• 제목/요약/키워드: Cu(110)

검색결과 206건 처리시간 0.031초

소결분위기 변환온도가 Al2O3/Cu 나노복합재료의 미세조직과 파괴강도에 미치는 영향 (Effect of Sintering Atmosphere Changing Temperature on Microstructure and Mechanical Property of Al2O3/Cu Nanocomposites)

  • 오승탁;윤세중
    • 한국분말재료학회지
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    • 제11권5호
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    • pp.421-426
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    • 2004
  • The microstructure and mechanical property of hot-pressed $Al_2O_3/Cu$ composites with a different temperature for atmosphere changing from H$_{2}$ to Ar have been studied. When atmosphere-changed from H$_{2}$ to Ar gas at 145$0^{\circ}C$, the hot-pressed composite was characterized by inhomogeneous microstructure and low fracture strength. On the contrary, when atmosphere-changed at low temperature of 110$0^{\circ}C$ the composite showed more homogeneous microstructure, higher fracture strength and smaller deviation in strength. Based on the thermodynamic consideration and microstructural analysis, it was interpreted that the Cu wetting behavior relating to the formation of CuAlO$_{2}$ is probably responsible for strong dependence of microstructure on atmosphere changing temperature. The reason for a strong sensitivity of fracture strength and especially of its deviation to atmosphere changing temperature was explained by the microstructural inhomogeneity and by the role of CuAlO$_{2}$ phase on the interfacial bonding strength.

Ag(001) 표면 위에 놓인 Fe 선의 자성과 전자구조 (First-principles Study on Magnetism and Electronic Structure of Fe Chain on Ag(001))

  • 김영구;이재일
    • 한국자기학회지
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    • 제15권4호
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    • pp.217-220
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    • 2005
  • 제일원리적 에너지 띠 계산 방법인 전 전자 총 퍼텐셜 선형보강평면파동(all-electron full-potential linearized augmented plane ave) 방법에 일반기울기근사(generalized gradient approximation)를 채용하여 Ag(001) 표면 위에 [110] 방향으로 놓인 Fe 선의 전자구조와 자성을 이론적으로 연구하였다. Fe 선의 원자당 자기모멘트는 $3.02\;{\mu}_B$로 Cu(001) 위에 놓인 Fe[110] 선의 값($2.99\;{\mu}_B$) 보다 약간 컸다. Fe 선의 자기모멘트가 상당히 증가한 것은 이웃한 결합수가 줄어들고 그 결과로 Fe-d 전자상태의 띠폭이 줄어들어 국소화 되고 스핀분리가 증가하였기 때문이다. Fe-d 전자상태의 띠 폭은 약 1.6eV였으며 스핀분리는 약 3.2 eV였다.

합금원소 첨가 및 열처리 공정 제어를 통한 Al-7Si-0.35Mg 주조재 합금의 기계적 특성 향상 (Improvement of the Mechanical Properties of Al-7Si-0.35Mg Cast Alloys by the Optimised Combination of Alloying Elements and Heat Treatment)

  • 조영희;이정무;진진우;정재길
    • 한국주조공학회지
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    • 제36권1호
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    • pp.1-9
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    • 2016
  • Improvement of the mechanical properties of a commercial aluminium casting alloy, A356, was achieved through an optimised combination of alloying elements, modification, and heat treatment. 0.7 wt.% Cu and an additional 0.2 wt.% Mg were added to an Al-7Si-0.35Mg alloy for strengthening at both room and elevated temperatures, whilst a subsequent decrease in the ductility was compensated for by the modification of eutectic Si by Sr addition at a level of up to 110 ppm. It was found that the dissolution of Cu-rich or Mg-rich phases could be maximised by solid-solutionising an alloy with 40 ppm Sr at $530^{\circ}C$, increasing the tensile and yield strengths to 350 MPa and 297 MPa, respectively, with a reasonably high strain of 5% after peak-aging at $210^{\circ}C$. Further addition of Sr up to 110 ppm is, however, more likely to interfere with the dissolution of the Cu-rich or Mg-rich phases during solid solution treatment, resulting in a slight decrease in both tensile and yield strengths at room temperature. Besides the Cu addition, such undissolved phases, on the other hand, may contribute to elevated temperature strength at $200^{\circ}C$.

RF 마그네트론 스퍼터링 방법으로 증착된 CuS 박막의 구조적 및 광학적 특성에 대한 스퍼터링 전력의 영향 (Effect of Sputtering Power on Structural and Optical Properties of CuS Thin Films Deposited by RF Magnetron Sputtering Method)

  • 이상운;신동혁;손영국;손창식;황동현
    • Current Photovoltaic Research
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    • 제8권1호
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    • pp.27-32
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    • 2020
  • CuS thin films were deposited on glass substrates at room temperature by RF magnetron sputtering. The structural and optical properties of CuS thin films grown by varying RF-power from 40 W to 100 W were studied. From the XRD analysis, we confirmed hexagonal crystal structures grown in the preferred orientation of the (110) plane in all CuS thin films, and the intensity of the main diffraction peak increased in proportion to the increase of RF-power. In the case of CuS thin film deposited at 40W, small-sized particles formed a thin and dense surface morphology with narrow pore spacing, relatively. As the power increased, the grain size and grain boundary spacing increased sequentially. The peaks for the binding energy of Cu 2p3/2 and Cu 2p1/2 were determined at 932.1 eV and 952.0 eV, respectively. The difference in binding energy for the Cu2+ states was the same at 19.9 eV regardless of process parameters. The transmittance and band gap energy in the visible region tended to decrease with increasing sputtering powers.

공정조성의 SnPb 및 SnAgCu 선형 솔더의 electromigration 특성 평가 (Electromigration charateristics of eutectic SnPb and SnAgCu thin stripe lines)

  • 윤민승;이신복;주영창
    • 한국마이크로전자및패키징학회:학술대회논문집
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    • 한국마이크로전자및패키징학회 2003년도 기술심포지움 논문집
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    • pp.63-67
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    • 2003
  • Electromigration characteristics of $SnAg_3Cu_{0.7}$ and eutectic SnPb solder were studied using thin stripe-type test structures. Significant changes in the microstructure of two solders were observed after electromigration test, in which the temperature and the current density were varied from 90 to $110^{\circ}C$ and from $4.0\times10^4\;A/cm^2\;to\;9.2\times10^4\;A/cm^2$. In SnAgCu solders, hillocks were main]y observed near the anode end. From resistance measurements, it was calculated that the activation energy of the SnAgCu solder for electromigration was 1.04 eV And in eutectic SnPb without the effect of pads, while depleted region was found near cathode end, Sn-rich hillocks were observed near the anode end. During eutectic SnPb electromigration, it were observed that electromigration behavior had two migration modes.

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Synthesis of binary Cu-Se and In-Se nanoparticle inks using cherry blossom gum for CuInSe2 thin film solar cell applications

  • Pejjai, Babu;Reddy, Vasudeva Reddy Minnam;Seku, Kondaiah;Cho, Haeyun;Pallavolu, Mohan Reddy;Le, Trang Thi Thuy;Jeong, Dong-seob;Kotte, Tulasi Ramakrishna Reddy;Park, Chinho
    • Korean Journal of Chemical Engineering
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    • 제35권12호
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    • pp.2430-2441
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    • 2018
  • Selenium (Se)-rich binary Cu-Se and In-Se nanoparticles (NPs) were synthesized by a modified heat-up method at low temperature ($110^{\circ}C$) using the gum exudates from a cherry blossom tree. Coating of CISe absorber layer was carried out using Se-rich binary Cu-Se and In-Se NPs ink without the use of any external binder. Our results indicated that the gum used in the synthesis played beneficial roles such as reducing and capping agent. In addition, the gum also served as a natural binder in the coating of CISe absorber layer. The CISe absorber layer was integrated into the solar cell, which showed a power conversion efficiency (PCE) of 0.37%. The possible reasons for low PCE of the present solar cells and the steps needed for further improvement of PCE were discussed. Although the obtained PCE is low, the present strategy opens a new path for the fabrication of eco-friendly CISe NPs solar cell by a relatively chief non-vacuum method.

Leuconostoc mesenteroides CBI-110에 의한 Alternan의 생산 (Production of Alternan by Leuconostoc mesenteroides CBI-110)

  • 정호권;김광년;이홍석;정선호
    • 한국미생물·생명공학회지
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    • 제27권1호
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    • pp.35-40
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    • 1999
  • Alternan known as a kind of dextran is a linear and cyclic polysaccharide which is synthesized with sucrose by alternaansucrase (EC2.4.1.140) of Leuconostoc mesenteroides. But this polysaccharide is different from dextran in its structure and other properties. For the purpose of applying alternan for the food, cosmetic, and pharmaceutical industries, we isolated an excellent alternan-porducing strain, Leu. mesenteroides CBI-110. The optimum culture conditions were studied to improve the yield, and the activity of alternansucrase was increased up to 33U/ml in the optimum culture media. The concentrations of $Mn^{2+}$ and $Cu^{2+}$ ions were 0.01% and 0.03%, respectively, for the effective production of alternan. Finally, we obtained 25.6g/L of alternan.

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Bi-Sr-Ca-Cu-O계열 초전도체의 초구조 (SUPERSTRUCTURES OF Bi-Sr-Ca-Cu-O SUPERCONDUTORS)

  • 남궁찬;이상윤
    • 한국재료학회지
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    • 제4권3호
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    • pp.268-279
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    • 1994
  • 단일상을 갖는 $Bi_2S_2CaCu_2O_{8+x}$ (2212)의 x-ray 분말 pattern을 a=5.408, c=30.83 $\AA$의 격자상수 및 역격자 벡터 $q^*=0.211b^*-c^*$을 갖는 pseudo tetragonal subcell을 이용하여 모두 index하였다. 임계온도 110K를 갖는 $Bi_2S_2CaCu_2O_{10+x}$ 상은 incommensurate supercell에 속하는 매우 많은 x-ray분말선들을 가지고 있다. Indixing guide로 전자회절사진(electron diffraction photographs)을 이용 x-ray분말 pattern에 대한 지수결정방법을 얻었다.$Bi_2S_2CaCu_2O_{10+x}$(2223)의 단위세표(unit cell)는 기하학적으로 격자상수 a=5.411, b=5.420, c=37.29(2) A을 갖는 orthorhombic subcell이다. Supercell반사 지수들은 subcell의 파 벡터 $\pm q^*=0.211b^*-0.78c^*$을 갖는 k,1지수로부터 영향을 받은 것이다. b 방향으로의 inconnensurate성분 $\delta$는 두 상에 대해 다 같으나, 2212에서 2223 상으로의 변환에 따라 c 방향으로의 초격자성분(superlattic component)은 connensurate($\varepsilon$=1)로부터 incommensurate($\varepsilon$=0.78)로 변한다.

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풍납토성 출토 청동유물의 제작기술 및 납 원료의 산지추정 (Manufacturing technique and provenance Analysis of Bronze Artefacts excavated from Pungnap earthen fortress)

  • 한우림;김소진;한민수;황진주;이은우
    • 헤리티지:역사와 과학
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    • 제48권2호
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    • pp.110-119
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    • 2015
  • 풍납토성은 백제 초기의 토성으로 토기 및 주거유물과 더불어 다량의 청동기가 출토되었다. 본 연구에서는 풍납토성 출토 청동기의 제작기술과 청동기 내에 포함된 납 원료의 산지를 추정하기 위해 출토지가 명확한 7점의 청동기 시편에 대한 분석을 실시하였다. 금속심이 남아있는 4점에 대한 미세조직 및 성분 분석 결과, 3점은 Cu-Sn-Pb의 3원계 합금이며 나머지 1점은 Cu-Sn의 2원계 합금의 청동기로, 조직 내에 뚜렷한 쌍정이 관찰 됨을 확인할 수 있다. 또한 주성분 이외에 S(황), Fe(철)가 검출되어 황동광($CuFeS_2$) 또는 반동광($Cu_5FeS_4$)을 원광석으로 사용하였음을 알 수 있다. 납동위원소비 분석을 이용한 산지 추정 결과 4점의 청동포수, 청동세환 2점, 청동유물 편(나)의 청동기에 산지는 zone 3(충청남 북도, 전라남 북도)의 지역으로 표시되었다. 청동유물 편(라)는 중국 북부로 표시되었으며 청동검은 zone 2(경상남 북도)의 원료를 사용하여 제작하였을 것으로 판단된다.