• Title/Summary/Keyword: Cu(Mg) alloy

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Copper Electroplating on Mg Alloy in Pyrophosphate Solution

  • Van Phuong, Nguyen;Moon, Sungmo
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.124.1-124.1
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    • 2016
  • In this work, uniform thickness and good adhesion of electrodeposited copper layer were achieved on AZ91 Mg alloy in alkaline noncyanide copper solution containing pyrophosphate ion by employing appropriate zincate pretreatment. Without zincate pretreatment, the electrodeposited copper layer on AZ91 Mg alloy was porous and showed poor adhesion which was explained by small number of nucleation sites of copper due to rapid dissolution of the magnesium substrate in the pyrophosphate solution. The zincate pretreatment was found as one of the most important steps that can form a conducting layer to cover AZ91 surface which decreased the dissolution rate of AZ91 Mg alloy about 40 times in the copper pyrophosphate solution. Electrodeposited copper layer on AZ91 Mg alloy after an appropriate zincate pretreatment showed good adhesion and uniform thickness with bright surface appearance, independent of the deposition time but the surface roughness of the electrodeposited copper layer increased with increasing Cu deposition time.

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A Study on the Nano-Deformation Characteristics of Grain-Size Controlled Rheology Material Surfaces for Surface Crack Prediction (표면크랙 예측을 위한 결정립 제어 레오로지 소재 표면의 나노 변형특성에 관한 연구)

  • 윤성원;김현일;강충길
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.355-358
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    • 2004
  • In this study, the deformation characteristics of grain-size controlled rheology materials surfaces were investigated as a part of the research on the surface crack prediction in semi-solid formed automobile components. The microstructure of rheology Al-Si alloys consists of primary and eutectic regions. In eutectic regions the crack initiation begins with initial fracture of the eutectic silicon particles and inside other intermetallic phases. Nano-deformation characteristics in the eutectic and primary region of semi-solid aluminum alloys (356 alloy and 319 alloy) were investigated through the nanoindentation/scratch experiments and the AFM observation.

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Potential Difference of Cyclic Polarization Curve of an Aircraft Al Alloy: ∆E (Esec,corr - Ecorr)

  • Sun, Qingqing;Chen, Kanghua
    • Journal of Electrochemical Science and Technology
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    • v.11 no.2
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    • pp.140-147
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    • 2020
  • This paper presents a hypothesis and its experimental validation that ∆E (Esec,corr - Ecorr) of cyclic polarization curve of an Al-Zn-Mg-Cu alloy decreases firstly and then increases with the increasing of corrosion rate or corroded fraction Fcorr of alloy surface. The minimum value of ∆E is obtained when Fcorr ≈ 50%. In addition, a proportional relationship between ∆E and |50% - Fcorr| was found. This non-monotonic relation between ∆E and extent of localized corrosion indicates that additional attention should be paid on using ∆E to assess localized corrosion behaviour of Al-Zn-Mg-Cu alloys.

Influence of Cu and Zn Contents on the Properties of Al-Fe-Cu-Mg Based Casting Alloys (Cu 및 Mg 첨가량에 따른 Al-Fe-Cu-Mg계 주조합금의 특성변화)

  • Kim, Jeong-Min;Kim, Nam-Hoon;Shin, Je-Sik;Kim, Ki-Tae;Ko, Se-Hyun
    • Journal of Korea Foundry Society
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    • v.34 no.4
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    • pp.130-135
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    • 2014
  • Efforts have been made to develop new silicon-free aluminum casting alloys that possess high electrical and thermal conductivity. In this research Al-Fe-Cu-Mg alloys with various Cu and Mg contents were investigated for their various properties. As the Cu or Mg content was increased, the electrical conductivity gradually decreased, while the tensile strength of the Al-Fe-Cu-Mg alloy tended to be improved. It was found that fluidity was generally inversely proportional to the Cu content, but the alloys containing 1%Mg showed considerably low fluidity, regardless of the Cu content.

Effect of T6 and T73 Heat Treatments on Microstructure, Mechanical Responses and High Cycle Fatigue Properties of AA7075 Alloy Modified with Mg and Al2Ca ((Mg + Al2Ca)로 개량된 AA7075 합금의 미세조직, 기계적 특성, 그리고 고주기 피로 특성에 미치는 T6 및 T73 열처리의 효과)

  • Hwang, Y.J.;Kim, G.Y.;Kim, K.S.;Kim, Shae K.;Yoon, Y.O.;Lee, K.A.
    • Transactions of Materials Processing
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    • v.30 no.1
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    • pp.5-15
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    • 2021
  • The effects of heat treatments (T6 and T73) on the microstructure, mechanical properties, and high cycle fatigue behavior of modified AA7075 alloys were investigated. A modified 7075 alloy was manufactured using modified-Mg (Mg-Al2Ca) instead of the conventional element Mg. Based on the microstructure, the average grain size was 4.5 ㎛ (T6) and 5.2 ㎛ (T73). Regardless of heat treatment, the modified AA7075 alloys consisted of Al matrix containing homogeneously distributed Al2CuMg and MgZn2 phases with reduced Fe-intermetallic compound. Room temperature tensile tests showed that the properties of modified 7075-T6 (Y.S.: 622MPa, T.S: 675MPa, elongation: 15.4%) were superior to those of T73 alloy (Y.S.: 492MPa, T.S: 548MPa, elongation: 12.8%). Experimental data show that the fatigue life of T6 was 400 MPa, about 64% of its yield strength. However, the fatigue life of T73 alloy was 330 MPa and 67%. Irrespective of the stress level, all crack initiation points were located on the specimen surface, and no inclusions acting as stress concentrators were seen. Superior mechanical properties and high cycle fatigue behavior of modified AA7075-T6 alloy are attributed to the fine grains and homogeneous distribution of small second phases such as MgZn2 and Al2CuMg, in addition to reduced Fe-intermetallic compounds.

Improvement of the Mechanical Properties of Al-7Si-0.35Mg Cast Alloys by the Optimised Combination of Alloying Elements and Heat Treatment (합금원소 첨가 및 열처리 공정 제어를 통한 Al-7Si-0.35Mg 주조재 합금의 기계적 특성 향상)

  • Cho, Young-Hee;Lee, Jung-Moo;Jin, Jin-Woo;Jung, Jae-Gil
    • Journal of Korea Foundry Society
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    • v.36 no.1
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    • pp.1-9
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    • 2016
  • Improvement of the mechanical properties of a commercial aluminium casting alloy, A356, was achieved through an optimised combination of alloying elements, modification, and heat treatment. 0.7 wt.% Cu and an additional 0.2 wt.% Mg were added to an Al-7Si-0.35Mg alloy for strengthening at both room and elevated temperatures, whilst a subsequent decrease in the ductility was compensated for by the modification of eutectic Si by Sr addition at a level of up to 110 ppm. It was found that the dissolution of Cu-rich or Mg-rich phases could be maximised by solid-solutionising an alloy with 40 ppm Sr at $530^{\circ}C$, increasing the tensile and yield strengths to 350 MPa and 297 MPa, respectively, with a reasonably high strain of 5% after peak-aging at $210^{\circ}C$. Further addition of Sr up to 110 ppm is, however, more likely to interfere with the dissolution of the Cu-rich or Mg-rich phases during solid solution treatment, resulting in a slight decrease in both tensile and yield strengths at room temperature. Besides the Cu addition, such undissolved phases, on the other hand, may contribute to elevated temperature strength at $200^{\circ}C$.

Pitting Characteristics and Electrochemical Polarization Behaviors in Al-Cu-Si-Mg-Ag-Zr Alloys with Ageing (Al-Cu-Li-Mg-Ag-Zr합금의 시효에 따른 전기화학적 분극 거동과 공식특성)

  • Min, B.C.;Chung, D.S.;Shon, T.W.;Cho, H.K.
    • Journal of the Korean Society for Heat Treatment
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    • v.9 no.2
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    • pp.103-111
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    • 1996
  • In this paper, we studied on both electrochemical polarization behaviors and pitting characteristics of ultra high strength Al-Cu-Li-Mg-Ag-Zr alloys(named C1 and C2) and 2090 alloy according to their treatments in the deaerated 3.5% NaCl, using by the potentiodynamic and the potentiostatic method, SEM micrograph and surface roughness including depth of pitting attack. With the cyclic polarization curves, the hysteresis of the C1 and C2 alloys appeared more remarkably than that of the 2090 alloy, because of precipitation microstructural difference between C1, C2 alloys and 2090 alloy. In the pitting experiments, the correlations between pitting growth and aging conditions were analyzed with the SEM micrograph and measurement of the pit depth.

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Mechanical and Electrical Properties of an Al-Fe-Mg-Cu-B System Alloy for Electrical Wire Fabricated by Wire Drawing (인발가공에 의해 제조된 전선용 Al-Fe-Mg-Cu-B계 합금의 기계적 및 전기적 특성)

  • Jung, Chang-Gi;Hiroshi, Utsunomiya;Son, Hyeon-Taek;Lee, Seong-Hee
    • Korean Journal of Materials Research
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    • v.27 no.11
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    • pp.597-602
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    • 2017
  • In this study, an Al-0.7wt%Fe-0.2wt%Mg-0.2wt%Cu-0.02wt%B alloy was designed to fabricate an aluminum alloy for electrical wire having both high strength and high conductivity. The designed Al alloy was processed by casting, extrusion and drawing processes. Especially, the drawing process was done by severe deformation of a rod with an initial diameter of 12 mm into a wire of 2 mm diameter; process was equivalent to an effective strain of 3.58, and the total reduction in area was 97 %. The drawn Al alloy wire was then annealed at various temperatures of 200 to $400^{\circ}C$ for 30 minutes. The mechanical properties, microstructural changes and electrical properties of the annealed specimens were investigated. As the annealing temperature increased, the tensile strength decreased and the elongation increased. Recovery or/and recrystallization occurred as annealing temperature increased, and complete recrystallization occurred at annealing temperatures over $300^{\circ}C$. Electric conductivity increased with increasing temperature up to $250^{\circ}C$, but no significant change was observed above $300^{\circ}C$. It is concluded that, from the viewpoint of the mechanical and electrical properties, the specimen annealed at $350^{\circ}C$ is the most suitable for the wire drawn Al alloy electrical wire.

Effects of Mg and Cu Amounts on the Casting Characteristics and Tensile Property of Al-Zn-Mg-Cu Alloys (Al-Zn-Mg-Cu 합금의 주조성 및 인장특성에 미치는 Mg 및 Cu 첨가량의 영향)

  • Kim, Ki-Tae;Lim, Young-Suk;Kim, Jeong-Min
    • Journal of Korea Foundry Society
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    • v.32 no.1
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    • pp.38-43
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    • 2012
  • The effects of Mg and Cu amounts on the casting characteristics and tensile property of Al-Zn-Mg-Cu alloys were investigated for the development of high strength aluminium alloys for gravity mold casting. Increase of copper amounts in Al-6%Zn-3%Mgy% Cu alloys resulted in reduction of the fluidity of these alloys and had little effects on the tensile property of these alloys. Increase of magnesium amounts from 1.0wt% to 3.3wt% in Al-6%Zn-x%Mg-0.5%Cu alloys resulted in reduction of the elongation of these alloys from 12% to 3% and increase of the tensile strength of these alloys from 340MPa to 450MPa, but had little effects on the fluidity of these alloys.