• Title/Summary/Keyword: Crystalline VOx

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Effect of Vanadium Surface Density of SCR Catalyst on Reaction Activity and SO2 Durability (상용 SCR 촉매의 바나듐 표면밀도가 반응활성 및 SO2 내구성에 미치는 영향연구)

  • Won, Jong Min;Park, Kwang Hee;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.28 no.2
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    • pp.158-164
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    • 2017
  • In this study, the reaction activity and XRD, BET, and Raman analysis were performed to verify $NH_3$-SCR reaction characteristics of various commercial SCR catalysts. It can be seen that the reaction rate of each commercial SCR catalyst increased linearly with increasing the vanadium content (1.3-5.4 wt%). In addition, through the above analysis, it was possible to confirm that the addition of WOx in the catalyst increased the Turn over frequency (TOF) within the range where the VOx surface density was more than 8.1 and the crystalloid VOx was not formed through the surface structure analysis. $SO_2$ durability tended to decrease with increasing the vanadium content, and the durability increased the most when W and Si were added.