• Title/Summary/Keyword: Crystal plasticity

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Phase Transition and ionic Conductivity of Cesium Hydrogen Sulfate-PAN Composites (황산수소 세슘-PAN 복합체의 상전이와 이온 전도성)

  • 최병구;박상희
    • Polymer(Korea)
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    • v.28 no.2
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    • pp.149-153
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    • 2004
  • The cesium hydrogen sulfate (CsHSO$_4$) crystal is a superprotonic conductor above 140$^{\circ}C$ and possesses protonic conductivity three to low orders of magnitude higher than that at room temperature. Recently, the possibility of it as an electrolyte material for fuel cell system draws much attention. However, its plasticity and absorption of humidity place a limitation on its application. In this study, composites consisting of CsHSO$_4$ and polyacrylonitrile were prepared, and their phase transition properties and the ionic conductivities were evaluated. When the content of CsHSO$_4$ was about 80 vol%, a mechanically strong film with the protonic conductivity of 1${\times}$10$\^$-3/ Scm$\^$-1/ were made.

A Study on the Surface Characteristics of Injection Mold and Injection Molded Part depending on LGP-Mold Fabrication Methods (도광판 금형의 제작 방법에 따른 사출금형 및 성형품의 표면특성에 관한 연구)

  • Do, Y.S.;Kim, J.S.;Ko, Y.B.;Kim, J.D.;Yoon, K.H.;Hwang, C.J.
    • Transactions of Materials Processing
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    • v.16 no.8
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    • pp.596-602
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    • 2007
  • LGP (Light Guiding Plate) of LCD-BLU (Liquid Crystal Display - Back Light Unit) is one of the major components that affect the product quality of LCD. The optical patterns of LGP(2.2") molds are fabricated by three different methods, namely, (1) laser ablation, (2) chemical etching and (3) LiGA-reflow, respectively. The characteristics of surface patterns and roughnesses of molds and injection molded parts were compared to evaluate the optical characteristics. The optical patterns of injection molded LGP with mold fabricated by LiGA - reflow method showed the best geometric structure. The surface roughness (Ra) of LGP#s with molds fabricated by (1) laser ablation: $Ra={\sim}31nm$, (2) chemical etching: $Ra={\sim}22nm$, and (3) LiGA-reflow: $Ra={\sim}4nm$.

Localized Necking in a Round Tensile Bar for a HCP Material Considering Tension-compression Asymmetry in Plastic Flow (소성 비대칭성을 갖는 HCP 소재의 국부변형 및 네킹해석)

  • Yoon, J.H.;Lee, J.H.
    • Transactions of Materials Processing
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    • v.21 no.5
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    • pp.285-290
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    • 2012
  • In spite of progress in predicting ductile failure, the development of a macroscopic yield criterion to describe damage evolution in HCP (hexagonal close-packed) materials remains a challenge. HCP materials display strength differential effects (i.e., different behavior in tension versus compression) in their plastic response due to twinning. Cazacu and Stewart(2009) developed an analytical yield criterion for porous material containing randomly distributed spherical voids in an isotropic, incompressible matrix that shows tension-compression asymmetry. The goal of the calculations in this paper is to investigate the effect of the tension-compression asymmetry on necking induced by void nucleation, evolution and consolidation. In order to investigate the effect of the tension-compression asymmetry of the matrix on necking and fracture initiation, three isotropic materials A, B, and C were examined with different ratios of tension-compression asymmetry. The various types of material had BCC, FCC, and HCP crystal structures, respectively. The ratio between tension and compression in plastic flow significantly influences the fracture shape produced by damage propagation as well as affecting the localized neck.

Molding Stability of Hydro-Mechanical High Speed Injection Molding for Thin-Wall(0.3mm) LGP (박판(0.3mm) 도광판 성형을 위한 유압식 고속사출성형의 성형 안정성 연구)

  • Hwang, C.J.;Kim, J.S.;Oh, J.G.;Jeong, C.;An, H.J.;Heo, Y.M.;Kim, J.D.;Yoon, K.H.
    • Transactions of Materials Processing
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    • v.17 no.8
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    • pp.657-661
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    • 2008
  • Recently, products of electronic industry and related parts are required to have the thickness thinner and thinner to reduce the part weight. To go with this trend, LGP(light guide plate) of LCD-BLU(Liquid Crystal Display-Back Light Unit: It is one of kernel parts of LCD) for cell phone has the thickness of ${\sim}0.3mm$ and the battery case of cell phone has ${\sim}0.25mm$. Accordingly, high speed injection molding is required to mold products which have thinner parts. To achieve high speed injection and proper control of hydraulic unit, various design was applied to conventional injection unit. In the present paper, we concentrated on the molding stability of hydro-mechanical high speed injection machine to make an LGP of 0.3mm thickness.

Texture Evolution of Extruded AZ80 Mg Alloy under Various Compressive Forming Conditions (AZ80 마그네슘 합금 압출재의 압축 성형조건에 따른 방위특성 분석)

  • Yoon, J.H.;Lee, S.I.;Lee, J.H.;Park, S.H.;Cho, J.H.
    • Transactions of Materials Processing
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    • v.21 no.4
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    • pp.240-245
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    • 2012
  • With the increasing demand for light-weight materials to reduce fuel consumption, the automobile industry has extensively studied magnesium alloys which are light weight metals. The intrinsic poor formability and poor ductility at ambient temperature due to the hexagonal close-packed (HCP) crystal structure and the associated insufficient number of independent slip systems restricts the practical usage of these alloys. Hot working of magnesium alloys using a forging or extrusion enables net-shape manufacturing with enhanced formability and ductility since there are several operative non-basal slip systems in addition to basal slip plane, which increases the workability. In this research, the thermomechanical properties of AZ80 Mg alloy were obtained by compression testing at the various temperatures and strain rates. Optical microscopy and EBSD were used to study the microstructural behavior such as misorientation distribution and dynamic recrystallization. The results were correlated to the hardening and the softening of the alloy. The experimental data in conjunction with a physical explanation provide the optimal conditions for net-shape forging under hot or warm temperatures through control of the grain refinement and the working conditions.

Mechanical Behavior and Physical Properties of Zr-Ti-Cu-Ni-Be Amorphous and Partially Crystallized Alloy Extracted from a Commercial Golf Club Head (Zr-Ti-Cu-Ni-Be 합금으로 제조된 상용 골프클럽헤드의 부위별 물리적 특성 및 기계적 거동)

  • Choi, Young-Chul;Hong, Sun-Ig
    • Korean Journal of Materials Research
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    • v.15 no.11
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    • pp.697-704
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    • 2005
  • The deformation behavior of a bulk amorphous and crystallized amorphous $Zr_{22.5}Ti_{14}Cu_{12.5}Ni_{10}Be_{22.5}$ alloy extracted from a commercial golf club head was characterized at room temperature ana $300^{\circ}C$. At room temperature, amorphous specimens revealed higher yield stress and ductility than partially crystallized alloy specimens. Amorphous alloy displayed some plasticity before fracture, which resulted from strain hardening and repeated crack initiation and propagation. The fracture is mainly localized on one major shear band, and the compressive fracture angle of the amorphous specimen between the stress axis and the fracture plane was about $40^{\circ}$ Scanning electron microscope observations revealed mainly a vein-like structure in the amorphous alloy But the fracture surface of partially crystallized amorphous alloy consisted of vein-like and featureless fracture structure. The partially crystallized alloy extracted from the thick part of the club fractured in the elastic region, at a much lower stress level than the amorphous, suggesting that relatively coarse crystal particles formed during cooling cause the brittle fracture.

Effect of Interesterified Lard for the Preparation of Pie Crust (에스테르화 라아드가 파이 껍질 제조에 미치는 영향)

  • Kim, Myoung-Ae
    • Korean Journal of Food Science and Technology
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    • v.24 no.3
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    • pp.251-255
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    • 1992
  • Lard was randomly interesterified to improve handling efficiency with increase of plasticity, and it's physicochemical properties and adaptability for making pie were investigated. Fatty acid and triacylglycerol composition were not changed after interesterification. Interesterified lard could be useful during winter because the handling was convenient due to drop in the temperature range of $18{\sim}23.5^{\circ}C$ in lard and $13{\sim}19.5^{\circ}C$ in interesterified lard with SFI $15{\sim}25$. Interesterified lard was decreased in the extensibility by change of crystal form, and not suitable for making pie as the inferior characters for layers forming, appearance and shortness. But interesterified lard mixed with plastic fat of high extensibility showed the possibility of making pie, and the maximum mixture ratio was 50% for good pie quality.

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Finite Element Analysis and Experimental Verification for the Cold-drawing of a FCC-based High Entropy Alloy (FCC계 고엔트로피 합금의 냉간 인발 유한요소해석 및 실험적 검증)

  • Cho, H.S.;Bae, S.J.;Na, Y.S.;Kim, J.H.;Lee, D.G.;Lee, K.S.
    • Transactions of Materials Processing
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    • v.29 no.3
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    • pp.163-171
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    • 2020
  • We present a multi-step cold drawing for a non-equiatomic Co10Cr15Fe25Mn10Ni30V10 high entropy alloy (HEA) with a simple face-centered cubic (FCC) crystal structure. The distribution of strain in the cold-drawn Co10Cr15Fe25Mn10Ni30V10 HEA wires was analyzed by the finite element method (FEM). The effective strain was expected to be higher as it was closer to the surface of the wire. However, the reverse shear strain acted to cause a transition in the shear strain behavior. The critical effective strain at which the shear strain transition behavior is completely shifted was predicted to be 4.75. Severely cold-drawn Co10Cr15Fe25Mn10Ni30V10 HEA wires up to 96% of the maximum cross-sectional reduction ratio were successfully manufactured without breakage. With the assistance of electron back-scattering diffraction and transmission electron microscope analyses, the abundant deformation twins were found in the region of high effective strain, which is a major strengthening mechanism for the cold-drawn Co10Cr15Fe25Mn10Ni30V10 HEA wire.

A Study on the Simulation and DSF Molding of V-groove Type Light Guide for a Backlight Unit (백라이트 유닛용 V-그루브 도광판의 전산모사 및 DSF성형에 관한 비교연구)

  • Cho K. H.;Yoon K. H.
    • Transactions of Materials Processing
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    • v.14 no.3 s.75
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    • pp.282-290
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    • 2005
  • Nowadays, TFT-LCD is widely used as display unit of many digital devices. And, the backlight unit(BLU) is used as a light source of TFT-LCD module. In the backlight unit, the most important component is a light guide, which guides the input light to the TFT-LCD module uniformly. Recently, many researchers have focused on improving the efficiency of BLU by changing the design and structure of a light guide. In the present paper, a series of simulation was performed to find the optimal luminance distribution of emanated light from the given geometry as the first step. From the results of simulations for the light guide with given V-groove pattern, the emanated light from it is mostly affected by the groove angle. In the case of acute angle, about 74 degrees was found as optimal angle to satisfy the restrictions of angular luminance distribution, FWHM, the maximum luminance, etc. However, as far as the average luminance value was concerned, the case of 120 degrees(abtuse angle) was found to be the best while prism films were added to the BLU. As a next step the light guide samples of 74 and 120 degrees were manufactured by DSF method, which was recently proposed by the authors. Of course, most of design parameters were chosen by the aid of simulation results. Finally, the results of average luminance values were compared between the simulation and DSF molded samples.

Mechanical and Thermal Conductivity Properties of Yttrium Nitrate Added AlN Sintering Body (Y(NO3)3·6H2O 첨가된 AlN 소결체의 기계적 및 열전도도 특성)

  • Chung, J.K.;Lee, J.H.;Ha, T.K.
    • Transactions of Materials Processing
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    • v.27 no.1
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    • pp.48-53
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    • 2018
  • Aluminum nitride (AlN) is used by the semiconductor industry that has requirements for high thermal conductivity. The theoretical thermal conductivity of single crystal AlN is 320W/mK. Whereas, the values measured for polycrystalline AlN ceramics range from 20 W/mK to 280 W/mK. The variability is strongly dependent upon the purity of the starting materials and non-uniform dispersibility of the sintering additive. The conventional AlN sintering additive used yttria ($Y_2O_3$), but the dispersibility of the powder in the mixing process was important. In this study, we investigated the mechanical and thermal conductivity of yttrium nitrate ($Y(NO_3)_3{\cdot}6H_2O$), as a sintering additive in order to improve the dispersibility of $Y_2O_3$. The sintering additives content was in the range of 2 to 4.5wt.%. The density of AlN gradually increased with increasing contents of sintering additive and the flexural strength gradually increased as well. The flexural strength of the sintered body containing 4 wt% of $Y_2O_3$ and $Y(NO_3)_3{\cdot}6H_2O$ was 334.1 MPa and 378.2 MPa, respectively. The thermal conductivities were 189.7W/mK and 209.4W/mK, respectively. In the case of hardness, there was only a slight difference and the average value was about 10 GPa. Therefore, densification, density and strength values were found to be proportional to its content. It was confirmed that AlN using $Y(NO_3)_3{\cdot}6H_2O$ displayed relatively higher thermal conductivity and mechanical properties than the $Y_2O_3$.