• 제목/요약/키워드: Cyclic properties

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전기변색 $MoO_3$ 박막의 열처리 효과 (Annealing Effects of The Electrochromic $MoO_3$ Thin Films)

  • 임동규;이진민;조봉희;김동진;김영호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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    • pp.505-508
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    • 1999
  • The effect of the heat treatment on electrochromic properties of $MoO_3$ thin films is investigated by studing optical modulation, optical density, response time, and cyclic voltammetry. From the results of XRD analysis, heat-treated at $450^{\circ}C$ in air for 1 hour $MoO_3$ thin films are found to be crystalline while as-deposited film and heat-treated at low temperature (${\leq}300^{\circ}C$) are amorphous. The electrochrornic devices using as-deposited $MoO_3$ films exhibits good electrochromic properties compare to those using the heat treated $MoO_3$ films. It has shown that the heat-treatment affected the stability and the electrochromic properties of $MoO_3$ films.

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Classification of Bacillus Beneficial Substances Related to Plants, Humans and Animals

  • Mongkolthanaruk, Wiyada
    • Journal of Microbiology and Biotechnology
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    • 제22권12호
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    • pp.1597-1604
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    • 2012
  • Genus Bacillus is a spore-forming bacterium that has unique properties in cell differentiation, allowing the forming of spores in stress conditions and activated in the vegetative cell, with suitable environments occurring during the life cycle acting as a trigger. Their habitat is mainly in soil; thus, many species of Bacillus are associated with plants as well as rhizosphere bacteria and endophytic bacteria. Signal transduction is the principal mechanism of interactions, both within the cell community and with the external environment, which provides the subsequent functions or properties for the cell. The antimicrobial compounds of Bacillus sp. are potentially useful products, which have been used in agriculture for the inhibition of phytopathogens, for the stimulation of plant growth, and in the food industry as probiotics. There are two systems for the synthesis of these substances: nonribosomal synthesis of cyclic lipopeptides (NRPS) and polyketides (PKS). For each group, the structures, properties, and genes of the main products are described. The different compounds described and the way in which they co-exist exhibit the relationship of Bacillus substances to plants, humans, and animals.

실내 가속부식시험을 통한 해양 강관합성 말뚝의 방식 기법 수명 평가 (Evaluation of Life Time for Anti-Corrosive Methods for Marine Steel Sheet by Cyclic Corrosion Test)

  • 박종원;이종구;이경황;김진홍;정문경;이주형
    • Corrosion Science and Technology
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    • 제8권6호
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    • pp.243-250
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    • 2009
  • When a steel sheet pipe applied to marine environment, an anti-corrosive coating should be treated to obtain long-term life-time for steels, especially, splash zone. Although anti-corrosive property of coatings is required to be tested in real marine environment, it is difficult because of long test time such as 20 years or more time. Therefore, we used cyclic corrosion tester in a laboratory, which has similar conditions with salt-dry-wet process such as real marine environment. Anti-corrosive properties of the coatings and two steels were tested their anti-corrosive properties under cyclic corrosion test conditions(KS D ISO 14993) and the results were compared with estimate life-time in real marine environment. According to cyclic corrosion test, accelerated corrosive factor of each anti-corrosive coating was investigated accelerated corrosive factor from impedance with EIS method. Accelerated corrosive factor of type SS400 carbon steel and A690 was also investigated their accelerated corrosive factor from the regression curves of weigh loss results. One of the anti-corrosive coatings showed about 50 years life-time compared with standard sample life-time. Carbon steel SS400 showed from 0.1 mm/yr to 0.06 mm/yr as its corrosion rate.

Effect of surface treatment on the mechanical properties of nickel-titanium files with a similar cross-section

  • Kwak, Sang Won;Lee, Joo Yeong;Goo, Hye-Jin;Kim, Hyeon-Cheol
    • Restorative Dentistry and Endodontics
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    • 제42권3호
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    • pp.216-223
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    • 2017
  • Objectives: The aim of this study was to compare the mechanical properties of various nickel-titanium (NiTi) files with similar tapers and cross-sectional areas depending on whether they were surface-treated. Materials and Methods: Three NiTi file systems with a similar convex triangular cross-section and the same ISO #25 tip size were selected for this study: G6 (G6), ProTaper Universal (PTU), and Dia-PT (DPT). To test torsional resistance, 5 mm of the straightened file's tip was fixed between polycarbonate blocks (n = 15/group) and continuous clockwise rotation until fracture was conducted using a customized device. To evaluate cyclic fatigue resistance, files were rotated in an artificial curved canal until fracture in a dynamic mode (n = 15/group). The torsional data were analyzed using 1-way analysis of variance and the Tukey post-hoc comparison test, while the cyclic fatigue data were analyzed using the Mann-Whitney U test at a significance level of 95%. Results: PTU showed significantly greater toughness, followed by DPT and G6 (p < 0.05). G6 showed the lowest resistance in ultimate torsional strength, while it showed a higher fracture angle than the other files (p < 0.05). In the cyclic fatigue test, DPT showed a significantly higher number of cycles to failure than PTU or G6 (p < 0.05). Conclusions: Within the limitations of this study, it can be concluded that the torsional resistance of NiTi files was affected by the cross-sectional area, while the cyclic fatigue resistance of NiTi files was influenced by the surface treatment.

주기적(週期的) 반복하중(反復荷重)에 의한 연약점토(軟弱粘土)의 강도특성(强度特性) (Cyclic Strength Characteristics of Soft Clay)

  • 하광현
    • 대한토목학회논문집
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    • 제4권4호
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    • pp.49-58
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    • 1984
  • 연약점토(軟弱粘土)(방콕)의 주기적(週期的) 반복하중(反復荷重)에 의(依)한 거동(擧動)을 구명(糾明)하기 위하여 부교란시료(不攪亂試料)에 대(對)한 일련(一連)의 반복하중(反復荷重)을 이용(利用)한 삼축압축시험(三軸壓縮試驗)을 시도(試圖)했다. 본(本)시험(試驗)은 포속압력(抱束壓力) 및 초기전단응력(初期剪斷應力)을 변화(變化)시켜 가면서 점토(粘土)의 전단변형(剪斷變形), 강도변화(强度變化) 등(等)을 조사(調査) 비교(比較)한다. 그 결과(結果) 초기전단응력(初期剪斷應力)이 증가(增加)함으로써 응력(應力)-변형곡선(變形曲線)은 적은 변화(變化)를 보였고, 반복하중(反復荷重)에 의(依)한 강도변화(强度變化)는 응력비(應力比)로 표현(表現)될 때 포속압력(抱束壓力)이 $1.0kgf/cm^2$이었을 때 더 컸으며, 축차응력(逐差應力)으로 표현(表現)될 경우(境遇)는 포속압력(抱束壓力)이 $1.5kgf/cm^2$이었을 때 크게 나타났다.

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콘크리트구조물의 반복적 동결융해에 대한 수치 해석적 열화 예측 및 신뢰성 모델 개발 (Development of Deterioration Prediction Model and Reliability Model for the Cyclic Freeze-Thaw of Concrete Structures)

  • 조태준;김이현;조효남
    • 콘크리트학회논문집
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    • 제20권1호
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    • pp.13-22
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    • 2008
  • 다공성 시스템 내부 동결체의 생성과 성장은 온도경사와 화학적 에너지뿐만 아니라 열 물리학적 영향과 이동 물질에 의해서도 영향을 받는다. 더욱이 융해 화학물질의 확산율은 반복적인 동경융해 환경 하에서 매우 높은 값을 나타낸다. 결과적으로 콘크리트구조물의 열화는 해양환경과, 높은 고도 및 북쪽 지방에서 특히 크게 발생된다. 그러나 균열 성장과 누적된 손상에 의한 열화를 동반한 동결융해의 특성은 실험을 통해서 추정하기가 곤란하다. 이러한 손상을 예측하기 위해서 응답면기법 (RSM)을 이용한 회귀분석법을 사용하였다. 콘크리트구조물에서 반복되는 동결융해로 인한 열화의 주요 변수인 물-시멘트비, 연행공기, 동결융해의 반복 횟수 등은 응답면기법의 한계상태방정식을 구성하는데 중요한 입력 변수로 사용되었다. 누적변형률, 상대동탄성계수, 또는 등가 소성변형과 같은 주요한 열화 변수에 대한 회귀방정식은 열화된 구조물의 성능을 평가할 수 있다. 300번의 동결융해 반복 후의 상대동탄성계수와 잔류변형의 결과는 실험 결과와 매우 유사한 경향을 나타내었다. 응답면기법의 결과는 설계 시 한계값에 대한 초과 확률을 예측하는데 사용되어질 수 있다. 그러므로 개발된 예측 기법을 활용하여 반복적인 동결융해에 의해서 누적 손상을 받는 콘크리트구조물의 생애주기 관리에 사용될 수 있다.

Fe-30 Ni-0.24C합금에서 역변태 오스테나이트의 기계적 성질에 미치는 이전가공도 및 역변태 Cycle수의 영향 (Effect of Prior Deformation and Cyclic Transformation on the Mechanical Properties in Fe-30 Ni-0.24C Alloy)

  • 김학신;이규복;홍순국
    • 열처리공학회지
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    • 제3권4호
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    • pp.1-9
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    • 1990
  • In this study, the ausformed martensite cooled to $-196^{\circ}C$ with various deformation degrees in Fe-30%Ni-0.24%C alloy was transformed to reversed austenite at $500^{\circ}C$ by cyclic reverse martensitic transformation. The effects of prior deformation and the number of cyclic reverse transformation on the microstructure and the mechanical properities of reversed anstensite were investigated. Experimental results showed that the strength of reversed austenite was higher than that of original austenite. This is due to higher dislocation density and grain refining. The reversed austenite formed from ausformed martensite was highly strengthened by prior deformation. This strengthening effect of reversed austenite is attributed to higher dislocation density than grain fefining. The yield strength of reversed austenite below 30% prior deformation, but above 30% prior deformation the strength of reversed austenite is lower than that of deformed austenite. This is due to partly disappearance of strain hardening effect at higher deformation degree by reverse transformation. The strength of reversed austenite is increased with the number of cyclic transformation. Especially, it is principally strengthened by the first cyclic transformation and shows higher increase in yield strength than that of ultimate tensile strength.

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Modified cyclic steel law including bond-slip for analysis of RC structures with plain bars

  • Caprili, Silvia;Mattei, Francesca;Gigliotti, Rosario;Salvatore, Walter
    • Earthquakes and Structures
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    • 제14권3호
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    • pp.187-201
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    • 2018
  • The paper describes a modified cyclic bar model including bond-slip phenomena between steel reinforcing bars and surrounding concrete. The model is focused on plain bar and is useful, for its simplicity, for the seismic analyses of RC structures with plain bars and insufficient constructive details, such as in the case of '60s -'70s Mediterranean buildings. The model is based on an imposed exponential displacements field along the bar including both steel deformation and slip; through the adoption of equilibrium and compatibility equations a stress-slip law can be deducted and simply applied, with opportune operations, to RC numerical models. This study aims to update and complete the original monotonic model published by the authors, solving some numerical inconsistencies and, mostly, introducing the cyclic formulation. The first aim is achieved replacing the imposed linear displacement field along the bar with an exponential too, while the cyclic behaviour is described through a formulation based on the results of parametric analyses concerning a large range of steel and concrete properties and geometric configurations. Validations of the proposed model with experimental results available in the current literature confirm its accuracy and the reduced computational burden, highlighting its suitability in performing nonlinear analyses of RC structures.

The mechanical properties of rock salt under cyclic loading-unloading experiments

  • Chen, Jie;Du, Chao;Jiang, Deyi;Fan, Jinyang;He, Yi
    • Geomechanics and Engineering
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    • 제10권3호
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    • pp.325-334
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    • 2016
  • Rock salt is a near-perfect material for gas storage repositories due to its excellent ductility and low permeability. Gas storage in rock salt layers during gas injection and gas production causes the stress redistribution surrounding the cavity. The triaxial cyclic loading and unloading tests for rock salt were performed in this paper. The elastic-plastic deformation behaviour of rock salt under cyclic loading was observed. Rock salt experienced strain hardening during the initial loading, and the irreversible deformation was large under low stress station, meanwhile the residual stress became larger along with the increase of deviatoric stress. Confining pressure had a significant effect on the unloading modulus for the variation of mechanical parameters. Based on the theory of elastic-plastic damage mechanics, the evolution of damage during cyclic loading and unloading under various confining pressure was described.

Conformational Study of Cyclic Ac-Cys-Pro-Xaa-Cys-NHMe Peptides: a Model for Chain Reversal and Active Site of Disulfide Oxidoreductase

  • Park, Hae-Sook;Kim, Choon-mi;Kee, Kang-Young
    • 대한약학회:학술대회논문집
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    • 대한약학회 2002년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.2
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    • pp.330.2-330.2
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    • 2002
  • The conformational study on cyclic Ac-Cys-Pro-Xaa-Cys-NHMe (Ac-CPXC-NHMe: X = Ala, Val. Leu. Aib. Gly. His. Phe, Tyr. Asn. and Ser) peptides has been carried out using the ECEPP/3 force field and the hydration shell model in the unhydrated and hydrated states. This work has been undertaken to investigate structural implications of the CPXC sequence as the chain reversal for the initiation of protein folding and as the motif for active site of disulfide oxidoreductases. The backbone conformation DAAA is in common the most feasible for cyclic CPXC peptides in the hydrated state. which has a type 1${\beta}$-turn at the Pro-Xaa sequence. The proline residue and the hydrogen bond between backbones of two cystines appear to play a role in stabilizing this preferred conformation of cycilc CPXC peptides. However. the distributions of backbone conformations and ${\beta}$-turns may indicate that the cyclic CPXC peptide seems to exist as an ensemble of ${\beta}$-turns and coiled conformations. The intirnsic stability of the cyclic CPXC motif itself the active conformation appears to play a role in determining electrochemical properties of disulfide oxidoreductases.

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