoxy) ethyl acetate (BCA) with a ratio of 7:1:3 to fabricate the electrode paste. To analyze electrochemical characteristics, cyclic voltammetry was performed to evaluate the stability of the devices under the voltage range of -0.5-0.5 V. The calculated specific capacitances were 44.04 and 8.62 F/g for 10 and 500 mV/s scan rates, respectively.

Synthesis and Electrochemical Properties of Porous Li4Ti5O12 Anode Materials (기공구조로 제조된 Li4Ti5O12 음극활물질의 전기화학적 특성)

  • Seo, Jin-Seong;Na, Byung-Ki
    • Korean Chemical Engineering Research
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    • v.57 no.6
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    • pp.861-867
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    • 2019
  • $Li_4Ti_5O_{12}$ is a promising next-generation anode material for lithium-ion batteries due to excellent cycle life, low irreversible capacity, and little volume expansion during charge-discharge process. However, it has poor charge capacity at high current density due to its low electrical conductivity. To improve this weakness, porous $Li_4Ti_5O_{12}$ was synthesized by sol-gel method with P123 as chelating agent. The physical characteristics of as-prepared sample was investigated by XRD, SEM, and BET analysis, and electrochemical properties were characterized by cycle performance test, cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS). $Li_4Ti_5O_{12}$ synthesized by 0.01mol ratio of P123/Ti showed most unified particle size, high specific surface area, and relatively high porosity. EIS analysis showed that depressed semicircle size was remarkably reduced, which suggested resistance value in electrode was decreased. Capacity in rate performance showed 178 mAh/g at 0.2C, 170 mAh/g at 0.5C, 110 mA/h at 5C, and 90 mAh/g at 10C. Capacity retention also showed 99% after rate performance.

Seismic Performance of RC Column-Steel Beam Connections for Large Columns (대형기둥 적용을 위한 철근콘크리트기둥-강재보 접합부의 내진성능)

  • Park, Hong Gun;Lee, Ho Jun;Kim, Chang Soo;Hwang, Hyeon Jong
    • Journal of Korean Society of Steel Construction
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    • v.28 no.4
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    • pp.231-242
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    • 2016
  • Earthquake resistance of RC column-steel beam (RCS) joints with simplified details were studied. Simplified details are necessary for large columns to improve the productivity and constructability. To strengthen the beam-column joint, the effects of transverse beams, studs, and U-cross ties were used. Four 2/3 scale interior RCS connections were tested under cyclic lateral loading. The specimens generally exhibited good deformation capacity exceeding 4.0% story drift ratio after yielding of both beam and beam-column joint. Ultimately, the specimens failed by shear mechanism of the joint panel. The test strengths were compared with the predictions of existing design methods.

Evaluation and Comparison of Nanocomposite Gate Insulator for Flexible Thin Film Transistor

  • Kim, Jin-Su;Jo, Seong-Won;Kim, Do-Il;Hwang, Byeong-Ung;Lee, Nae-Eung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.278.1-278.1
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    • 2014
  • Organic materials have been explored as the gate dielectric layers in thin film transistors (TFTs) of backplane devices for flexible display because of their inherent mechanical flexibility. However, those materials possess some disadvantages like low dielectric constant and thermal resistance, which might lead to high power consumption and instability. On the other hand, inorganic gate dielectrics show high dielectric constant despite their brittle property. In order to maintain advantages of both materials, it is essential to develop the alternative materials. In this work, we manufactured nanocomposite gate dielectrics composed of organic material and inorganic nanoparticle and integrated them into organic TFTs. For synthesis of nanocomposite gate dielectrics, polyimide (PI) was explored as the organic materials due to its superior thermal stability. Candidate nanoprticles (NPs) of halfnium oxide, titanium oxide and aluminium oxide were considered. In order to realize NP concentration dependent electrical characteristics, furthermore, we have synthesized the different types of nanocomposite gate dielectrics with varying ratio of each inorganic NPs. To analyze gate dielectric properties like the capacitance, metal-Insulator-metal (MIM) structures were prepared together with organic TFTs. The output and transfer characteristics of organic TFTs were monitored by using the semiconductor parameter analyzer (HP4145B), and capacitance and leakage current of MIM structures were measured by the LCR meter (B1500, Agilent). Effects of mechanical cyclic bending of 200,000 times and thermally heating at $400^{\circ}C$ for 1 hour were investigated to analyze mechanical and thermal stability of nanocomposite gate dielectrics. The results will be discussed in detail.

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A Probabilistic Analysis of Liquefaction Potential and Pore Water Pressure Build up due to Earthquake (지진하중에 의한 액화의 가능성과 간극수압의 발생에 관한 확률론적 연구)

  • Kim, Young-Su;Lee, Song;Cho, Woo-Chul
    • Geotechnical Engineering
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    • v.8 no.2
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    • pp.31-44
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    • 1992
  • The probabilistic and statistical model is used to estimate the probability of liquefaction potential and pore water pressure build up due to earthquake in fully saturated sand deposit for each case of being structure(anisotropic) or not(isotropic). To execute this paper, dynamic shear strength parameters to show the relationship between shear strength and cyclic loading under isotropic or anisotropic condition in saturated sand deposit are presented. Using these parameters, the program which Predicts Pore water Pressure build up due to earthquake is developed. Using the 3-dimensional Random Field Model considering uncertainty of resistance and strength parameter, the program which computes the probability of liquefaction potential is developed. The developed program is applied to a case study, and then the result shows that the probability of liquefaction in isotropic condition is higher than in anisotropic condition. The ratio of pore water pressure tends to decrease as Kc increases.

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Fatigue Life Analysis and Prediction of 316L Stainless Steel Under Low Cycle Fatigue Loading (저사이클 피로하중을 받는 316L 스테인리스강의 피로수명 분석 및 예측)

  • Oh, Hyeong;Myung, NohJun;Choi, Nak-Sam
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.12
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    • pp.1027-1035
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    • 2016
  • In this study, a strain-controlled fatigue test of widely-used 316L stainless steel with excellent corrosion resistance and mechanical properties was conducted, in order to assess its fatigue life. Low cycle fatigue behaviors were analyzed at room temperature, as a function of the strain amplitude and strain ratio. The material was hardened during the initial few cycles, and then was softened during the long post period, until failure occurred. The fatigue life decreased with increasing strain amplitude. Masing behavior in the hysteresis loop was shown under the low strain amplitude, whereas the high strain amplitude caused non-Masing behavior and reduced the mean stress. Low cycle fatigue life prediction based on the cyclic plastic energy dissipation theory, considering Masing and non-Masing effects, showed a good correlation with the experimental results.

Crystal Structure and Electrochemical Properties of LiMn2-yMyO4 Cathode Material by Complex Substitution of Mg and Zn (Mg와 Zn의 복합치환에 따른 LiMn2-yMyO4 정극 활물질의 결정 구조 및 전기화학적 특성)

  • 정인성;정해덕;구할본
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.4
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    • pp.361-366
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    • 2002
  • Spinel $LiMn_{2-y}M_yO_4$ and $LiMn_{2-y}M_yO_4$ (M=Mg, Zn) powders were synthesized by solid-state method at $800^{\circ}C$ for 37h. Crystal structure and electrochemical properties were analyzed by X-ray diffraction, charge-discharge test, cyclic voltammetry and ac impedance to $LiMn_{2-y}M_yO_4$. All cathode material showed spinel structure in X-ray diffraction. Ununiform distortion which calculated by (111) face and (222) face was almost constant in spite of the change of the kind and the substituting ratio of the metal cation in $LiMn_{2-y}M_yO_4$ (M=Mg, Zn). $LiMn_{1.9}Mg_{0.05}Zn_{0.05}O_4/Li$ cell substituted $Mg^{+2}$ and $Zn^{+2}$ showed excellent discharge capacities than other cells, which it presented about 120mAh/g at the 1st cycle and about 73mAh/g at the 250th cycle, respectively. AC impedance of $LiMn_{2-y}M_yO_4/Li$ cells showed the similar resistance of about 65~110$\Omega$ before cycling.

Evaluation of Dynamic Ground Properties of Pohang Area Based on In-situ and Laboratory Test (현장실험 및 동적실내실험을 이용한 포항지역 동적 지반특성 평가)

  • Kim, Jongkwan;Kwak, Tae-Young;Han, Jin-Tae;Hwang, Byong-Youn;Kim, Ki-Seog
    • Journal of the Korean Geotechnical Society
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    • v.36 no.9
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    • pp.5-20
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    • 2020
  • In 2017, after the Pohang earthquake, liquefaction phenomena were firstly observed after the observation of domestic earthquake by epicenter. In this study, various in-situ tests and laboratory tests were performed to determine the dynamic properties in (1) Songlim Park, (2) Heunghae-eup, Mangcheon-ri and (3) Heungan-ri, Pohang. As a site investigation, the standard penetration test (SPT), cone penetration test (CPT), multichannel analysis of surface wave (MASW), density logging, downhole test, and electrical resistivity survey were performed. In addition, cyclic triaxial test against sampled sand from site was also conducted. Based on the result, high ground water level and loose sand layer in shallow depth were observed for all sites. In addition, liquefaction resistance ratio of soil sampled from Songlim park was lower than those of Jumunjin sand, Toyoura sand, and Ottawa sand.

Experimental and numerical investigation on the seismic behavior of the sector lead rubber damper

  • Xin Xu;Yun Zhou;Zhang Yan Chen;Song Wang;Ke Jiang
    • Earthquakes and Structures
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    • v.26 no.3
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    • pp.203-218
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    • 2024
  • Beam-column joints in the frame structure are at high risk of brittle shear failure which would lead to significant residual deformation and even the collapse of the structure during an earthquake. In order to improve the damage issue and enhance the recoverability of the beam-column joints, a sector lead rubber damper (SLRD) has been developed. The SLRD can increase the bearing capacity and energy dissipation capacity, and also demonstrating recoverability of seismic performance following cyclic loading. In this paper, the hysteretic behavior of SLRD was experimentally investigated in terms of the regular hysteretic behavior, large deformation behavior and fatigue behavior. Furthermore, a parametric analysis was performed to study the influence of the primary design parameters on the hysteretic behavior of SLRD. The results show that SLRD resist the exerted loading through the shear capacity of both rubber parts coupled with the lead cores in the pre-yielding stage of lead cores. In the post-yielding phase, it is only the rubber parts of the SLRD that provide the shear capacity while the lead cores primarily dissipate the energy through shear deformation. The SLRD possesses a robust capacity for large deformation and can sustain hysteretic behavior when subjected to a loading rotation angle of 1/7 (equivalent to 200% shear strain of the rubber component). Furthermore, it demonstrates excellent fatigue resistance, with a degradation of critical behavior indices by no more than 15% in comparison to initial values even after 30 cycles. As for the designing practice of SLRD, it is recommended to adopt the double lead core scheme, along with a rubber material having the lowest possible shear modulus while meeting the desired bearing capacity and a thickness ratio of 0.4 to 0.5 for the thin steel plate.

Manufacture of Cement-Bonded Particleboards from Korean Pine and Larch by Curing of Supercritical CO2 Fluid

  • Suh, Jin-Suk;Hermawan, Dede;Kawai, Shuichi
    • Journal of the Korean Wood Science and Technology
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    • v.28 no.4
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    • pp.41-50
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    • 2000
  • Cement-bonded particleboard is being used as outdoor siding material all over the world, because this composite particularly bears a light weight, high resistance against fire, decay, and crack by cyclic freezing and thawing, anti-shock property, and strength enhancement. Construction systems are currently changing into a frame-building style and wooden houses are being constructed with prefabrication type. Therefore, they require a more durability at outdoor-exposed sides. In this study, the cement hydration property for Korean pine particle, Japanese larch particle and face- and middle layer particles (designated as PB particle below) used in Korean particleboard-manufacturing company was investigated, and the rapid manufacturing characteristics of cement-bonded particleboard by supercritical $CO_2$ curing was evaluated. Korean pine flour showed a good hydration property, however, larch flour showed a bad one. PB particle had a better hydration property than larch flour. The addition of $Na_2SiO_3$ indicated a negative effect on hydration, however, $MgCl_2$ had a positive one. Curing by supercritical $CO_2$ fluid gave a conspicuous enhancement in the performances of cement-bonded particleboards compared to conventional curing. $MgCl_2$ 3%-added PB particle had the highest properties, and $MgCl_2$ 1%-added Korean pine particle had the second class with the conditions of cement/wood ratio of 2.7, a small fraction-screened particle and supercritical curing. On the contrary, the composition of non-hammermilled or large fraction-screened particle at cement/wood ratio of 2.2 was poorer. Also, the feasibility for actual use of 3%-added, small PB particle-screened fraction was greatest of all the conventional curing treatments. Relative superiority of supercritical curing vs. conventional curing at dimensional stability was not so apparent as in strength properties. Through the thermogravimetric analysis, it was ascertained that the peak of a component $CaCO_3$ was highest, and the two weak peaks of calcium silicate hydrate and ettringite and $Ca(OH)_2$ were present in supercritical treatment. Accordingly, it was inferred that the increased formation of carbonates in board contributes to strength enhancement.

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