• 한국재료학회지
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• 제33권1호
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• pp.8-14
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• 2023

In order to broaden the range of application of light weight aluminum alloys, it is necessary to enhance the mechanical properties of the alloys and combine them with other materials, such as cast iron. In this study, the effects of adding small amounts of Cu and Zr to the Al-Si-Mg based alloy on tensile properties and corrosion characteristics were investigated, and the effect of the addition on the interfacial compounds layer with the cast iron was also analyzed. Although the tensile strength of the Al-Si-Mg alloy was not significantly affected by the additions of Cu and Zr, the corrosion resistance in 3.5 %NaCl solution was found to be somewhat lowered in this research. The influence of Cu and Zr addition on the type and thickness of the interfacial compounds layer formed during compound casting with cast iron was not significant, and the main interfacial compounds were identified to be Al₅FeSi and Al₈Fe₂Si phases, as in the case of the Al-Si-Mg alloys.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 2004년도 추계학술발표회 발표논문집
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• pp.941-942
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• 2004

• 한국재료학회:학술대회논문집
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• 한국재료학회 1998년도 IUMRS-ICEM ABSTRACT BOOK
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• pp.48.3-48
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• 1998

• 한국자기학회지
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• 제6권4호
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• pp.211-217
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• 1996

Fe-B-Nb-Cu계 초미세결정합금의 고주파수 대역에서의 연자기 특성을 개선하기 위하여, 이 합금에 대한 Al 첨가효과 및 적정 Al 함유합금을 $10\;\mu\textrm{m}$ 이하의 두께를 가진 극박형으로 만들었을 때의 자기적 특성이 조사되었다. 그 결과 $Fe_{78}Al_{4}Nb_{5}B_{12}Cu_{1}$ 조성합금의 경우에 100 kHz 이상의 고주파 영역에서 높은 실효투자율과 낮은 자심손실 값을 나타내었다. 또 이 합금을 두께 $10\;\mu\textrm{m}$ 이하로 극박화한 경우 1 MHz영역까지의 실효투자율 및 자심손실 특성이 크게 개선되었다. 즉, 두께 $8\;\mu\textrm{m}$의 $Fe_{78}Al_{4}Nb_{5}B_{12}Cu_{1}$ 합금의 1 MHz에서의 실효 투자율은 5,000이었으며, 자심손실은 1 MHz, 0.2 T에서 1.4 kW/kg의 값을 보였다. 이러한 우수한 연자기 특성은 Al 첨가에 의해 자구구조의 변화 및 10 nm 이하의 보다 미세한 $\alpha-Fe$상 생성등에 기인하는 것으로 해석되었다.

• 한국분말재료학회지
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• 제11권3호
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• pp.193-201
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• 2004

1960년 Au-Si계 합금에서 처음으로 비정질상이 급속 응고법에 의해 보고된 이래/sup 1)/ 지난 40년 간 많은 합금계에서 비정질상이 보고되어졌다. 대표적으로 Fe-, Ni-, Co기 합금 등 많은 합금계에서 비정질상이 보고되었으나, 비정질상의 형성을 위해서는 약 105 K/s이상의 높은 냉각속도를 필요로 하였다. 1980년대 수백 K/s의 낮은 냉각속도 하에서도 비정질상이 형성될 수 있는 다원계 합금(multi-component alloy)이 Mg-Ln-(Ni, Cu, Zn), Ln-Al-TM 합금에서 보고되어 졌으나 많은 관심을 받지 못하다가 1993년 Zr-Ti-Ni-Cu-Be 합금에서 수 ㎝ 크기의 비정질합금 제조가 보고되면서 전 세계적으로 많은 관심을 받게 되었다. Zr-Ti-Ni-Cu-Be계 벌크 비정질 합금이 보고된 후 Zr-(Nb,Pd)-Al-TM, Pd-Cu-Ni-P, Fe-Co-Zr-Mo-W-B, Ti-Zr-Ni-Cu-Sn등 여러 합금계에서 벌크 비정질 합금이 보고되었다. (중략)

• 분석과학
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• 제7권4호
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• pp.517-526
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• 1994

Mn의 함량을 달리하여 제조한 Al-Li-Cu-Mg-Mn-Zr 합금의 미고용상 및 분산상을 EPMA(Electron Probe Microanalyzer)와 SAEM(Scanning Auger Electron Microscope)으로 분석하였다. 또한 미고용상의 부피 분율, 분포 및 형태를 광학현미경으로 관찰하였으며, 상온과 고온에서의 인장 특성을 조사하였다. Mn의 함량이 증가함에 따라 미고용상의 부피분율을 급격히 증가하고 연신율을 감소하였다. Mn은 기지 조직의 결정립을 미세하고 균일하게 분포하도록 하였다. 인장시험 결과, 0.44 wt% Mn이 첨가된 합금이 다른 합금보다 우수한 기계적 특성을 나타내었다.

• 한국분말재료학회지
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• 제4권4호
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• pp.252-257
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• 1997

Cu-brazed layer between the sintered-cam(Fe-5Cr-lMo-0.5P-2.5C, wt%) and seamless steelpipe(0.25-0.35C, 0.3-1.0 Mn, bal Fe, wt%) in the camshaft shows a columnar structure of $\gamma$-phase growing from the steel pipe. Liquid phase sintered 60Fe-40Cu alloys are carburized to simulate the brazing process giving rise to the columnar growth. Liquid film migrations and columnar growth of $\gamma$-grains are observed in the carburized regions. The $\gamma$-grains grow in the same direction as the C-diffusion. Fe-solubility in the liquid of carburized region is higher than in the uncarburized by about 0.3 at%. The columnar growth is driven by the gradient of the supersaturated Fe-solute in the liquid between two adjacent $\gamma$-grains.

• Nuclear Engineering and Technology
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• 제32권4호
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• pp.372-378
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• 2000

The effect of alloying elements on the creep resistance of Zr alloys was investigated using thermal creep tests that were performed as a part of advanced fuel cladding development. The creep tests were conducted at 40$0^{\circ}C$ and 150 MPa for 240 hr. A statistical model was derived from the relationship between the steady-state creep rate and the content of individual alloying elements. The creep strengthening effect decreased in the following sequence : Nb, Sn, Mn, Cr, Mo, Fe and Cu. The high creep resistance of Sn and the opposite effect of Fe on zirconium alloys seem to be associated with their lowering and enhancing, respectively, the self-diffusivity of the zirconium matrix.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.788-789
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• 2006

Microstructure and soft magnetic properties of bulk amorphous and/or nanocrystalline $Fe_{73.5}Cu_1Nb_3Si_{13.5}B_9$ alloys prepared by consolidation at 5.5GPa were investigated. The relative density of the bulk sample 1 (from amorphous powders) was 98.5% and the grain sizes were about 10.6nm. While the relative density and grain sizes of bulk sample 2 (from nanocrystalline powders) are 98% and 20.1nm, respectively. Particularly, the bulk samples exhibited a good combined magnetic property: for Sample1, $M_s=125emu/g$ and $H_c=1.5Oe;$ for Sample2, $M_s=129emu/g$ and $H_c=3.3Oe$. The success of synthesizing the nanocrystalline Fe-based bulk alloys will be encouraging for the future development of bulk nanocrystalline soft magnetic alloys.

• 한국자기학회지
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• 제5권5호
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• pp.421-426
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• 1995

The magnetic properties of the hot-pressed magnets made from the Fe-Nd-B alloys, mechanically ground and subsequently blended with binary additives such as Al-Cu and Ag-Zn before hot pressing, were investigated. The coercivities of the magnets increased as the concentration of Al-Cu increased up to 1 wt.% or up to 3 wt.% in the case of Ag-Zn. At higher concentrations the coercivities decreased markedly. The maximum gain in coercivity by the addition was about 20 %. typical values of $_{i}H_{c}$ and $B_{r}$ of a hotpressed magnet containing 1 wt.% Al-Cu were 18 kOe and 7 kG, respectively. It was found that Cu, Ag, and Zn, which diffused into the magnet during hot pressing, were mostly concentrated on the Nd-rich grain boundary phase whereas Al was present not only in the grain boundary region but also in the matrix grains.