• Bulletin of the Korean Chemical Society
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• v.22 no.7
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• pp.669-672
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• 2001

Pseudo-first-order rate constants have been measured spectrophotometrically for the title reactions. The plot of kobs vs the concentration of alkali metal ethoxides is linear for the reactions performed in the presence of complexing age nt, 18-crown-6 ether, but curved upwardly for the corresponding reactions performed in the absence of the complexing agent, indicating that the alkali metal ions studied in this study behave as a catalyst. The catalytic effect was found to increase in the order Li+ << K+ ${\leq}$ Na+. Second-order rate constants were determined for the reactions with dissociated free ethoxide (kEtO-) and with ion paired alkali metal ethoxides (kEtO-M+ ) from ion pairing treatments. The magnitude of catalytic effect (kEtO-M+/kEtO-) was found to be 2.3, 9.5 and 8.7 for the reaction of 8-(5-nitroquinolyl) 2-furoate, while 1.4, 3.6 and 4.2 for that of 4-nitrophenyl 2-furoate, indicating that the catalytic effect is larger in the reaction of the former substrate than in that of the latter one. The larger catalytic effect was attributed to two possible complexing sites with alkali metal ions in the former substrate.

• Structural Monitoring and Maintenance
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• v.7 no.4
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• pp.295-317
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• 2020

Investigation of the stability of arch dam abutments is one of the most important aspects in the analysis of this type of dams. To this end, the Bakhtiari dam, a doubly curved arch dam having six wedges at each of its abutments, is selected. The seismic safety of dam abutments is studied through time history analysis using the design-based earthquake (DBE) and maximum credible earthquake (MCE) hazard levels. Londe limit equilibrium method is used to calculate the stability of wedges in abutments. The thrust forces are obtained using ABAQUS, and stability of wedges is calculated using the code written within MATLAB. Effects of foundation flexibility, grout curtain performance, vertical component of earthquake, nonlinear behavior of materials, and geometrical nonlinearity on the safety factor of the abutments are scrutinized. The results show that the grout curtain performance is the main affecting factor on the stability of the abutments, while nonlinear behavior of the materials is the least affecting factor amongst others. Also, it is resulted that increasing number of the contraction joints can improve the seismic stability of dam. A cap is observed on the number of joints, above which the safety factor does not change incredibly.

• Journal of Korean Society of Steel Construction
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• v.22 no.1
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• pp.33-42
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• 2010

Patterning with a geodesic line is essential for economical or efficient usage of membrane materialsin fabric tension membrane structural engineering and analysis. The numerical algorithm to determine the geodesic line for membrane structures is generally classified into two. The first algorithm finds a non-linear shape using a fictitious geodesic element with an initial pre-stress, and the other algorithm is the geodesic line cutting or searching algorithm for arbitrarily curved 3D surface shapes. These two algorithms are still being used only for the three-node plane stress membrane element, and not for the four-node element. The lack of a numerical algorithm for geodesic lines with four-node membrane elements is the main reason for the infrequent use of the four-node membrane element in membrane structural engineering and design. In this paper, a modified numerical algorithm is proposed for the generation of a geodesic line that can be applied to three- or four-node elements at the same time. The explicit non-linear static Dynamic Relaxation Method (DRM) was applied to the non-linear geodesic shape-finding analysis by introducing the fictitiously tensioned 'strings' along the desired seams with the three- or four-node membrane element. The proposed algorithm was used for the numerical example for the non-linear geodesic shape-finding and patterning analysis to demonstrate the accuracy and efficiency, and thus, the potential, of the algorithm. The proposed geodesic shape-finding algorithm may improve the applicability of the four-node membrane element for membrane structural engineering and design analysis simultaneously in terms of the shape-finding analysis, the stress analysis, and the patterning analysis.

• Water for future
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• v.14 no.1
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• pp.39-49
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• 1981

The purpose of this study is to examine the meander charactericstics for the rivers in Korea..In this study, the new characteristics factors of meander are proposed, and the relationships among the factors proposed in this study and the existing factors are derived. An attempt is made to find considerable relation among meander characteristics, but width and meander belt did not show any defined trend and considerable scatter of points was observed. Relationships among the meander length, belt and flowrate, etc., which are factors of meander characteristics, are analyzed the 67 rivers above 30km in length. Channel shape factor which is the ratio of the length from the starting point to the end to the channel lenght, tortuosity which is the ratio of the curved channel length against the channel length are suggested for a new characteristics factor of meander. They are well correlated with channel length, Horton's shape facotr and meander gradient, consequently have to be important measures of river meander. The result of the detailed comparison and the analysis of degree of sinuosity, velocity and water surface slop are brought light on the fact show that the curved reach is morestable than the straight one. The ratio of the meander length to the meander belt and its accumulative frequency showed excellent correlationship when plotted on the semi-log paper. The results of regression analysis of meander belt and meander length show linear for the South Han river branches and power curve for the Geum river and the Nakdong river branches.

• The Journal of The Korea Institute of Intelligent Transport Systems
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• v.16 no.3
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• pp.73-82
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• 2017

As of December 2016, the number of registered automobiles in Korea exceeds 21million. As a result, greenhouse gas emission by transportation sector are increasing every year. It was concluded that the development of the driving strategy considering the driving behavior and the road conditions, which are known to affect the fuel efficiency and the greenhouse gas emissions, could be the most effective fuel economy improvement. Therefore, this study aims to develop a fuel efficient driving strategy in a complex linear section with uphill and curved sections. The road topography was designed according to 'Rules about the Road Structure & Facilities Standards'. Various scenarios were selected. After generating the speed profile, it was applied to the Comprehensive Modal Emission Model and fuel consumption was calculated. The scenarios with the lowest fuel consumption were selected. After that, the fuel consumption of the manual driver's driving record and the selected optimal driving strategy were compared and analyzed for verification. As a result of the analysis, the developed optimal driving strategy reduces fuel consumption by 21.2% on average compared to driving by manual drivers.

• Tuberculosis and Respiratory Diseases
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• v.42 no.2
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• pp.218-225
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• 1995

Background: Airway resistance(Raw) is measured with the body plethysmograph by displaying the relationship between airflow and alveolar pressure($V/P_A$). If the resistance curve on $V/P_A$ tracing is curved or looped, the estimation of Raw is difficult. This study was designed to examine wheather there is any correlation between the shape of resistance curve and the clinical status and the pulmonary function of patients. Methods: The 146 pulmonary disease patients with increased Raw were included in this study. The shapes of resistance curves on $V/P_A$ tracing with body plethysmograph during quiet breathing were analyzed and compared with pulmonary function. Results: The results were as follows ; 1) The shapes of resistance curves were summarized in 5 categories; type 1: linear, type 2: ovoid, type 3: sigmoid, type 4: scoop, type 5: paisley. The type 3 except 1 case, type 4 and type 5 were found to have loop mainly in expiratory phase. 2) Although the shapes of resistance curves were not typical for specific disease, the resistance curves of acute disease tended to belong to type 1 or 2 and those of chronic airflow obstruction tended to belong to type 3, 4 or 5. But resistance curves of bronchial asthma and destructive lung with tuberculosis showed all types in proportion to degree of airflow obstruction or destruction of parenchyme. 3) In the cases of resistance curves going to type 5 rather than type 1 and those with looping, airflow obstuction tended to be severe and airway resistance and residual volume tended to increase. Conclusions: Analysis of resistance curve on $V/P_A$ tracing measuring airway resistance is helpful for judging degree of airflow obstruction and air trapping. Although the shape of resistance curve is not typical for specific disease, there is a close association between looping and airway obstruction.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.7
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• pp.4087-4092
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• 2014

The gangway connection of the articulated high speed railway vehicles (HSRV) is a double wrinkled rubber component to seal the air of the corridor under a range of angular deviations between the carriage end parts. From the results of non-linear structural analysis, one of the severe loading conditions for the connection is mixed mode (rolling+yawing) angular displacements while passing through the small-radius curved siding track of the HSRV depot. In this study, to ensure the safety enhancement of the component, the optimal design for the cross section of that was performed using the Solid Isotropic Material with Penalization (SIMP) method. Nonlinear finite element analysis confirmed that the decreases in the maximum principal strain of the optimized design under rolling and mixed modes are 68% and 39%, respectively, compared to the initial design.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.28 no.5
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• pp.344-349
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• 2015

A new information society of late has arrived by the rapid development of various information & communications technologies. Accordingly, mobile devices which are light and thin, easy and convenient to carry on the market. Also, the requirements for the larger television sets such as fast response speed, low-cost electric power, wider visual angle display are sufficiently satisfied. The currently most widely studied display material, the Organic Light-emitting Diodes(OLEDs) overwhelms the Liquid Crystal Display(LCD), the main occupier of the market. This new material features a response speed of more than a thousand times faster, no need of backlight, a low driving voltage, and no limit of view angle. And the OLEDs has high luminance efficiency and excellent durability and environment resistance, quite different from the inorganic LED light source. The OLEDs with simple device structure and easy produce can be manufactured in various shapes such as a point light source, a linear light source, a surface light source. This will surely dominate the market for the next generation lighting and display device. The new display utilizes not the glass substrate but the plastic one, resulting in the thin and flexible substrate that can be curved and flattened out as needed. In this paper, OLEDs device was produced by changing thickness of Teflon-AF of hole injection material layer. And as for the electrical properties, the four layer device of ITO/TPD/$Alq_3$/BCP/LiF/Al and the five layer device of ITO/Teflon AF/TPD/$Alq_3$/BCP/Lif/Al were studied experimentally.

• Radiation Oncology Journal
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• v.1 no.1
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• pp.29-36
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• 1983

The treatment of tumors along curved surfaces with stationary electron beams using cone collimation may lead to non-uniform dose distributions due to a varying air gap between the cone surface and patient. For large tumors, more than one port may have to be used in irradiation of the chest wall, often leading to regions of high or low dose at the junction of the adjacent ports. Electron-beam arc therapy may elimination many of these fixed port problems. When treating breast tumors with electrons, the energy of the internal mammary port is usually higher than that of the chest wall port. Bolus is used to increase the skin dose or limit the range of the electrons. We invertiaged the effect of various arc beam parameters in the isodose distributions, and combined into a single arc port for adjacent fixed ports of different electron beam eneries. The higher fixed port energy would be used as the arc beam energy while the beam penetration in the lower energy region would be controlled by a proper thickness of bolus. We obtained the results of following: 1. It is more uniform dose distribution of electron to use rotation than stationary irradiation. 2. Increasing isocenter depth on arc irradiation, increased depth of maximum dose, reduction in surface dose and an increasing penetration of the linear portion of the curve. 3. The deeper penetration of the depth dose curve and higher X-ray background for the smaller field sized. 4. If the isocenter depth increase, the field effect is small. 5. The decreasing arc beam penetration with decreasing isocenter depth and the isocenter depth effect appears at a greater depth as the energy increases. 6. The addition of bolus produces a shift in the penetration that is the same for all depths leaving the shape of the curves unchanged. 7. Lead strips 5 mm thick were placed at both ends of the arc to produce a rapid dose drop-off.

• Korean Journal of Applied Biomechanics
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• v.18 no.1
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• pp.203-212
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• 2008

The purpose of this study is to propose appropriate model for 3 staged Didimsae movement to Jajinmori rhythm and to provide information for ideal foot step movements. For the locational change of body center, the height of body center is lowered at the moment of forward step and during forward intersection of the feet, forward direction linear motion is converted to vertical motion to maintain stability. Speed change of body center reduces flow of body on step forward moment and controls rapid forward movement for stabled movement and position when preventing fast forward horizontal direction movement of centroid speed while knee joint and foot joint are vertically risen for heel bone contacts the ground. For angle changes of joints, in order to prevent hyperextension of lower leg, hip joint is extended and knee joint is curved to secure stability of movement for smooth curves and extension. When centroid of foot joint is moved from top of the feet to whole foot sole and when left foot makes dorsal curve, stabled movement is accomplished.