• Title/Summary/Keyword: CuZn

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ZnS:Mn/Cu,Cl계 나노 형광체 EL의 발광 특성 연구

  • Kum, Jeong-Hun;Lee, Seong-Eui
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.291-291
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    • 2009
  • ZnS:Mn/Cu,Cl 계 나노 형광체의 특성을 살펴보았다. 실험에서는 ZnS:Mn 과 ZnS:Cu,Cl 형광체 파우더를 이용하여 밀링을 통하여 분쇄하여 EL 소자를 제작하였다. 형광체 파우더를 볼밀에 $\Phi5mm$의 지르코나이 볼과 에탄올과 함께 넣고 2, 4, 6, 8, 10일간 밀링을 하였다. 밀링한 형광체 파우더를 SEM을 통하여 파우더의 사이즈를 관찰하였다. 또 이 파우더를 이용하여 EL 소자를 제작하였다. 소자의 구조는 기판은 알루미나 기판을, 하부 전극은 Au, 유전체는 $BaTiO_3$ 유전체 페이스트를 사용하였으며, 형광체 적층 후 ITO 전극을 스퍼터를 이용하여 증착하여 제작하였다. 제작한 소자를 이용하여 소자의 휘도 등 발광 특성을 살펴보았다.

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Co Gas Sensing Property of ZnO/CuO Hetero-Contact Ceramics (ZnO와 CuO의 접촉형 세라믹스의 일산화탄소 가스 감응특성)

  • 전석택;최경만
    • Journal of the Korean Ceramic Society
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    • v.29 no.7
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    • pp.565-571
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    • 1992
  • Gas sensing properties of P-N contact ceramics, composed of ZnO and CuO pairs sintered at different temperatures, were studied for 1% CO gas. Between 10$0^{\circ}C$ and 32$0^{\circ}C$ temperature range, it was observed that 2-probe current-voltage (I-V) characteristics, temperature and voltage dependence of sensivities were dependant largely upon ZnO samples. Pairs including a ZnO sample sintered at 110$0^{\circ}C$ showed maximum senitivity of 9 and 13 depending upon counterpart CuO samples, at 260~29$0^{\circ}C$. On the other hand, pairs including a ZnO samples sintered at 90$0^{\circ}C$ showed increasing sensitivity within in the measured temperature range and maximum sensitivities were about 4.

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Microstructure of $\textrm{Zn}_{1-x}\textrm{Fe}_{x}\textrm{Se}$ Epilayers Grown by Molecular Beam Epitaxy (MBE에 의해 성장된 $\textrm{Zn}_{1-x}\textrm{Fe}_{x}\textrm{Se}$ 반도체 박막의 미세구조)

  • Park, Gyeong-Sun
    • Korean Journal of Materials Research
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    • v.7 no.9
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    • pp.805-810
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    • 1997
  • MBE에 의해 성장된 Zn$_{1-x}$ Fe$_{x}$Se박막의 미세구조가 고분해능 투과전자현미경에 의해 연구되었다.Zn$_{1-x}$ Fe$_{x}$Se 박막에서 CuAu-l과 CuPt의 규칙격자가 발견되었다. 이 규칙격자는 전자 회절과 단면 고분해능 격자 이미지에 의해 조사되었다.CuAu-l규칙격자는 (001)InP기판 위에 성장된 Zn$_{1-x}$ Fe$_{x}$Se(x=0.43)에서 관찰되었고, 반면에 CuPt규칙격자는 (001)GaAs기판 위에 성장된 Zn$_{1-x}$ Fe$_{x}$Se(x=0.43)에서 관찰되었다.43)에서 관찰되었다.

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Removal of Mixed Cd, Cr, Cu, Ni and Zn by Hibiscus canabinas (Hibiscus canabinas를 이용한 Cd, Cr, Cu, Ni 및 Zn의 제거)

  • 최문술;임철호
    • Korean Journal of Environmental Biology
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    • v.22 no.1
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    • pp.120-126
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    • 2004
  • Kenaf plants were hydroponically grown in reactor containing toxic metals as Cd, Cu, Cr, Ni and Zn to examine the ability to take up heavy metal. The plants were fertilized using a nutrient solution, which was appropriately adjusted to optimum pH, DO and conductivity. For n hydraulic retention time of 8 days, Cr, Cd, Cu, Ni and Zn were removed up to 90.5, 80.5, 66.1%, 71.1% and 79.4%, and reduced from 2.34 to 0.54 mg $L^{-1}$, 3.37 to 1.07 mg $L^{-1}$, 4.92 to 3.19 mg $L^{-1}$, 6.31 to 4.41 mg $L^{-1}$ and 6.27 to 2.09 mg $L^{-1}$. Especially, accumulation rate of Cr, Cd, Cu, Ni and Zn in the plant were measured up to 347.32, 275.39, 157.52, 50.48 and 211.01 mg DW kg $L^{-1}d^{-1}$, respectively. We considered that Kenaf plants removed Cr, Cd and Zn more effectively than other toxic metals applied.

Age-Hardening Behavior of AuCu-Zn Alloys (AuCu-Zn합금의 시효경화거동)

  • Choe, Seok-Gyu;Shiraishi, Takanobu;Kim, Hyeong-Il;Ohta, Michio;Nakagawa, Masaharu
    • Korean Journal of Materials Research
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    • v.6 no.2
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    • pp.235-241
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    • 1996
  • 등온자비 AuCu에 2.4, 4.3, 6.1at% Zn이 첨가된 합금의 시효경화거동과 상변태를 조사하였다. AuCu l형이 단독으로 존재하는 경우는 경도가 시효초기에 급격히 상승한 후 저하하였고, Zn 첨가량의 증가에 따라 규칙-불규칙 전이온도(Tc)가 약간 하강하였지만, AuCu l형+AuCu ll형의 공존영역의 온도는 훨씬 낮아졌다.

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Effect of Cu concentration on the luminescence of ZnS:Cu,Cl blue-green phosphor

  • Cho, Tai-Yeon;Lee, Hak-Soo;Han, Sang-Do;Gwak, Ji-Hye;Shin, Dong-Hyuk;Han, Chi-Hwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1537-1538
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    • 2007
  • ZnS:Cu,Cl phosphor was synthesized by solid-liquid state reaction with two firing steps. Each stage of the process was carefully monitored so that the final product was comparable to commercially-available phosphor. The effect of $Cu^{2+}-doping$ concentration has been investigated on the luminescence characteristics of ZnS:Cu,Cl blue-green phosphors for inorganic electroluminescent device.

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$SiO_2$ coating of ZnS:Cu,Cl blue-green nano phosphor

  • Lee, Hong-Ro ;Park, Chang-Hyun ;Cho, Tai-Yeon;Han, Sang-Do
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2007.11a
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    • pp.75-76
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    • 2007
  • ZnS:Cu,Cl phosphor was coated by solid-gel reaction with $SiO_2$ outside layer. The effect of $Cu^{2+}$-doping concentration has been investigated on the luminescence characteristics of ZnS:Cu,Cl blue-green phosphors for inorganic electro luminescent device. Also, SiO2 coated layers' effect on luminescence characteristics. Evaluation of luminescence characteristics dependent on the synthesis conditions is important to get high-performance phosphors properties. EL and PL properties such as luminescence intensity and chromaticity of ZnS:Cu,Cl phosphors synthesized with different concentration of activator, $Cu^{2+}$, were analysed separately

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Enhanced Catalytic Activity of Cu/Zn Catalyst by Ce Addition for Low Temperature Water Gas Shift Reaction (Ce 첨가에 따른 저온수성가스전이반응용 Cu/Zn 촉매의 활성 연구)

  • Byun, Chang Ki;Im, Hyo Bin;Park, Jihye;Baek, Jeonghun;Jeong, Jeongmin;Yoon, Wang Ria;Yi, Kwang Bok
    • Clean Technology
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    • v.21 no.3
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    • pp.200-206
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    • 2015
  • In order to investigate the effect of cerium oxide addition, Cu-ZnO-CeO2 catalysts were prepared using co-precipitation method for water gas shift (WGS) reaction. A series of Cu-ZnO-CeO2 catalyst with fixed Cu Content (50 wt%, calculated as CuO) and a given ceria content (e.g., 0, 5, 10, 20, 30, 40 wt%, calculated as CeO2) were tested for catalytic activity at a GHSV of 95,541 h-1, and a temperature range of 200 to 400 ℃. Cu-ZnO-CeO2 catalysts were characterized by using BET, SEM, XRD, H2-TPR, and XPS analysis. Varying composition of Cu-ZnO-CeO2 catlysts led the difference characteristics such as Cu dispersion, and binding energy. The optimum 10 wt% doping of cerium facilitated catalyst reduction at lower temperature and improved the catalyst performance greatly in terms of CO conversion. Cerium oxide added catalyst showed enhanced activities at higher temperature when it compared with the catalyst without cerium oxide. Consequently, ceria addition of optimal composition leads to enhanced catalytic activity which is attributed to enhanced Cu dispersion, lower binding energy, and hindered Cu metal agglomeration.

Synthesis and Structural Properties of YBa2Cu3O7-x Films/ZnO Nanorods on SrTiO3 Substrates

  • Jin, Zhenlan;Park, C.I.;Song, K.J.;Han, S.W.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.169-169
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    • 2012
  • The high-temperature superconductor YBa2Cu3O7-x (YBCO) have attached attentions because of a high superconducting transition temperature, low surface resistance, high superconducting critical current density (Jc), and superior superconducting capability under magnetic field. Moreover, the Jc of YBCO superconductors can be enhanced by adding impurities to the YBCO films for vortex-pinning. Understanding and controlling pinning centers are key factors to realize high Jc superconductors. We synthesized vertically-aligned ZnO nanorods on SrTiO3 (STO) substrates by catalyst-free metal-organic chemical vapor deposition (MOCVD), and subsequently, deposited YBCO films on the ZnO nanorods/STO templates using pulsed laser deposition (PLD). The various techniques were used to analyze the structural and interfacial properties of the YBCO/ZnO nanorods/STO hybrid structures. SEM, TEM, and XRD measurements demonstrated that YBCO films on ZnO nanorods/STO were well crystallized with the (001) orientation. EXAFS measurements from YBCO/ZnO nanorods/STO at Cu K edge demonstrated that the local structural properties around Cu atoms in YBCO were quite similar to those of YBCO/STO.

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Experimental Study on the Accumulation of Cadmium and Other Metals in the Fish Bodies(Oryzias latipes) (송사리(Oryzias latipes)의 생체내 카드뮴 및 미량금속의 축적에 관한 실험적 연구)

  • 조영채;송인순;박상환
    • Journal of Environmental Health Sciences
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    • v.26 no.3
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    • pp.25-31
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    • 2000
  • In order to assess the accumulation levels of cadmium and other metals(Zn, Cu, Ca and Fe) in fish bodies, an experimental study was performed by raising fry of "Oryzias latipes" in the water containing cadmium 0.03 ppm, cadmium 0.03 ppm + zinc 0.03 ppm and in the tap water(control group) were made. In the results the concentration of Cd in fish bodies were increased with advancing exposure time in Cd 0.03 ppm treated group and 0.03 ppm + Zn 0.03 ppm treated group, but there was no significantly different between both groups with Cd concentration in each week. The concentration of Zn in fish bodies was no changed with advancing exposure time in control group and Cd 0.03 ppm + Zn 0.03 ppm treated group were significantly different from control and Cd 0.03 ppm treated group. The concentration of Cu, Ca and Fe in fish bodies were increased with advancing exposure time, and control group was higher than any other groups. Simple correlation analysis showed that the positive correlation between Cd and Zn, Cu and Ca, Fe, Ca and Fe, but Cd was negative correlation with Cu, Ca and Fe. In conclusion, we investigated a tendency that the concentration of Cd and Zn in fish bodies tended to increase with the lapse of time, but Cu was unchanged and those of Ca and Fe were decreased in administrating the trace dose of Cd and Zn in water. in water.

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