• Journal of the Korean Wood Science and Technology
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• v.34 no.2
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• pp.37-45
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• 2006

The viscoelastic properties of blends of melamine-formaldehyde (MF) resin and poly(vinyl acetate) (PVAc) for engineered flooring used on the Korean traditional ONDOL house floor heating system were investigated by dynamic mechanical thermal analysis (DMTA). Because MF resin is a thermosetting adhesive, the effect of MF rein was shown across all thermal behaviors. The addition of PVAc reduced the curing temperature. The DMTA thermogram of MF resin showed that the storage modulus (E') increased as the temperature was further increased as a result of the cross-linking induced by the curing reaction of the resin. The storage modulus (E') of MF resin increased both as a function of increasing temperature and with increasing heating rate. From isothermal DMTA results, peak $T_{tan{\delta}}$ values, maximum value of loss modulus (E") and the rigidities (${\Delta}E$) of MF/PVAc blends at room temperature as a function of open time, peak $T_{tan{\delta}}$ and maximum loss modulus (E") values were found to increase with blend MF content. Moreover, the rigidities of the 70:30 and 50:50 MF/PVAc blends were higher than those of the other blends, especially of 100% PVAc or MF. We concluded that blends the MF/PVAc blend ratios correlate during the adhesion process.

• Computers and Concrete
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• v.13 no.1
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• pp.31-47
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• 2014

This research is focused on obtaining the fracture property of steel fiber reinforced concrete(SFRC) specimens at early ages of 1, 2, 3 and 7-day, respectively. For this purpose, three point bending tests of nine groups of SFRC beams with notch of 40mm depth and different steel fiber ratios were conducted. The experimental results of early age specimens were compared with the 28-day hardened SFRC specimens. The test results indicated that the steel fiber ratios and curing age significantly influenced the fracture properties of SFRC. A reasonable addition of steel fiber improved the fracture toughness of SFRC, while the fracture energy of SFRC developed with curing age. Moreover, a quadratic relationship between splitting strength and fracture toughness was established based on the experiment results. Additionally, afinite element (FE) method was used to investigate the fracture properties of SFRC.A comparison between the FE analysis and experiment results was also made. The numerical analysis fitted well with the test results, and further details on the failure behaviors of SFRC could be revealed by the suggested numerical simulation method.

• Macromolecular Research
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• v.16 no.6
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• pp.561-566
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• 2008

NR composites with different curing systems were aged thermally at 60, 70, 80, and $90^{\circ}C$ for 2-185 days in a convection oven, and the changes in the crosslink density were investigated as a function of the accelerated thermal aging. The overall crosslink densities increased with increasing aging time irrespective of the aging temperatures and curing systems. The changes in crosslink density were enhanced by increasing the aging temperature. The degree of the increased crosslink density was in the following order: "the conventional cure system > the semi-EV system > the EV system". For short term thermal aging, the change in crosslink density with the aging time was complicated, particularly for low temperature aging. The activation energies of the change in crosslink density with thermal aging using the conventional and semi-EV cure systems increased and then remained relatively constant with increasing aging time, whereas that of the specimen with an EV cure system tended to increase linearly. The experimental results were explained by the dissociation of the existing polysulfidic linkages and the formation of new cross links through the crosslinking-related chemicals remaining in the sample.

• Korean Journal of Materials Research
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• v.22 no.9
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• pp.454-458
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• 2012

Various adhesive materials are used in flip chip packaging for electrical interconnection and structural reinforcement. In cases of COF(chip on film) packages, low temperature bonding adhesive is currently needed for the utilization of low thermal resistance substrate films, such as PEN(polyethylene naphthalate) and PET(polyethylene terephthalate). In this study, the effects of anhydride and dihydrazide hardeners on the low-temperature snap cure behavior of epoxy based non-conductive pastes(NCPs) were investigated to reduce flip chip bonding temperature. Dynamic DSC(differential scanning calorimetry) and isothermal DEA(dielectric analysis) results showed that the curing rate of MHHPA(hexahydro-4-methylphthalic anhydride) at $160^{\circ}C$ was faster than that of ADH(adipic dihydrazide) when considering the onset and peak curing temperatures. In a die shear test performed after flip chip bonding, however, ADH-containing formulations indicated faster trends in reaching saturated bond strength values due to the post curing effect. More enhanced HAST(highly accelerated stress test) reliability could be achieved in an assembly having a higher initial bond strength and, thus, MHHPA is considered to be a more effective hardener than ADH for low temperature snap cure NCPs.

• Polymer(Korea)
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• v.26 no.4
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• pp.501-507
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• 2002

In this work, diglycidylether of bisphenol-S (DGEBS) epoxy resin was prepared by alkaline condensation of bisphenol-S (BPS) with epichlorohydrin (ECH) in the presence of NaOH catalyst. The structure of the synthesized DGEBS epoxy resin was confirmed by IR, NMR spectra, and elemental analysis. The curing reaction and glass transition temperature ($T_g$) of DGEBS epoxy resin cured with phthalic anhydride (PA) and tetrahydrophthalic anhydride (THPA) at curing agents were studied by dynamic differential scanning calorimetry (DSC). The thermal stability of the cured specimen was investigated by thermogravimetric analysis (TGA). As a result, the activation energy ($E_a$) of DGEBS/PA system was higher than that of DGEBS/THPA system, whereas $T_g$, initial decomposed temperature (IDT), and decomposition activation energy ($E_t$) of DGEBS/PA were lower than those of DGEBS/THPA. This was probably due to the fact that the crosslinking density of DGEBS/THPA was increased by ring strain of curing agent.

• Composites Research
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• v.20 no.6
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• pp.8-14
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• 2007

Debonding failure characteristics of the composite skin-stiffener specimens were experimentally investigated. The influences of bonding methods, types of stiffener shape and various secondary bonding parameters were evaluated. Present test results combined with the previous test results[1] showed that the failure displacement of the skin-stiffener specimens well evaluates the skin-stiffener debonding failure strength of the composite stiffened panels. The specimens with an open type stiffener had lower bending stiffness and larger failure displacement than those with a closed type stiffener. Secondary bonding and co-curing with adhesive had better failure strength than co-curing without adhesive film. Secondary bonded specimens failed by adhesive failure and co-cured specimens failed by delamination failure. As the bondline thickness was thinner, the skin-stiffener specimens had higher failure strength. The fillets had no influence on failure strength of the specimens. The influence of the surface roughness was shown according to types of stiffener shape.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2002.10a
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• pp.265-268
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• 2002

In this work, the blend system of epoxy and PMR-15 polyimide is investigated in terms of the cure behaviors and thermal stabilities. The cure behaviors are studied in DSC measurements and thermal stabilities are also carried out by TGA analysis. DDM (4, 4'-diamino diphenyl methane) is used as curing agent for EP and the content of PMR-15 is varied within 0, 5, 10, 35, and 20 phr to neat EP. As a result, the cure activation energy ($E_a$) is increased at 10 phr of PMR-15, compared with that of neat EP. From the TGA results of EP/PMR-15 blend system, the thermal stabilities based in the initial decomposed temperature (IDT) and integral procedural decomposition temperature (IPDT) are increased with increasing the PMR-15 content. The fracture toughness, measured in the context of critical stress intensity factor ($K_{IC}$) and critical strain energy release rate ($G_{IC}$), shows a similar behavior with $E_a$. This result is probably due to the crosslinking developed by the interactions between intermolecules in the polymer chains.

• Magazine of the Korea Concrete Institute
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• v.6 no.3
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• pp.152-161
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• 1994

Most widened bridges have been constructed by the joining-construction method that makes new and existing bridges structurally a single structure. Since the joining-construction method has several problems in design and construction viewpoint, this study is conducted in order to investigate the structural behaviors of RC slabs, which are widened and influenced by traffic-induced vibration of existing bridge during placing and curing of new concrete, with the prototype flexural strength test and FEM analysis. It was found that cracks are generated in construction joint at low applied load and that stress concentration at the joints and slips between steel bar and concrete are occured. But, the decreasing of load carrying capacity is negligible according to the traffic-induced vibration as well as the difference of construction method.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.34 no.3
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• pp.37-43
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• 2006

Six types of hat stiffened composite panels were manufactured with different bonding methods and stiffener section shapes and compression testing of these panels were performed. The panels showed similar behaviors in bucking and postbuckling region before a skin-stiffener separation failure occurred. Although all the separation failures occurred at the same locations of stiffener flanges close by skin buckling crests, the separation loads, separation failure growth behaviors and final collapse loads were different with respect to bonding methods and stiffener section shapes. As the separation failure initiated early and propagated larger area, collapse loads and structural efficiency of the panels decreased.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2014.11a
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• pp.197-198
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• 2014

The concrete work of bridge decks is performed in a high place, which may reduce safety and productivity. In addition, the conventional method for deck forms require a great deal of manpower, and a form (sheathing) board is damaged when removed after curing. As a result, the concrete deck work of bridge construction becomes the cause of delayed construction and increased cost. To solve these problems, SMART form, a system form, is developed. SMART form is a temporary device for easier installation and removal, by mounting it to the lower flange of a bridge girder and using a mechanical behavior of the form system for deck concrete pouring. For stable installation and removal of the developed SMART form, geometric behaviors should be analyzed to prove its validity. Furthermore, the validity of geometric behaviors when the SMART form size is altered in response to the various arrangement of bridge girders should be proved. Thus, the study is intended to analyze the geometric validity of the form system for bridge deck concrete pouring. The structural stability of the form system for bridge deck concrete pouring can be secured, which will be applied in the field.