• Journal of the Korean Crystal Growth and Crystal Technology
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• v.9 no.3
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• pp.299-302
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• 1999

$La_{2-x}Sr_{x}CuO_{4}$ single-crystalline films were prepared on bulk single crystals of Zn-doped $La_{2-x}Sr_{x}CuO_{4}$ as the substrates by LPE technique using two deferent methods. When prepared using an alumina crucible in normal electrical furnace, the $La_{2-x}Sr_{x}CuO_{4}$ films were contaminated with less than 3 at% aluminum from the alumina crucibles. Aluminum contamination either reduced or completely destroyed the superconductivity of the $La_{2-x}Sr_{x}CuO_{4}$ films, For LPE growth by modified TSFZ method using an infrared heating furnace without crucibles, the $La_{2-x}Sr_{x}CuO_{4}$ films of x=0.11 showed superconducting with $Tc_{onset}=36\;K$, which is 10 K higher than that in the $La_{2-x}Sr_{x}CuO_{4}$ bulk single crystals.

• Journal of the Mineralogical Society of Korea
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• v.19 no.3 s.49
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• pp.171-187
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• 2006

The status of heavy metal contamination was investigated using chemical analyses of stream waters and sediments obtained from Samsanjeil and Sambong Cu mining area in Goseong-gun, Gyeongsangnam-do. In addition, the degree and the environmental risk of heavy metal contamination in stream sediments was assessed through pollution index (Pl) and danger index (DI) based on total digestion by aqua regia and fractionation of heavy metal contaminants by sequential extraction, respectively. Not only the degree of heavy metal contamination was significantly higher in Samsanjeil area than in Sambong area, but its environmental risk was also revealed much more serious in Samsanjeil area than in Sambong area. The differences in status and level of contamination and environmental risk between both two mining areas may be attributed to existence of contamination source and geology. Acid mine drainage is continuously discharged and flows into the stream in Samsanjeil mining area, and it makes the heavy metal contamination in the stream more deteriorated than in Sambong mining area in which acid mine drainage is not produced. In addition, the geology of Samsanjeil mining area is mainly comprised of andesitic rocks including a small amount of calcite and having lower pH buffering capacity fer acid mine drainage, and it is likely that the heavy metal contamination cannot be naturally attenuated in streams. On the contrary, the main geology of Sambong mining area consists of pyroclastic sedimentary Goseong formation containing a high content of carbonates, particularly calcite, and it seems that these carbonates of high pH buffering capacity prevent the heavy metal contamination from proceeding downstream in stream within that area.

• Journal of the Korean earth science society
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• v.27 no.1
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• pp.73-82
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• 2006

Dust samples were collected from 10 middle and high schools in the Gochang-Gun, Korea. Heavy metal concentrations were determined for the dry-deposited dusts from indoor and outdoor of classroom and playground of each sampling site. Concentrations of Cd, Cu, Pb and Zn in indoor's dusts were highly concentrated. Also concentrations of Cu, Ni, Pb and Zn in outdoor's dusts were highly concentrated. Concentrations of Cd, Cu and Zn in the dusts were much higher than the world average contents in soil and environmental orientation value. These levels are similar to those of the dust samples at middle schools and high schools located in Jeonju-city, Korea. Compared with concentrations of heavy metals in soils and dusts in Korea, the environment of indoor and outdoor of classroom is highly concentrated except for Cu, Zn. The concentrations of playground is less than that of residential dust and main road dust and playground in Jeonju-city. Playground dusts in 1 school exhibited the enhanced heavy metal pollution with a pollution index (Kloke, 1979) greater than 1.0, but indoor and outdoor dusts in 7 schools exhibited the enhanced heavy metal pollution with a pollution index (by Kloke) yester than 1.0.

• Economic and Environmental Geology
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• v.38 no.4 s.173
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• pp.451-462
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• 2005

In order to examine the extent of environmental contamination at abandoned Samsanjeil Cu mines in Kosung-kun, Kyeongsangnam-do, we have investigated the contaminations and mobility of toxic trace elements from mine wastes including about 280,000 tonnages of tailings by chemical experiments (total extraction, partial extraction by 0.1N HCI and sequential extraction procedure). Total concentrations of trace elements showed that Cu, As, Co, Zn, Pb, and Cd concentrations in tailings were 14.0, 3.6, 3.1, 2.1, 2.1 and 1.6 times greater than those in background soil, respectively. From the proportion of metals bound to the exchangeable and carbonate fractions, the comparative mobility of metals decrease in order of $Zn(29.0\%)>Cu(12.3\%)Pb(9.6\%)>Cd(3.0\%)>As=Co(0.0\%)$. Based on the concentrations, chemical speciations of tailings, waste rock and nearby soil, it was revealed that Cu and Zn were the most possible elements to contaminate the surrounding environment in Samsanjeil mine area. In addition, the tailings had total trace metal concentrations below Dutch guideline values except Cu, and they might not affect adverse impact on environment.

• Environmental Analysis Health and Toxicology
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• v.31
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• pp.21.1-21.7
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• 2016

Objectives The present study analyzes metal contamination in sediment of the East Kolkata Wetlands, a Ramsar site, which is receiving a huge amount of domestic and industrial wastewater from surrounding areas. The subsequent uptake and accumulation of metals in different macrophytes are also examined in regard to their phytoremediation potential. Methods Metals like cadmium (Cd), copper (Cu), manganese (Mn), and lead (Pb) were estimated in sediment, water and different parts of the macrophytes Colocasia esculenta and Scirpus articulatus. Results The concentration of metals in sediment were, from highest to lowest, Mn ($205.0{\pm}65.5mg/kg$)>Cu ($29.9{\pm}10.2mg/kg$)>Pb ($22.7{\pm}10.3mg/kg$)>Cd ($3.7{\pm}2.2mg/kg$). The phytoaccumulation tendency of these metals showed similar trends in both native aquatic macrophyte species. The rate of accumulation of metals in roots was higher than in shoots. There were strong positive correlations (p <0.001) between soil organic carbon (OC) percentage and Mn (r =0.771), and sediment OC percentage and Pb (r=0.832). Cation exchange capacity (CEC) also showed a positive correlation (p <0.001) with Cu (r=0.721), Mn (r=0.713), and Pb (r=0.788), while correlations between sediment OC percentage and Cu (r=0.628), sediment OC percentage and Cd (r=0.559), and CEC and Cd (r=0.625) were significant at the p <0.05 level. Conclusions Bioaccumulation factor and translocation factors of these two plants revealed that S. articulatus was comparatively more efficient for phytoremediation, whereas phytostabilization potential was higher in C. esculenta.

• Korean Journal of Environmental Agriculture
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• v.24 no.3
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• pp.222-231
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• 2005

Most of the tailings have been left without any management in abandoned metalliferous mines and have become the main source of heavy metal contamination of agricultural soils and crops in the these areas. To compare of environmental assessment of heavy metals in tailings derived from various 25-metalliferous mines in Korea, 3 different analysis methods such as water soluble, 0.1 M-HCl extractable, and total acid digestion method (aqua regia) were used. The chemical composition of water soluble in mine tailing were in the order ${SO_4}^{2-}>Ca^{2+}>Mn^{2+},\;Na^+,\;Al^{3+}>Mg^{2+},\;Fe^{3+}>Cl^-$. Specially, pH, EC, ${SO_4}^{2-},\;and\;Ca^{2+}$ concentrations in tailing varied considerably among the different mines. The average total concentrations of Cd, Cu, Pb, Zn, and As in tailing were 31.8, 708, 4,961, 2,275 and 3,235 mg/kg, respectively. Specially, the contents of Cd, Zn and As were higher than those of countermeasure values for soil contamination (Cd : 4, Zn : 700 and As : 15 mg/kg in soil) by Soil Environmental Conservation Act in Korea. The rates of water soluble heavy metals to total contents in tailings were in the order Cd > Zn > Cu > Pb > As. The rates of 0.1M-HCl extractable Cd, Cu, Pb, Zn, and As (1M-HCl) to total content were 17.4, 10.2, 6.5, 6.8 and 11.4% respectively. The enrichment factor of heavy metals in tailings were in the order As > Pb > Cd > Cu > Zn. The pollution index in tailing Au-Ag mine tailing were higher than those of other mine tailing. As a results of enrichment factor and pollution index for heavy metal contaminations in mine tailing of metalliferous mines, the main contaminants are mine waste materials including tailings.

• Journal of Environmental Impact Assessment
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• v.22 no.5
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• pp.481-489
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• 2013

There are U.S. troops with a force about 290,000 strong stationed all around the world, approximately 150 countries. Among the troops, USFK has performed principal part with its stationing for 50 years against the military threat of North Korea. However, as a result of an investigation made into environmental contamination of several bases which were restituted from US to ROK by the Land Partnership Plan in the process of relocation of USFK, it was found that the area was contaminated by not only TPH and BTEX caused by diesel fuel and JP-8 but also various heavy metal over the standard level according to the operations of corps. Among these bases, 4 corps, each of which has different duties and function, were chosen to be analyzed for the characteristics and degrees of soil contamination. Fisrt of all, in armored camp the soil was contaminated by TPH and heavy metal (Zn, Ni, Pb) due to the repairing activities of tracked vehicles and shooting exercises. In army aviation camp, the soil was contaminated by TPH, BTEX and heavy metal (Zn, Cd) due to repairing activities of aircrafts. Also, in engineer camp there was contaminated area polluted by TPH and heavy metal (Zn, Pb) caused by open-air storage of various construction materials and TPH, BTEX and heavy metal (Zn, Pb, Cu) contamination of aircraft shooting area in shooting range camp were detected. Managing environment will be more effective when we identify the contaminative characteristics and take necessary measures in advance.

• Economic and Environmental Geology
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• v.26 no.2
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• pp.175-185
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• 1993

Soils and dusts collected from Changhang smelter area were analyzed for Cu, Pb, Zn, and Cd in order to determine their dispersion pattern and mode of occurrences, and to investigate the pollution level of heavy metals such as Cu, Pb, Zn, and Cd by smelting activity. The soil pH of Changhang area is in the range of 3.7~8.8, and increased with increasing distance from the smelter site. The particles containing heavy metals are several tens of ${\mu}m$ in diameter, and have well crystal form. Samples collected near the smelter show similar particle properties in size, shape, and composition, which means that they could be originated from the same contamination source. Element couples of Cu, Pb, Zn, and Cd indicate high correlation with each other, which means that Cu, Pb, Zn, and Cd could be originated from the same point source of smelter. Heavy metal contents were decayed to background levels from 2.5 kilometer away from the smelter.

• Applied Chemistry for Engineering
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• v.35 no.4
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• pp.346-351
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• 2024

Chemical reduction using catalysts and NaBH₄ presents a promising approach for reducing 4-nitrophenol contamination while generating valuable byproducts. Covalent organic frameworks (COFs) emerge as a versatile platform for supporting catalysts due to their unique properties, such as high surface area and tunable pore structures. This study employs design of experiments (DOE) to systematically optimize the synthesis of Cu embedded COF (Cu/COF) catalysts for the reduction of 4-nitrophenol. Through a series of experimental designs, including definitive screening, mixture method, and central composition design, the main synthesis parameters influencing Cu/COF formation are identified and optimized: MEL:TPA:DMSO = 0.31:0.36:0.33. Furthermore, the optimal synthesis temperature and time were predicted to be 195 ℃ and 14.7 h. Statistical analyses reveal significant factors affecting Cu/COF synthesis, facilitating the development of tailored nanostructures with enhanced catalytic performance. The catalytic efficacy of the optimized Cu/COF materials is evaluated in the reduction of 4-nitrophenol, demonstrating promising results in line with the predictions from DOE.

• Journal of the Korean Society of Environmental Restoration Technology
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• v.11 no.4
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• pp.1-11
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• 2008

This paper analyzed the status of contaminated soils in order to manage it efficiently in Incheon using Geographic Information System (GIS) and investigated the concepts and techniques of the GIS and interpolation method. GIS technique is applied to the analysis of soil quality monitoring data. The purposes of this research are to assess the soil contamination of Incheon metropolitan area and to analyze the existing contents of heavy metals (Cd, Cu, As, Hg, Pb, $Cr^{+6}$) and pH in soil. The samples had been collected from year 1998 to year 2002 by the Soil Contamination Monitoring Network. The soil quality monitoring results were imported with the geographical information of the monitoring programs in capital area. It is found that currently available GIS technique has a great extend of potential for soil quality management. From the analysis of soil quality monitoring results, the GIS application demonstrates the poor soil quality in the central capital area and the it is improved as it travels down to the suburb area. Concerning about the data interpolation, the discrepancy caused by applying different method was ignorable, although Kriging method is further developed.