• Title/Summary/Keyword: Cu-bearing

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A Study on the Hot Cracking Phenomena of Cu-Ni Bearing Hot Rolled Steels (Cu-Ni 첨가형 열연강판의 열간균열현상에 관한 연구)

  • Yun, In-Taek;Jo, Yeol-Rae;Kim, Sun-Ho;Kim, In-Bae
    • Korean Journal of Materials Research
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    • v.9 no.4
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    • pp.335-340
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    • 1999
  • The hot cracking phenomena and phase behaviors during hot working process of Cu-Ni bearing hot rolled steels were investigated by a $90^{\circ}$bending tests, BSE image analysis and EDS analysis. For aNi-free 1.2% Cu bearing steel, the surface hot cracking occurred about $1100^{\circ}C$ due to a liquid state Cu-enriched phase formed continuously at the interface between oxide scale and matrix. The liquid Cu-enriched phase penetrated into austenite grain boundaries and caused surface cracking during the hot working. In case of 0.6% Ni containing 1.2% Cu-Ni bearing steel, solid state Cu-Ni-riched phase existed at the scale/matrix interface as a discontinuous type. But the higher addition of 1.2% Ni, solid state Ni-Cu-riched phase was formed dominantly in the oxide scale. It was found that the addition of Ni suppressed the surface cracking of 1.2% Cu bearing steel by eliminating the liquid state Cu-enriched phase.

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A Study on the Determination of Bearing Capacity of Polluted Soils with Various Concentrations (농도가 다른 오염지반의 지지력 결정에 관한 연구)

  • 안종필;박상범
    • Journal of the Korean Geotechnical Society
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    • v.15 no.6
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    • pp.57-69
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    • 1999
  • This study investigates the existing theoretical backgrounds for bearing capacity determination according to the plasticity of soils when unsymmetrical surcharge is loaded on polluted soft soils. It also investigates the behavior of the displacement and bearing capacity by unsymmetrical surcharge on the Polluted soft soils. by comparing the analytical results and the actual measurements performed through the model test. Model tests were carried out as follows : soil tank, bearing frame and bearing plate are made for the test ; the water content in soil tank was kept constant while the contaminants in natural soils and polluted material were gradually increased ; unsymmetrical surcharge is increased at regular intervals and then the amounts of settlement, lateral displacement and upheaval are observed. In conclusion, the value of critical surcharge was expressed as $q_{ cr}= 2.78_{Cu}$ which was similar to those $Tschebotarioff(q_{cr}=3.0_{Cu)$ and $Meyerhof(q_{cr}=(B/2H+\pi/2_{Cu})$ had proposed. The value of ultimate capacity was expressed as $q_{ult}=4.84_{Cu}$ which was similar to that of Prandtl.

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A Study on the Wear Characteristics of Bearing According to its Material in Scroll Compressor (스크롤 압축기의 크랭크 샤프트의 베어링 재질에 따른 마모특성에 관한 실험적 연구)

  • Sung, Chi-Un;Park, Young-Do;Hwang, Yu-Jin;Back, Gee-Dae;An, Sung-Young;Lee, Jae-Keun
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.194-202
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    • 2008
  • In this study, we investigated the tribology behaviour of two different bearing materials. One of these alloys content is Cu(90)-Sn(10) alloy and is widely used in the automotive industry.The other is Al alloy. This bearing content is Al-Sn-Si-Cu. Therefore, it is required to study on the lublicating characteristics of bearing according to different materials. In this study, compressor bearings made by respectively "PTFE solid lubricant" and "AI alloy with superior load carrying capacity, rubbing and impact endurance", have gone through journal bearing test. Lubrication and abrasion characteristics are evaluated by analyzing the material characteristics of a scroll compressor bearing bush. The AI alloy bearing showed the most excellent lubrication and abrasion characteristics than Cu-Sn alloy under high load condition.

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Synthesis and Characterization of Various Di-N-Functionalized Tetraaza Macrocyclic Copper(II) Complexes

  • Kang, Shin-Geol;Kim, Na-Hee;Lee, Rae-Eun;Jeong, Jong-Hwa
    • Bulletin of the Korean Chemical Society
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    • v.28 no.10
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    • pp.1781-1786
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    • 2007
  • Two copper(II) complexes, [CuL3](ClO4)2 bearing one N-CH2CH2CONH2 group as well as one N-CH2CH2CN group and [CuL4](ClO4)2 bearing two N-CH2CH2CONH2 groups, have been prepared by the selective hydrolysis of [CuL2](ClO4)2 (L2 = C-meso-1,8-bis(cyanoethyl)-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane). The complex [CuL5](ClO4)2 bearing one N-CH2CH2C(=NH)OCH3 and one N-CH2CH2CN groups has been prepared as the major product from the reaction of [CuL2](ClO4)2 with methanol in the presence of triethylamine. In acidic aqueous solution, the N-CH2CH2C(=NH)OCH3 group of [CuL5](ClO4)2 undergoes hydrolysis to yield [CuL6](ClO4)2 bearing both N-CH2CH2COOCH3 and N-CH2CH2CN groups. The crystal structure of [CuL5](ClO4)2 shows that the complex has a slightly distorted square-pyramidal coordination polyhedron with an apical Cu-N (N-CH2CH2C(=NH)OCH3 group) bond. The apical Cu-N bond distance (2.269(3) A) is ca. 0.06 A longer than the apical Cu-O (N-CH2CH2CONH2 group) bond of [CuL4](ClO4)2. The pendant amide group of [CuL3](ClO4)2 is involved in coordination. The carboxylic ester group of [CuL6](ClO4)2 is also coordinated to the metal ion in various solvents but is removed from the coordination sphere in the solid state.

A Study on the Ageing Behavior of Cu-bearing HSLA steels by thermal analysis (열분석법에 의한 Cu를 함유한 HSLA강의 시효 거동에 관한 연구)

  • 박태원;심인옥;김영우;강정윤
    • Proceedings of the KWS Conference
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    • 1994.05a
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    • pp.44-47
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    • 1994
  • The ageing behavior of Cu-bearing HSLA steels was studied by using Differential scanning calorimetry(DSC), Transmission electron microscopy and hardness tester. Two heat evolution peaks were observed during DSC scans over the temperature range of 25~590$^{\circ}C$ at a heating rate of 5$^{\circ}C$/min. The peaks appeared in low (241∼319$^{\circ}C$ : HSLA-A, 224∼310$^{\circ}C$ : HSLA-B) and high temperature (514∼590$^{\circ}C$ : HSLA-A, 451∼558$^{\circ}C$ : HSLA-B) are attributed to the formation of coherent Cu-clusters and noncoherent $\varepsilon$-Cu phase, respectively. It was confirmed that as ageing proceeds, the coherent bcc Cu-clusters transform to noncoherent fcc $\varepsilon$-Cu phase. In the case of the ageing to peak hardness at 300$^{\circ}C$ and 400$^{\circ}C$, the coherent Cu-clusters contributed to the hardening. As ageing time and temperature increase over peak hardness, noncoherent $\varepsilon$-Cu are formed and hardness decreases.

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Determination of Optimum Cu and Mn Contents in Cu-bearing Hot Rolled Steel Sheets (Cu첨가형 열연강판의 최적 Cu 및 Mn 첨가량 규명)

  • Yoon, Il-Sung;Yun, In-Taek;Cho, Yeol-Rae;Kim, In-Bae
    • Korean Journal of Materials Research
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    • v.8 no.3
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    • pp.274-279
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    • 1998
  • Optimum Cu and Mn contents in 0.05wt%C-Cu bearing hot rolled steel sheets were investigated by vickers hardness measurement, tensile test and transmission electron microscopy. It was determined that the optimum Cu and Mn contents were 1.2wt% and 0.75-0.85wt% respectively. It was confirmed by TEM observation that the coarse recipitates were fcc $\varepsilon$-Cu in 0.05%C-1.2%Cu-0.75%Mn-O.O4%Nb steel sheets. The Cu-bearing steel sheets having 780MPa of tensile strength could be fabricated by 10% pre-strain and aging treatment at $550^{\circ}C$ for 30min.

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Primary Dispersion of Elements in Altered Wallrocks around the Gold-bearing Quartz Veins at the Okgye Mine (옥계 함금석영맥광상 주변모암에서의 원소들의 일차분산)

  • Hwang, In Ho;Chon, Hyo Taek
    • Economic and Environmental Geology
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    • v.27 no.6
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    • pp.549-556
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    • 1994
  • Geochemical studies on gold-bearing quartz veins and wallrocks from the Okgye mine were carried out in order to investigate the primary dispersion patterns of gold and associated elements and to quantify the dispersion width of elements with distance from the gold-bearing quartz veins. Gold-bearing quartz veins occur in basaltic trachyandesite of unknown age. Enrichment of $k_2O$, MnO, Au, As, Rb, Sb, Pb, Zn, Cu, Ag and Cd, and depletion of $Na_2O$ and Sr are found in altered wallrocks. The ratio of $k_2O(k_2O+Na_2O)$, alteration index for trace elements, and Rb/Sr in altered wallrocks are increased, whereas Sr/CaO ratio is decreased with approach to the gold-bearing quartz veins. The widths of primary dispersion range from 17 cm to 155 cm. The relative dispersion width increases in order Au=Cu=Zn=Ag=Cd$k_2O$=Rb and Ba< $Na_2O$ $Na_2O$, As, Sb, Sr, Pb, Au, Cu, Zn, Ag and Cd, and a quadratic function for $k_2O$, MnO, Rb and Ba.

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Seizure Failure of Engine Crankshaft Bearings

  • Ni, X.;Cheng, H.S.
    • Tribology and Lubricants
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    • v.11 no.5
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    • pp.162-171
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    • 1995
  • The application of reciprocating engine crankshaft bearings is of particular importance and interest among the plain bearing, not only because the sheer volume of intemal combustion engines now produced, but because the severe operating conditions they are subjected to. Demands for better performances of crankshaft bearings have provide an important impetus in the development of bearings and bearing materials. As engine design progresses toward higher outpt and higher efficiency, crankshaft bearings must perform under more seveve operating conditions. Higher load, temperature, and speed as well as lower viscosity oil are applied to the bearing sysem, resulting in a smaller minimum oil film thickness. This means more solid-solid contact between the shaft and bearing, and the bearing is exposed to more danger of seizure. Some engines may experience bearing seizure problems. However, understanding about the seizure behavior and mechanism is far from being enough. Seizure resistance of a bearing-shaft system will be affected by the properties of the shaft and bearing, especially their materials and surface texture. Commonly used engine bearing materials include Al-Pb-Si, Al-Sn-Si, Al-Sn, and Cu-Pb with Pb-Sn-Cu overlay. These materials have very different properties. They showed different behaviors dering seizure tests and seizure may occur with different mechanism for different bearing material. Shaft materials also affect the seizure resistance of the system. Surface texture of the bearing and shaft have apparent effects on the lubrication and solid-solid contact pattern, and therefore will affect the seizure behavior of the system. Bearings and shafts which are made of different materials and have different surface textures have been tested and analyzed. Their effects on seizure resistance are discussed and possible seizure mechanisms for different beatings are presented in this paper.

Hydrochloric Acid Leaching of Arsenic from Arsenic-Bearing Copper Slime. (동전련 부산물인 함비소 동슬라임으로부터 염산에 의한 비소의 침출)

  • 유용주;황필규
    • Resources Recycling
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    • v.1 no.1
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    • pp.51-57
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    • 1992
  • The hydrochloric acid leaching has been studied as a fundamental experiment on the recovery of arsenic from arsenic-bearing copper slime in copper electrorefining. The slime is mainly composed of $\beta-Cu_3As$ Which is intermetallic compound of CU and As. And the minor components are $CU_2O$ and CusAs in the slime. The optimum conditions of leaching of the slime were found to be as follows : 6N hydrochloric acid, particle size passed through 140 mesh, leaching for 150 min at $60^{\circ}C$, ratio of HCI/slime of 3 to 1 ; where 98 percent of arsenic were leached out of the As-bearing slime.

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Effects of Copper-bearing Montmorillonite (Cu-MMT) on Escherichia coli and Diarrhea on Weanling Pigs

  • Xia, M.S.;Hu, C.H.;Xu, Z.R.;Ye, Y.;Zhou, Y.H.;Xiong, L.
    • Asian-Australasian Journal of Animal Sciences
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    • v.17 no.12
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    • pp.1712-1716
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    • 2004
  • Copper-bearing montmorillonite (Cu-MMT) was produced by $Cu^{2+}$ cation exchange reaction. X-ray diffraction analysis showed that that the (001) basal spacing of the MMT crystal lattice increased from 1.544 to 1.588 nm after $Cu^{2+}$ exchange. This indicated that $Cu^{2+}$ entered into interlayer position of MMT as a hydrated cation or composite cation. In vitro results indicated that Cu-MMT had antibacterial activity on Escherichia coli $K_{88}$. Cu-MMT had unbalanced positive charge after cation exchange. Its antibacterial activity resulted from two aspects, one was electrostatic attraction which made E. coli $K_{88}$ being adhered on the montmorillonite surface, the other was the $Cu^{2+}$ slowly released, which could kill bacteria. In an in vivo study, four replicates of eight weanling pigs were assigned to each of two dietary treatments to study the effects of Cu-MMT on diarrhea, E. coli in the lumen of the jejunum and morphology of jejunal mucosa. As compared to the control, supplementation of the diet with 0.2% Cu-MMT improved average daily gain by 12.50% (p<0.05) and decreased F/G by 9.42% (p<0.05). The mean diarrhrea incidence was decreased by 71.80% (p<0.05). The viable counts of Escherichia coli in jejunal contents were significantly reduced (p<0.05). Villus height and the villus height to crypt depth ratio at the jejunal mucosa were increased by 19.09% (p<0.05) and 37.10% (p<0.05), respectively.