• Title/Summary/Keyword: Current Collector

Search Result 255, Processing Time 0.037 seconds

Improvement of Cycle Performance of Graphite-Silicon Monoxide Mixture Negative Electrode in Lithium-ion Batteries (흑연과 실리콘 일산화물의 혼합물로 구성된 리튬이온 이차전지용 음극의 사이클 성능개선 연구)

  • Kim, Haebeen;Kim, Tae Hun;Ryu, Ji Heon
    • Journal of the Korean Electrochemical Society
    • /
    • v.22 no.4
    • /
    • pp.155-163
    • /
    • 2019
  • Mixture electrodes of a graphite having a good cycle performance and a silicon monoxide (SiO) having a high capacity are fabricated and their cycle performances are evaluated as negative electrodes for lithium-ion batteries. The electrode prepared by mixing the natural graphite and carbon-coated SiO in a mass ratio of 9:1 shows a reversible capacity of $480mAh\;g^{-1}$, 33% higher than that of graphite. However, the capacity deteriorates continuously upon cycling due to the volume change of silicon monoxide. In this study, the factors that can improve the cycle performance have been discussed through the change in the configurations of the electrode and the electrolyte. The electrode using the carboxymethyl cellulose (CMC) binder shows the best cycle performance compared to the conventional binders. The electrode sing the CMC and styrene-butadiene rubber (SBR) binder not only has almost the similar cycle characteristics with the electrode using the CMC binder but also has the better rate capability. When the fluoroethylene carbonate (FEC) is used as an electrolyte additive, the cycle life is improved. However, the electrolyte with 5 wt% of FEC is appropriate because the rate capability decreases when the content of FEC is increased to 10 wt%. In addition, when the mass loading of the electrode is lowered, the cycle performance is greatly improved. Also, enhanced cycle performance is achieved using the roughened Cu current collector polished by abrasive paper.

Preparation and Electrochemical Properties of Freestanding Flexible S/CNT/NiO Electrodes for Li-S Batteries (리튬-황 전지용 프리스탠딩 플렉서블 S/CNT/NiO 전극의 제조 및 전기화학적 특성)

  • Shin, Yun Jung;Lee, Won Yeol;Kim, Tae Yun;Moon, Seung-Guen;Jin, En Mei;Jeong, Sang Mun
    • Korean Chemical Engineering Research
    • /
    • v.60 no.2
    • /
    • pp.184-192
    • /
    • 2022
  • Porous NiO synthesized via hydrothermal synthesis was used in the electrodes of lithium-sulfur batteries to inhibit the elution of lithium polysulfide. The electrode of the lithium-sulfur battery was manufactured as a freestanding flexible electrode using an economical and simple vacuum filtration method without a current collector and a binder. The porous NiO-added S/CNT/NiO electrode exhibited a high initial discharge capacity of 877 mA h g-1 (0.2 C), which was 125 mA h g-1 higher than that of S/CNT, and also showed excellent retention of 84% (S/CNT: 66%). This is the result of suppressing the dissolution of lithium polysulfide into the electrolyte by the strong chemical bond between NiO and lithium polysulfide during the charging and discharging process. In addition, for the flexibility test of the S/CNT/NiO electrode, the 1.6 × 4 cm2 pouch cell was prepared and exhibited stable cycle characteristics of 620 mA h g-1 in both the unfolded and folded state.

Enhanced Performance in a Lithium-ion Battery via the Crystal-aligned LiNi0.6Mn0.2Co0.2O2 and the Relevant Electrochemical Interpretation (결정배향 LiNi0.6Mn0.2Co0.2O2 전극활물질을 통한 리튬이차전지 성능 향상 및 이의 전기화학적 해석)

  • Cham, Kim
    • Journal of the Korean Chemical Society
    • /
    • v.66 no.6
    • /
    • pp.451-458
    • /
    • 2022
  • Through the crystal alignment research based on the magnetic properties of LiNixMnyCo1-(x+y)O2 such as magnetic susceptibility and related anisotropy, a crystal aligned LiNi0.6Mn0.2Co0.2O2 electrode is obtained, in which the (00l) plane is frequently oriented perpendicular to the surface of a current collector. The crystal aligned LiNi0.6Mn0.2Co0.2O2 electrode steadily exhibits low electrode polarization properties during the charge/discharge process in a lithium-ion battery, thus affording an improved capacity compared to a pristine LiNi0.6Mn0.2Co0.2O2 electrode. The aligned LiNi0.6Mn0.2Co0.2O2 electrode may have an appropriate structural nature for fast lithium-ion transport due to the oriented (00l) plane, and thus it contributes to enhancing the battery performance. This enhancement is analyzed in terms of various electrochemical theories and experiment results; thus, it is verified to occur because of the considerably fast lithium-ion transport in the aligned LiNi0.6Mn0.2Co0.2O2 electrode.

Trend Analysis of Latest Technology and Market for Commercialization of an Attached Photovoltaic-thermal Module (부착형 태양광열 모듈의 상용화를 위한 최신기술 및 시장 동향 분석)

  • Sangmu Bae;Hobyung Chae;Jinhwan Oh;Jeong-Heum Cho;SangHeon Jeong;Namjin Lyu;Yujin Nam
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
    • /
    • v.19 no.1
    • /
    • pp.14-25
    • /
    • 2023
  • In order to overcome the limitations of the individual renewable energy technologies such as photovoltaic (PV) and solar-thermal and effectively realize zero energy buildings, the photovoltaic-thermal (PVT) technology is being proposed. The current PVT module was simply combined with a PV panel and a solar-thermal collector. Therefore, it was difficult to commercialize because the PVT module is heavy and has no significant advantages compared to applying the individual technology. In this study, an attached PVT module is proposed for the commercialization and securing competitiveness in the renewable energy market. The attached PVT module enables on-site work with a simplified manufacturing process and can significantly reduce the supply price of the product. Moreover, it can be easily applied on already installed the PV panels. This study aims to commercialize the attached PVT module, the basic data was established as follows: (1) latest technology related to PVT module, (2) Global trends of the PVT module market. The possibility of commercialization of the attached PVT module was reviewed based on the results of the latest technology and market trends analysis. The supply price of the attached PVT module is lower than the existing products and it is considered that there is a high possibility of commercialization and introduction market with the advantage such as utilizing the existing PV industry and market. Moreover, the attached PVT module can be produced simultaneously the thermal and electrical energy, and it can be presented as an innovative alternative that can respond to the energy demand for residential sector.

Recent Progress in Air-Conditioning and Refrigeration Research: A Review of Papers Published in the Korean Journal of Air-Conditioning and Refrigeration Engineering in 2011 (설비공학 분야의 최근 연구 동향: 2011년 학회지 논문에 대한 종합적 고찰)

  • Han, Hwa-Taik;Lee, Dae-Young;Kim, Seo-Young;Choi, Jong-Min;Paik, Yong-Kyoo;Kim, Su-Min
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
    • /
    • v.24 no.6
    • /
    • pp.521-537
    • /
    • 2012
  • This article reviews the papers published in the Korean Journal of Air-Conditioning and Refrigeration Engineering during 2011. It is intended to understand the status of current research in the areas of heating, cooling, ventilation, sanitation, and indoor environments of buildings and plant facilities. Conclusions are as follows. (1) Research trends of thermal and fluid engineering have been surveyed as groups of fluid machinery and fluid flow, thermodynamic cycle, and new and renewable energy. Various topics were presented in the field of fluid machinery and fluid flow. Research issues mainly focused on the rankine cycle in the field of thermodynamic cycle. In the new and renewable energy area, researches were presented on geothermal energy, fuel cell, biogas, reformer, solar water heating system, and metane hydration. (2) Research works on heat transfer area have been reviewed in the categories of heat transfer characteristics, pool boiling and condensing heat transfer, nanofluids and industrial heat exchangers. Researches on heat transfer characteristics included heat transfer above liquid helium surface in a cryostat, methane hydrate formation, heat and mass transfer in a liquid desiccant dehumidifier, thermoelectric air-cooling system, heat transfer in multiple slot impinging jet, and heat transfer enhancement by protrusion-in-dimples. In the area of pool boiling and condensing heat transfer, researches on pool boiling of water in low-fin and turbo-B surfaces, pool boiling of R245a, convective boiling two-phase flow in trapezoidal microchannels, condensing of FC-72 on pin-finned surfaces, and natural circulation vertical evaporator were actively performed. In the area of nanofluids, thermal characteristics of heat pipes using water-based MWCNT nanofluids and the thermal conductivity and viscosity were measured. In the area of industrial heat exchangers, researches on fin-tube heat exchangers for waste gas heat recovery and Chevron type plate heat exchanger were implemented. (3) Refrigeration systems with alternative refrigerants such as $CO_2$, hydrocarbons, and mixed refrigerants were studied. Heating performance improvement of heat pump systems were tried applying supplementary components such as a refrigerant heater or a solar collector. The effects of frost growth were studied on the operation characteristic of refrigeration systems and the energy performance of various defrost methods were evaluated. The current situation of the domestic cold storage facilities was analyzed and the future demand was predicted. (4) In building mechanical system fields, a variety of studies were conducted to achieve effective consumption of heat and maximize efficiency of heat in buildings. Various researches were performed to maximize performance of mechanical devices and optimize the operation of HVAC systems. (5) In the fields of architectural environment and energy, diverse purposes of studies were conducted such as indoor environment, building energy, and renewable energy. In particular, renewable energy and building energy-related researches have mainly been studied as reflecting the global interests. In addition, various researches have been performed for reducing cooling load in a building using spot exhaust air, natural ventilation and energy efficiency systems.