• 제목/요약/키워드: Crystalline graphite

검색결과 67건 처리시간 0.023초

배향된 판상 기공구조를 통해 열전도도 이방성을 갖는 다공질 재료의 제조 (Fabrication of Porous Materials having an Anisotropic Thermal Conductivity through the Alignment of Plate-shaped Pores)

  • 윤중열;송인혁;김해두
    • 연구논문집
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    • 통권33호
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    • pp.147-155
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    • 2003
  • In order to fabricate porous materials having an anisotropic thermal conductivity by aligning plate-shaped pores structure, alumina powder (AM-21, mean particle size $4\mum$) and flake crystalline graphite was used. The aligned pore structure was realized using multi-pressing process. Degree of pore orientation increased with the number of pressing and thermal conductivity, parallel to the pressing direction, decreased with the number of pressing. Thermal conductivity decreased significantly to the addition of 30vol% crystalline graphite, however, in the case of 60vol%, thermal conductivity did not decrease significantly due to the breakage of crystalline graphite. An anisotropy of the thermal conductivity increased with the content of crystalline graphite up to 30vol%. Graded pore structure was fabricated by controlling the content and size of crystalline graphite, which provides, possibly, the enhancement in mechanical strength and thermal insulation properties of the insulating bricks.

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그라파이트 기판을 이용한 유연 박막 실리콘 태양전지 특성 향상 (Performance Improvement of Flexible Thin Film Si Solar Cells using Graphite Substrate)

  • 임경열;조준식;장효식
    • 한국재료학회지
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    • 제29권5호
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    • pp.317-321
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    • 2019
  • We investigated the characteristics of nano crystalline silicon(nc-Si) thin-film solar cells on graphite substrates. Amorphous silicon(a-Si) thin-film solar cells on graphite plates show low conversion efficiency due to high surface roughness, and many recombination by dangling bonds. In previous studies, we deposited barrier films by plasma enhanced chemical vapor deposition(PECVD) on graphite plate to reduce surface roughness and achieved ~7.8 % cell efficiency. In this study, we fabricated nc-Si thin film solar cell on graphite in order to increase the efficiency of solar cells. We achieved 8.45 % efficiency on graphite plate and applied this to nc-Si on graphite sheet for flexible solar cell applications. The characterization of the cell is performed with external quantum efficiency(EQE) and current density-voltage measurements(J-V). As a result, we obtain ~8.42 % cell efficiency in a flexible solar cell fabricated on a graphite sheet, which performance is similar to that of cells fabricated on graphite plates.

감압조형시 흑연첨가 및 주입온도가 피복상태에 미치는 영향 (The Effect of Graphite Addition and Pouring Temperature on the Coating State in Vaccum Process)

  • 조성준
    • 한국세라믹학회지
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    • 제34권5호
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    • pp.544-551
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    • 1997
  • We tried to improve the coating capability of the coating material using an additive(hexagonal cystalline graphite) of 2%, 3%, 4% and 6% under various pouring temperature for the easy isolation of sand and coating material from the final product. As a result in case of using a 2% and 3% additive generally no burning state has been occurred under the low pouring temperature, but it has been gradually increased with the pouring temperature. On the other hand in case of using a 4% and 6% additive there has been no burning state through out the whole pouring temperature. From this result we could see that the best state of the final product without sand and coating material could generally be obtained if 4% and/or 6% of the crystalline graphite and the pouring temperature of 140$0^{\circ}C$$\pm$5$^{\circ}C$ would be used.

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봉상 카본 발열체의 제조와 열 및 전기적 특성에 관한 연구 (A Study on the Thermal and Electrical Characteristics with Manufacture of the Heating Element by Using Carbon with Bar Type)

  • 배강열;이광성;정한식;정희택;정효민
    • 설비공학논문집
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    • 제16권5호
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    • pp.430-437
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    • 2004
  • This paper is intended as an investigation of study on the thermal and electrical characteristics of the carbon heating element. In this experimentation, the electric material used is the crystalline graphite a kind of natural graphite. The bentonite is used to solidify the heating element and the vacuum furnace is used for sintering it. It is noted that the natural drying time should be at least 58 hours. The plating of the electric pole with the electroless nickel showed the lowest contact resistance among others. The resistance shows linear variation with regard to length. For the insulation and resolution, the glaze coating is best with 80% of water content. The temperature rising characteristic of the heating element is better than sheath heater saving 43% of rising time. The correlation equation for temperature was obtained with the electric power.

A study on the fabrication of poly crystalline Si wafer by vacuum casting method and the measurement of the efficiency of solar cell

  • Lee, Geun-Hee;Lee, Zin-Hyoung
    • 한국결정성장학회지
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    • 제12권3호
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    • pp.120-125
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    • 2002
  • Si-wafers for solar cells were cast in a size of $50{\times}46{\times}0.5{\textrm}{mm}^3$ by vacuum casting method. The graphite mold coated by BN powder, which was to prevent the reaction of carbon with the molten silicon, was used. Without coating, the wetting and reaction of Si melt to graphite mold was very severe. In the case of BN coating, SiC was formed in the shape of tiny islands at the surface of Si wafer by the reaction between Si-melt and carbon of the graphite mold on the high temperature. The grain size was about 1 mm. The efficiency of Si solar cell was lower than that of Si solar cell fabricated on commercial single and poly crystalline Si wafer. The reason of low efficiency was discussed.

반응소결 SiC-graphite 복합체의 마찰마모특성 (Tribological Properties of Raction-Bonded SiC-Graphite Composites)

  • 백용혁;신종윤;곽효섭;박용갑
    • 한국세라믹학회지
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    • 제33권5호
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    • pp.479-484
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    • 1996
  • The tribological properties of ceramics are very important in the application to engineering ceramic parts such as mechanical seal slurry valve disc and so on. In this study the effect of graphite addition on the mechanical and tribological properties of RBSC/graphite composites were investigated. The composites were prepared by adding graphite powder to the mixture of SiC powder metallic siliconcarbon black and alumina. Bending strength water absorption friction coefficient the amount of worn out material at a certain time and maximum surface roughness(Rmax) of the prepared composites were measured and crystalline phases were examined with XRD. The composite containing 5 vol% graphite powder showed improved bending strength due to high green density and decreased friction coefficient and wear resistance. The friction coefficient and the wear resistance of the composite were increased by adding graphite powder up to 10 vol% They decreased however as increasing the amount of graphite powder more that 10vol% There was no linear relationship between the tribological properties and bending strength of the composites.

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Alumina/graphite 복합체의 마찰마모 특성 (Tribological Properties of Alumina/Graphite Composites)

  • 백용혁;정종인;박용갑;김주영
    • 한국세라믹학회지
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    • 제34권4호
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    • pp.380-386
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    • 1997
  • The tribological properties of ceramics are very important in the application to engineering ceramic parts such as seal rings, pump parts, thread guides, and so on. In this study, the effects of graphite addition on the mechanical and tribological properties of alumina/graphite composites were investigated. The composites were prepared by the adding of graphite powder to the mixture of Al2O3, talc and calcium carbonate. Bending strength, water absorption, friction coefficient, the amount of worn out material at a certain time, and maximum surface roughness(Rmax) of the prepared composites were measured. Crystalline phases and microstructure were examined with XRD and SEM. The melt of Al2O3-CaO-MgO-SiO2 system was shown over 10 vol% graphite composition. As the amount of the graphite is increased, needle like crystals of mullite were formed and grown. We obtained the good properties of friction coefficients and wear resistance at the powder composition containing 15 vol% of graphite.

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Chemical Reaction between Aluminium and graphite Crucible During the Fabrication of Spherical Monosized Al particles

  • Kwon, Hansang
    • 한국분말재료학회지
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    • 제25권2호
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    • pp.99-103
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    • 2018
  • Spherical monosized pure aluminum (Al) particles are successfully fabricated by the pulsated orifice ejection method (POEM). The surface reaction between Al and the graphite crucible is investigated by analysing the microstructure and chemical composition of the materials. No significant chemical reaction occurs between Al and the graphite owing to the crystalline Al oxide (${\gamma}-Al_2O_3$) layer generated in the initial state. The ${\gamma}-Al_2O_3$ layer is clearly observed in all regions between the Al particles and graphite via transmission electron microscopy and confirmed by the selected area diffraction pattern. The morphology of the ${\gamma}-Al_2O_3$ layer perfectly follows the surface morphology of the graphite crucible, which showed nanoscale roughness. This implies that molten Al could not directly contact graphite even though the surface of the crucible became rough to some extent. However, this passivation phenomenon allowed the successful fabrication of monosized pure Al particles. Therefore, POEM is a useful process at least to manufacture monosized pure Al particles.

Graphite상의 ZnO Nanorod성장과 그를 이용한 Schottky Diode 제작

  • 남광희;백성호;박일규
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.421.2-421.2
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    • 2014
  • We report on the growth of ZnO nanorods (NRs) grown on graphite and silicon substrates via an all-solution process and characteristics of their heterojunctions. Structural investigations indicated that morphological and crystalline properties were not significantly different for the ZnO NRs on both substrates. However, optical properties from photoluminescence spectra showed that the ZnO NRs on graphite substrate contained more point defects than that on Si substrate. The ZnO NRs on both substrates showed typical rectification properties exhibiting successful diode formation. The heterojunction between the ZnO NRs and the graphite substrate showed a Schottky diode characteristic and photoresponse under ultraviolet illumination at a small reverse bias of -0.1 V. The results showed that the graphite substrate could be a good candidate for a Schottky contact electrode as well as a conducting substrate for electronic and optoelectronic applications of ZnO NRs.

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감압 조형시 흑연 첨가 및 주입 온도가 피복 상태에 미치는 영향(II) (The Effect of Graphite Addition and Pouring Temperature on the Coating State in Vaccum Process(II))

  • 조성준;임굉;김영백
    • 공학논문집
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    • 제2권1호
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    • pp.151-164
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    • 1997
  • 주형사 및 피복제의 용이한 분리를 위해 다양한 주입온도하에서 2%, 3%, 4% 및 6%의 첨가제(인상흑연)를 첨가하여 피복성능을 개선시켜 주고자 하였다. 실험결과 국산 피복제에 인상흑연을 2%와 3% 첨가하였을 경우 낮은 주입온도영역하에서는 대체적으로 소착현상이 발생하지 않았으나, 주입온도가 올라 감에 따라 소착현상 역시 점점 증가하였다. 반면에 일산 피복제에 인상흑연을 2%와 3% 첨가하였을 경우에는 전체 주입온도영역에 걸쳐 다량의 소착이 발생하였다. 4%와 6%의 인상흑연을 첨가한 경우에는 전체 주입온도영역에 걸쳐 소착현상이 거의 일어나지 않았다. 이러한 결과로부터 적절한 주입온도와 적당량의 첨가제를 사용함으로써 도형 성능을 개선해 줄 수 있음이 확인되었으며, 소착발생을 방지하기 위한 가장 적절한 첨가제의 양으로는 4-6%, 주입온도로는 $1400^{\circ}C$$\pm$$5^{\circ}C$가 됨을 알 수 있었다.

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