• 제목/요약/키워드: Cyanohydrin trimethylsilyl

검색결과 2건 처리시간 0.017초

Cyanosilylation of Carbonyl Compounds Catalyzed by Potassium L-Aspartate

  • George, Soney C.;Kim, Sung-Soo;Kim, Ho-Sub
    • Bulletin of the Korean Chemical Society
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    • 제28권12호
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    • pp.2431-2434
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    • 2007
  • Potassium L-aspartate has been used as a catalyst for the cyanosilylation of carbonyl compounds producing corresponding cyanohydrin trimethylsilyl ethers in excellent yield of up to 98%. Although the catalyst is chiral, the enantioselectivities observed are generally poor except for one case, α-naphthaldehyde, 89% ee.