• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.8
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• pp.3806-3813
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• 2012

The coastal environment is affected by Cu and Zn contamination through diverse routes, including antifouling agents, industrial wastewater, and domestic activities. In this study, Crassostrea gigas and Littorina brevicula were used to examine the distributions of Cu and Zn, which are related to the increase in the use of new antifouling agents that have been used for ships since the TBT ban in 2003. The average Cu and Zn concentrations in the samples were 231.8 ${\mu}g/g$ and 492.6 ${\mu}g/g$, respectively. Both the Cu and Zn concentrations were highest in the shipyard samples, followed by the harbor sample for Cu and the industrial area sample for Zn. The results indicated that the Cu concentration was affected by the antifouling agents, and the Zn concentration was affected by both the antifouling agents and industrial wastewater. The areas that need intensive control to address the Cu and Zn contamination in major Korean coasts were identified.

• Journal of Environmental Health Sciences
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• v.20 no.4
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• pp.17-35
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• 1994

This study was performed to investigate and assess the heavy metal contamination of sediment in main stream and tributaries of the Han-river in the vicinity of Seoul. Sediment were sampled at eight locations of main stream and eighteen locations of tributaries in the spring, summer, and fall in 1993. Six heavy metals of Cd, Cu, Pb, Zn, Cr, and Hg, were assessed. For an assessment of heavy metal contamination in sediment, the assessment method of Hakanson was modified to estimate for Han-river, then classification method of Muller in sediment quality was applied. For an assessment of contamination in each heavy metal, Contamination factor C$_f^i$ which was defined the ratio of concentration of i heavy metal in investigated location to background concentration of i heavy metal in uncontaminated upper area was used. The sediment quality in each heavymetal was classified as follows if C$_f^i$<1, Class I for Non contamination, if 1 < C$_f^i$ < 3, Class II for Low contamination, if 3< C$_f^i$ <6, Class III for Moderate contamination, if 6< C$_f^i$ <12, Class IV for Considerable contamination, and if C$_f^i$ > 12, Class V for High contamination.(abbreviation)

• Economic and Environmental Geology
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• v.34 no.3
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• pp.283-299
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• 2001

The middle cover soils and clay liners collected from the Kumheung landfill in Gongiu City were analysed for As, Ba, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, Sr, Ti and Zn concentrations using 0.] N HCl digestion and total/sequential extraction experiments followed by ICP-AES determination. The uncontaminated soil and sediment samples were also analyzed for the comparison. The results of sequential extraction showed that Cu was dominant in the oxidizable fraction, and As, Ni, Sr, Ba, and Mn were in the exchangeable fraction. Zinc and Mn occurred mostly in association with reducible, residual and carbonate fractions. Most of Cd and Pb were bound to the reducible and oxidizable fractions. The main carrier of Co, Cr, Fe and 11 was the residual fraction and another important carrier was the reducible fraction. The percentage of the metals of organically-bound form in the middle cover soils and clay liner was in the order of Cu(48%) > Ti(42%) > Pb(27%) > As(25%) > Cd(20%). As deduced from sequential extraction analysis, potential order of metal mobility in the middle cover soils and clay liner from the landfill was proposed: Cd > Sr > As > Ni > Mn > Ba > Cu > Pb > Zn » Co > 11 > Fe > Cr. Based on the 'geoaccumulation index' and the 'enrichment factor' normalized to A], the level of contamination of Cu, Ni and C1' was significant in the samples from Kumheung landfill and surrounding farmland. Their enrichments were attributed partly to anthropogenic pollutions.

• Economic and Environmental Geology
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• v.38 no.3 s.172
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• pp.221-236
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• 2005

In order to investigate the contamination levels and dispersion patterns of heavy metals such as Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn by urbanization, soils beneath roadside-trees and leaves of Ginkgo biloba were collected from Seoul area during October to November in 2001. All tree leaves were grouped into washed and unwashed ones. The pH of most soil ranges from 6 to 9 indicating a weak acidic and alkaline. The element couples of Cd-Co, Cr-Ni and Zn-Cu-Pb have good correlation in soils, and contamination sources of Cd-Co, Cr-Ni and Zn-Cu-Pb could be similar. High correlation coefficients among Pb, Cu and Zn in G. biloba indicates that these elements show the similar behavior during the metabolism processes. From the results of pollution index calculation for soils, industrialized and heavy traffic area were severly polluted by heavy metals such as Cd, Cu, Pb and Zn. By the discriminant analysis, industrialized and heavy traffic areas are enriched in the order of Ni> Cr> Pb. Cadmium is useful to discriminate between industrialized and heavy traffic areas, Co and Pb are highly enhanced in heavy traffic area.

• Journal of Soil and Groundwater Environment
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• v.18 no.1
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• pp.123-128
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• 2013

Water quality and contamination of sediment is a growing concern in the Iksan stream of Korea. Heavy metal contamination and changes in the physicochemical properties of the stream were evaluated. Water and sediment samples were collected from six sites during the dry and rainy seasons; pH, DO, EC, ORP, turbidity, $PO_4$-P, $NO_3$-N and selected heavy metals (Cu, Pb, Ni, As, Zn, Cd, Hg) were measured. Results showed almost no change in pH between seasons. DO was highest at site 2 (~2.63 mg/L) in the dry season; EC (1,540 ms/m) was greatest at site 1 in both seasons. The ORP gradually increased from the dry to rainy season at most of the sites and was highest at site 5. Turbidity was highest at site 1 and gradually decreased from the dry to rainy season at all sites except site 3. $PO_4$-P ranged from a high of 1,193mg/L at site 1 to in the dry season to a low of ~1.2 mg/L at site 4. In contrast, $NO_3$-N was highest at site 3 in the rainy season (12,531 mg/L). Among the heavy metals measured, Cu and Zn concentrations were highest at all sediment sites. Cu and Zn are added to livestock feed to improve reproductive rates and can be carried to the stream with manure. Transport of sediment and heavy metals during the rainy season is the major source of stream contamination and it is important to continue monitoring and take necessary action in these areas.

• Journal of Korean Society on Water Environment
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• v.37 no.4
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• pp.296-305
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• 2021

This work investigated heavy metal pollution in surface sediments of rivers in Busan, Korea. Surface sediments were analyzed in order to conduct contamination assessment of organic matter, nutrients, and heavy metal concentrations. Contamination assessment of heavy metals was conducted using geoaccumulation index (I_geo), pollution load index (PLI), and potential ecological risk index (RI). Accumulation of organic matter and nutrients were affected by water discharged from sewage treatment plant. The concentrations of organic matter and nutrients were found to be greater in points which were close to the sewage treatment plant more than points furthest. The concentrations of Pb, Zn, Cu, Cd, Hg, As, Cr, and Ni were found to be greater in surface sediment more than in the background. The mean concentrations of heavy metals were in the order of Zn (323.5 mg/kg) > Cu (70.5 mg/kg) > Pb (39.8 mg/kg) > Cr (33.4 mg/kg) > Ni (13.5 mg/kg) > As (9.4 mg/kg) > Cd (0.84 mg/kg) > Hg (0.092 mg/kg). The result of geoaccumulation indices indicated that Hg > Cr > Cu > Ni > Zn > As > Pb > Cd were found in order of severe contamination by heavy metals. From PLI and RI analysis, it was evident that the Suyeonggang 2 was the most contaminated river.

• Journal of Korean Society on Water Environment
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• v.18 no.4
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• pp.341-354
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• 2002

Heavy metal concentration/distribution in sediments and bivalves from the tidal flats in Saemankeum coastal area, western Korea, were investigated, Among 6 sampling sites, S2, S5 and S6 showed the higher levels of Zn, Cr, Ni, Cu and Cd contamination and S1 did the higher level of Pb contamination than other sites, while S-4 showed the lowest levels of these metal contamination. Overally, the levels of Zn, Cu and Pb concentrations in Sinonovacula constricta were estimated to be relatively high. The shell lengths of the collected mussels were linearly related to their dry weights of the whole soft parts, but the mussels collected from S3 were in a poor nutrition, resulting in the distinctively high levels of metal concentrations in the body. It was shown that in S. constricta, Cr, Ni, Cu and Zn are distributed equally into the whole soft parts or a little more into the flesh, after absorption, while Fe, Cd, Pb and Mn are transferred more into the non-flesh parts than into the flesh parts. In S. constricta, the heavy metal concentrations in the flesh increase with those in the whole soft parts. The bioaccumulation factors(heavy metal concentration in S. constricta/heavy metal concentration in sediment) showed that, of the examined metals, Cd is the most cumulative in the body of S. constricta, followed by Zn and Cu, while Mn, Cr, Ni and Pb are not cumulative.

• Journal of Soil and Groundwater Environment
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• v.7 no.3
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• pp.71-77
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• 2002

This research was carried out from 2001. 4 until 2001. 5 in order to examine the level of soil contamination in the vicinity of Nanjido. The sampling was done at near the Nanjido soil. At the each sampling site we did the sampling at different depth- surface(0~15cm deep), 1m deep, 2m deep, 3m deep. The contamination of Cd, Cu, Pb, As, $Cr^{+6}$, and Hg were tasted and analysed by spectra AA. The examination showed that the average concentration level of the entire sampled soil was Cd, 0.229mg/kg, Cu 8.349mg/kg, Pb : 11.083mg/kg, As : 0.298mg/kg, $Cr^{+6}$ : 0.124mg/kg, and Hg : 0.134mg/kg. The concentration level of at the depth of 0-l5cm, came out to be Cd : 0.305mg/kg, Cu : 8.464mg/kg, Pb : 11 383mg/kg, As : 0.128mg/kg, $Cr^{+6}$ : 0.153mg/kg, and Hg : 0.092mg/kg. It shows that in the cases of Cd and C $r^{+6}$ the average concentration level of the whole sampled soil was about 80% of that of 0-l5cm depth. And as for Hg and As. the average concentration level of the entire sampled soil came out to be approximately twice as high as the sample soil from the depth surface, As for Cu and Pb, there was not much difference between the entire samples average concentration level and the concentration level of surface. It was hard to find much relationship between the depth of each site where sampling was done and the level of concentration, the concentration level of Pb and Cu at the sampling site C and E was quite high, which suggests that it has been affected by the polluted the hyang-dong stream and fill random up waste.

• Proceedings of the Korea Association of Crystal Growth Conference
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• 1999.06a
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• pp.371-387
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• 1999

La2-xSrxCuO4 single-crystalline films were prepared on bulk single crystals of Zn-doped La2CuO4 as the substrates by LPE technique using tow deferent methods. When prepared using an alumina crucible in normal electrical furnace, the La2-xSrxCuO4 films were contaminated with less than 3 at% aluminum from the alumina crucibles. Aluminum contamination either reduced or completely destroyed the superconductivity of the La2-xSrxCuO4 films. For LPE growthby modified TSFZ method using an infrared heating furnace without crucibles, the La2-xSrxCuO4 films of x=0.11 showed superconducting with Tconset 36 K, which is 10 K higher than that in the La2-xSrxCuO4 bulk single crystals.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.8 no.2
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• pp.385-394
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• 2007

To study long-term characteristics of the heavy metal contamination, soil and sediment samples were collected at 14 sites in highway roadside during 6 years. The total concentrations of metals including Zn, Ni, Cu. Pb, Cr, Cd, and As in those samples were investigated. The results indicate that concentrations of Zn, Ni, and Cu in highway roadside soils are much higher than the metal concentrations in background soils and appear to be increased gradually. Strong linear relationships between the cumulative traffic and the contents of the metals in highway roadside soils were obtained. Therefore, they might be used to predict the heavy metal concentrations in the future highway roadside soils for establishing the countermeasure of soil and sediment contamination.