• Title/Summary/Keyword: Cyclic properties

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Electrochemical Properties of Langmuir-Blodgett(LB) Film of Alkyl Bromides (브롬화 알킬화합물 LB막의 전기화학적 특성)

  • Park, Keun-Ho;Son, Tae-Chul;Min, Chang-Hun
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.4
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    • pp.451-456
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    • 2009
  • We carried out this experiment to observe an electrochemical properties for LB films of alkyl compounds by the cyclic voltammetry. Alkyl bromides was deposited by using the Langmuir- Blodgett method on the ITO glass. We measured to an electrochemical measurement by using cyclic voltammetry with a three-electrode system(an Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode) in 0.5, 1.0, 1.5 and 2.0 N $NaClO_4$ solution. A measuring range was reduced from initial potential to -1350 mV, continuously oxidized to 1650 mV. The scan rate were 100 mV/s. As a result, an electrochemical properties of the LB films of alkyl bromides appeared irreversible process caused by only the oxidation current from the cyclic voltammogram. The diffusivity(D) effect of LB films decreased with increasing of alkyl compounds amount.

Liquefaction and post-liquefaction behaviour of a soft natural clayey soil

  • Kheirbek-Saoud, Siba;Fleureau, Jean-Marie
    • Geomechanics and Engineering
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    • v.4 no.2
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    • pp.121-134
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    • 2012
  • The paper presents the results of identification, monotonous and cyclic triaxial tests on a potentially liquefiable soil from the Guadeloupe island. The material is a very soft clayey soil whose susceptibility to liquefaction is not clear when referring to index properties such as grain size distribution, plasticity, etc. The classifications found in the literature indicate that the material has rather a "clay-like" behaviour, i.e., is not very susceptible to liquefaction, but its properties are very close to the threshold values given by the authors. Cyclic triaxial tests carried out on the material under different conditions show that liquefaction is possible for a relatively important level of cyclic deviator or number of cycles. The second part of the paper is devoted to the study of the recovery of the soil after liquefaction and possibly reconsolidation. For the specimens tested without reconsolidation, that simulated the soil immediately after an earthquake, the recovery is nearly non-existent but the drop in pore pressure during extension results in a small available strength. On the contrary, after reconsolidation, the increase in strength of the liquefied specimens is quite large, compared to the initial state, but with unchanged failure envelopes.

Effect of Seawater Temperature on the Cyclic Potentiodynamic Polarization Characteristics and Microscopic Analysis on Damage Behavior of Super Austenitic Stainless Steel (슈퍼오스테나이트 스테인리스강의 순환동전위 분극특성에 미치는 해수온도의 영향과 손상 거동에 관한 미시적 분석)

  • Hwang, Hyun-Kyu;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.20 no.6
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    • pp.412-425
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    • 2021
  • Because austenitic stainless steel causes localized corrosion such as pitting and crevice corrosion in environments containing chlorine, corrosion resistance is improved by surface treatment or changes of the alloy element content. Accordingly, research using cyclic potentiodynamic polarization experiment to evaluate the properties of the passivation film of super austenitic stainless steel that improved corrosion resistance is being actively conducted. In this investigation, the electrochemical properties of austenitic stainless steel and super austenitic stainless steel were compared and analyzed through cyclic potentiodynamic polarization experiment with varying temperatures. Repassivation properties were not observed in austenitic stainless steels at all temperature conditions, but super austenitic stainless steels exhibited repassivation behaviors at all temperatures. This is expressed as α values using a relational formula comparing the localized corrosion rate and general corrosion rate. As the α values of UNS S31603 decreased with temperature, the tendency of general corrosion was expected to be higher, and the α value of UNS N08367 increased with increasing temperatures, so it is considered that the tendency of localized corrosion was dominant.

Poisson's ratios of fabric materials in use for large-span membrane structures

  • Jianhui Hu;Wujun Chen;Chengjun Gao;Yibei Zhang;Yonglin Chen;Pujin Wang
    • Structural Engineering and Mechanics
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    • v.90 no.6
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    • pp.543-549
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    • 2024
  • The utilization of the fabric materials for lightweight building structures has attracted considerable attention due to the multiple functions and high strength-to-weight ratio. The mechanical properties of the fabric materials evolve with the loading cycle, especially for the Poisson's ratio that requires the full cyclic strain to determine the accurate values. The digital image correlation method has been justified but needs to meet the flexibility and complexity requirements of the fabric materials. This paper thus proposes a modified digital image correlation method to quantify the Poisson's ratio of fabric materials. To obtain the accurate Poisson's ratio of fabric materials in the cyclic experiments using non-contact measuring method, a speckle generation of the digital image correlation method is implemented to obtain the strain distribution and strain characteristics. The uniaxial cyclic experiments for the fabric materials are carried out in the warp, weft and 45° directions. The digital image correlation photos are taken when the material properties become stable in the cyclic loading. The results show that the strain distributions are non-uniform and dependent on the specimen directions. The reliable Poisson's ratios of the fabric materials in the warp, weft and 45° directions are 0.016, 1.2 and 2.6. The strain asymmetry at the maximum strain position is related with the weaving architecture. These observations and results are indispensable to understand the Poisson's ratios of fabric materials and to guide the proper analysis of the large-span membrane structures.

A Study on How Cyclic Casting of Base Metal Alloy for Dental Ceramic Crown May Effects upon Its Mechanical Properties and Microstructure (치과 도재용착 주조관용 비귀금속 합금의 반복주조가 기계적 특성 및 미세조직에 미치는 영향)

  • Choi, Un-Jae;Shin, Moo-Hak;Chung, Hee-Sun;Koh, Myoung-Won
    • Journal of Technologic Dentistry
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    • v.25 no.1
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    • pp.9-20
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    • 2003
  • Using a nickel-chrome casting alloy called 'Rexillium V' which is also available as base metal alloy for dental ceramic crown, 4 types of mixtures(A, B, C, D) with old and new metal were prepared for cyclic casting. The results of cyclic casting can be outlined as follows: 1. For Vickers hardness after casting, specimen A and D tended to have lower hardness in the course of cyclic casting, while specimen B and C tended to higher hardness. 2. The results of X-ray diffraction analysis showed that major crystal phase contained nickelchrome compounds and carbide. 3. The observation results of SEM photographs after cyclic casting show that there was a significant tendency to have similar structures among experimental groups. 4. The results of EDX analysis after cyclic casting showed that there were little differences in chemical composition between parent metal and base metal alloy. Although industrial nickel-chrome cast alloy did not show any significant change in material properties even through cyclic casting over several times, it is recommended that more there be more in-depth studies on how to detect any potential corrosion, discoloration and toxication of dental ceramic crown implanted in patient's oral cavity.

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Effects of silt contents on the static and dynamic properties of sand-silt mixtures

  • Hsiao, Darn H.;Phan, Vu T.A.
    • Geomechanics and Engineering
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    • v.7 no.3
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    • pp.297-316
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    • 2014
  • This paper presents a detailed study focused on investigating the effects of silt content on the static and dynamic properties of sand-silt mixtures. Specimens with a low-plastic silt content of 0, 15, 30 and 50% by weight were tested in static triaxial, cyclic triaxial, and resonant columns in addition to consolidation tests to determine such parameters as compression index, internal friction angle, cohesion, cyclic stress ratio, maximum shear modulus, normalized shear modulus and damping ratio. The test procedures were performed on specimens of three cases: constant void ratio index, e = 0.582; same peak deviator stress of 290 kPa; and constant relative density, $D_r$ = 30%. The test results obtained for both the constant-void-ratio-index and constant-relative-density specimens showed that as silt content increased, the internal friction angle, cyclic stress ratio and maximum shear modulus decreased, but cohesion increased. In testing of the same deviator stress specimens, both cohesion and internal friction angle were insignificantly altered with the increase in silt content. In addition, as silt content increased, the maximum shear modulus increased. The cyclic stress ratio first decreased as silt content increased to reach the threshold silt content and increased thereafter with further increases in silt content. Furthermore, the damping ratio was investigated based on different silt contents in three types of specimens.

Numerical study on fire resistance of cyclically-damaged steel-concrete composite beam-to-column joints

  • Ye, Zhongnan;Heidarpour, Amin;Jiang, Shouchao;Li, Yingchao;Li, Guoqiang
    • Steel and Composite Structures
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    • v.43 no.5
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    • pp.673-688
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    • 2022
  • Post-earthquake fire is a major threat since most structures are designed allowing some damage during strong earthquakes, which will expose a more vulnerable structure to post-earthquake fire compared to an intact structure. A series of experimental research on steel-concrete composite beam-to-column joints subjected to fire after cyclic loading has been carried out and a clear reduction of fire resistance due to the partial damage caused by cyclic loading was observed. In this paper, by using ABAQUS a robust finite element model is developed for exploring the performance of steel-concrete composite joints in post-earthquake fire scenarios. After validation of these models with the previously conducted experimental results, a comprehensive numerical analysis is performed, allowing influential parameters affecting the post-earthquake fire behavior of the steel-concrete composite joints to be identified. Specifically, the level of pre-damage induced by cyclic loading is regraded to deteriorate mechanical and thermal properties of concrete, material properties of steel, and thickness of the fire protection layer. It is found that the ultimate temperature of the joint is affected by the load ratio while fire-resistant duration is relevant to the heating rate, both of which change due to the damage induced by the cyclic loading.

The influence of fine particle migration on pore structure of overlying ballast under cyclic loading

  • Yu Ding;Yu Jia;Zhongling Zong;Xuan Wang;Jiasheng Zhang;Min Ni
    • Geomechanics and Engineering
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    • v.35 no.6
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    • pp.627-636
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    • 2023
  • The essence of subgrade mud pumping under train load is the migration of fine particles in subgrade soil. The migration of fine particles will change the pore structure of overlying ballast, thus affecting the mechanical properties and hydraulic properties of ballast layer. It is of great theoretical significance and engineering value to study the effect of fine particle migration on the pore structure of ballast layer under cyclic loading. In this paper, a tailor-made subgrade mud pumping test model and an X-ray computed tomography (CT) scanning equipment were used to study the influence of migration of fine particles in subgrade soil on the pore parameters (plane porosity, volume porosity, pore distribution and pore connectivity) of overlying ballast under cyclic loading. The results show that the compression of ballast pores and the blockage of migrated fine particles make the porosity of ballast layer decreases gradually. And the percentage of small pores in ballast layer increases, while the percentage of large pores decreases; the connectivity of pores also gradually decreases. Based on the test results, an empirical model of ballast porosity evolution under cyclic loading is established and verified.

A Study on the Long-term Mechanical Properties Under Static and Cyclic State of Composite Insulators for Transmission Lines (송전용 고분자 애자의 정적 및 동적인 상태에서 장기 기계적 특성 연구)

  • Kim, S.Y.;Kim, Y.S.;Hong, J.Y.;Park, W.K.
    • Proceedings of the KIEE Conference
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    • 1998.11c
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    • pp.869-871
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    • 1998
  • The extensive use of composite insulators for transmission lines can ultimately be justified only on long-term qualification tests. The actual load working on the insulator in the field is not static load but cyclic load. So in this paper, we discussed an examination of aging degradation by mechanical performance of composite insulators under static tension load and cyclic tension load. and also described useful approaches for analyzing their long term performance so as to develop reliable composite insulators. The static and cyclic tension load-time test data were examined by Weibull distribution for their capability of presuming long term performance. It was found that cyclic tension loads were more severe than static tension loads. The results also indicate that it may be relevant for an user to select composite insulators on basis of their performance under cyclic tension loads than static tension loads.

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Modulus degradation of concrete exposed to compressive fatigue loading: Insights from lab testing

  • Song, Zhengyang;Konietzky, Heinz;Cai, Xin
    • Structural Engineering and Mechanics
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    • v.78 no.3
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    • pp.281-296
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    • 2021
  • This article analyzed the modulus degradation of concrete subjected to multi-level compressive cyclic loading. The evolution of secant elastic modulus is investigated based on measurements from top loading platen and LVDT in the middle part of concrete. The difference value of the two secant elastic moduli is reduced when close to failure and could be used as a fatigue failure precursor. The fatigue hardening is observed for concrete during cyclic loading. When the maximum stress is smaller the fatigue hardening is more obvious. The slight increase of maximum stress will lead to the "periodic hardening". The tangent elastic modulus shows a specific "bowknot" shape during cyclic loading, which can characterize the hysteresis of stress-strain and is influenced by the cyclic loading stresses. The deterioration of secant elastic modulus acts a similar role with respect to the P-wave speed during cyclic loading, can both characterize the degradation of the concrete properties.