• Bulletin of the Korean Chemical Society
• /
• 제16권4호
• /
• pp.326-331
• /
• 1995

Poly(enaryloxynitriles) containing Schiff bases were prepared from p-bis(1-chloro-2,2-dicyanovinyl)benzene (2) and various aromatic diols having Schiff base moiety by interfacial polymerization. The chemical structure of the polymers was confirmed through synthesis of their corresponding model compounds. All the polymers were soluble in polar aprotic solvents and their brittle films were cast from DMF solution. They showed a large exotherm around 340 ℃ attributable to the chemical change of dicyanovinyl group. Especially, curing of azomethine group was observed to occur at 390 ℃ by differential scanning calorimetry. According to the thermogravimetric analyses, they exhibited excellent thermal stability with 60-90% residual weight at 500 ℃ in nitrogen.

• 한국화재소방학회:학술대회논문집
• /
• 한국화재소방학회 2008년도 추계학술논문발표회 논문집
• /
• pp.428-433
• /
• 2008

The strength capacity properties of concrete are much influenced by water content which has a significant effect on concrete spalling, especially, in high temperature areas. Therefore, the properties of the material's shall be closely examined first by measuring the water content in each material in order to analyze Concrete Fire Characteristics, and a reliable measuring method shall be presented in order to derive the following influence. The method used to measure the water content within concrete is mainly divided into 4 types; ASTM method, Nuclear Magnetic method, Ultrasonic measurement method, Radio Wave method, etc. It is essential to use a reliable measuring method for each experiment. In this experiment, we measured the water content and humidity of concrete by two methods; Relative/Absolute humidity method using VISALA HM44 measuring equipment which is easily measurable compared with other methods regardless of the shape of the experimental model, and a water content measuring experiment using ASTM C 566. If the aggregates are under the condition that their surface is dry but in saturation, there is no change of water content according to concrete curing methods. However if the aggregates are absolutely dry, the water content is significantly changed according to concrete curing methods.

• 한국건설순환자원학회논문집
• /
• 제7권4호
• /
• pp.121-127
• /
• 2012

본 연구에서는 플라이애시를 치환한 시멘트 모르터의 양생온도에 따른 강도증진을 검토하기 위하여 등가재령방법에 의한 강도증진해석을 실시하였다. 플라이애시를 30% 치환한 시멘트모르터의 겉보기활성화에너지를 ASTM C 1074 방법에 의하여 산정한 결과 34.75KJ/mol로 산정되었고, 이를 토대로 Plowman 모델과 Gompertz 모델을 이용하여 해석한 결과 해석치가 측정치를 양호하게 추정함을 알 수 있었고 특히 Gompertz 모델식이 보다 양호한 추정 정밀도를 갖는 것으로 확인되었다.

• 한국정밀공학회지
• /
• 제22권3호
• /
• pp.162-169
• /
• 2005

The functional external fixator system fur bone deformity near joints in legs using the worm gear was developed for curing the difference angles in fracture bone and the lengthening bar for curing the difference length in fracture bone. Both experiments and FE analysis were performed to compare the elastic stiffness in several loading modes and to improve the functional external fixator system for the bone deformity. The FE model using the compressive and bending FE analysis was applied to the FE analysis due to the angle differences. The results show that the compressive stiffness value in experiment was 175.43N/mm; the bending stiffness value in experiment was 259.74N/mm; compressive stiffness value in FEM was 188.67N/mm; bending stiffness value in FEA was 285.71N/mm. The errors between experiments and FEA were less than 10%. The maximum stress (157MPa) to the angle of clamp was lower than the yield stress (176.4MPa) of SUS316L. The stiffnesses in both axial compressive and bending of the new fixator are about 2 times higher than other products except EBI (2003).

• 한국정밀공학회:학술대회논문집
• /
• 한국정밀공학회 2004년도 추계학술대회 논문집
• /
• pp.1248-1251
• /
• 2004

The functional external fixator system for bone deformity near joints in legs using the worm gear was developed for curing the difference angles in fracture bone and the lengthening bar for curing the difference length in fracture bone. Both experiments and FE analysis were performed to compare the elastic stiffness in several loading modes and to improve the functional external fixator system for bone deformity near joints in legs. The FE model using the compressive and bending FE analysis was applied the FE analysis due to the angle differences. The results show that the compressive stiffness value in experiment was 175.43N/mm, the bending stiffness value in experiment was 259.74N/mm, compressive stiffness value in FEM was 188.67N/mm, bending stiffness value in FEA was 285.71N/mm. The errors between experiments and FEA were less than 10％. The maximum stress (157MPa) to the angle of clamp was lower than the yield stress (176.4MPa) of SUS316L. The stiffnesses in both axial compressive and bending of the new fixator are about 2 times higher than other products except EBI (2003).

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 2001년도 가을 학술발표회 논문집
• /
• pp.445-450
• /
• 2001

The paper investigates the relationships between dynamic elastic modulus and static elastic modulus or compressive strength according to curing temperature, aging, and cement type. Based on this investigation, the new model equations are proposed. Impact echo method estimates the resonant frequency of specimens and uniaxial compression test measures the static elastic modulus and compressive strength. Type I and V cement concretes, which have the water-cement ratios of 0.40 and 0.50, are cured under the isothermal curing temperature of 10, 23, and 50 $^{\circ}C$. Cement type and aging have no large influence on the relationship between dynamic and static elastic modulus, but the ratio of dynamic and static elastic modulus comes close to 1 as temperature increases. Initial chord elastic modulus, which is calculated at lower strain level of stress-strain curve, has the similar value to dynamic elastic modulus. The relationship between dynamic elastic modulus and compressive strength has the same tendency as the relationship between dynamic and static elastic modulus. The proposed relationship equations between dynamic elastic modulus and static elastic modulus or compressive strength properly estimates the variation of relationships according to cement type, temperature, and aging.

• Design & Manufacturing
• /
• 제8권2호
• /
• pp.46-49
• /
• 2014

Silicone is recently used for LED chip lense due to its good thermal stability and optical transmittance. In order to predict residual stress which causes optical briefringence and mechanical warpage of silicone, finite element analysis was conducted for curing process during silicone molding. For analysis of curing process, a dynamic cure kinetics model was derived based on the differential scanning calorimetry(DSC) test and applied to the material properties for finite element analysis. Finite element simulation result showed that the slow cure reduced abrupt reaction heat and it was predicted decrease of the residual stress.

• 한국지반공학회:학술대회논문집
• /
• 한국지반공학회 2008년도 춘계 학술발표회 초청강연 및 논문집
• /
• pp.754-761
• /
• 2008

In general, stress measurement of existent shotcrete lining be used by pressure cells. but, measuring instrument is lost by high pressure at shotcrete lining construction and pressure cell's measurement value have to low believability by natural conditions like curing temperature. In this study, proposed techniques to measure without utilizing sensitive stress sensor in natural condition at point that want stress of shotcrete lining after shotcrete lining construction. Executed numerical analysis to forecast stress level that interact in tunnel shotcrete lining, measured strain of hole by load action through hole in shotcrete lining. 3D FEM(finite element method) is enforced through various parameters curing time of shotcrete lining, thickness, load condition. Different model cases applied by parametic study. As analysis result, it could grasp development possibility of method that propose this time because it could examine corelation with strain by near hole of shotcrete lining and stress about load condition.

• 한국정밀공학회지
• /
• 제28권2호
• /
• pp.219-225
• /
• 2011

Silicone resin is recently used as encapsulant for high-power LED module due to its excellent thermal and optical properties. In the present investigation, finite element analysis of cure process was attempted to examine residual stress evolution behavior during silicone resin cure process which is composed of chemical curing and post-cooling. To model chemical curing of silicone, a cure kinetics equation was evaluated based on the measurement by differential scanning calorimeter. The evolutions of elastic modulus and chemical shrinkage during cure process were assumed as a function of the degree of cure to examine their effect on residual stress evolution. Finite element predictions showed how residual stress in cured silicone resin can be affected by elastic modulus and chemical shrinkage behavior. Finite element analysis is supposed to be utilized to select appropriate silicone resin or to design optimum cure process which brings about a minimum residual stress in encapsulant silicone resin.

• Korea-Australia Rheology Journal
• /
• 제16권4호
• /
• pp.175-182
• /
• 2004

Colloidal coating solution was prepared to enhance the hydrophilic property of the film surface. Water and ethanol were used as the dispersion media and (glycidoxypropyl) trimethoxysilane (GPS) as a binder in the colloidal silica coatings. Ethylene diamine was added to the colloidal silica solution as the curing agent. The colloidal silica solution was regarded as a hard-sphere suspension model with low volume fraction of the silica particles. Rheological properties of the silica suspensions modified with GPS have been investigated as a function of pH and concentration. The acidic solution showed high viscosity change by fast hydrolysis reaction and adsorption of the organic binders on the surface of silica particles. However, the hydrolysis was slow at the basic condition and the binders combined with themselves by condensation. The viscosity change was smallest at pH 7. The viscosity increased with the curing time after adding ethylenediamine, and the increase of viscosity at low pH was higher than that at high pH. The hydrophilic properties of the coating film were investigated by the contact angle of water and film surface. The smallest contact angle was shown under the strong acidic condition of pH 2.