• 제목/요약/키워드: Crystal phase

검색결과 1,919건 처리시간 0.041초

Novel Phase States in Highly Charged Colloidal Suspensions

  • Terada Y.;Muramoto K.;Tokuyama M.
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2003년도 The Fifth Asian Computational Fluid Dynamics Conference
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    • pp.19-20
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    • 2003
  • Brownian-dynamics simulation on highly charged colloidal suspensions is performed by employing Tokuyama effective force recently proposed. The radial distribution function suggests that there exist three novel phases, a gas phase, a liquid droplet phase, and a face-centered cubic (FCC) crystal droplet phase, depending on the minimum values of that potential. The dynamics of droplet growth is also investigated both in liquid droplet phase and in crystal droplet phase. Thus, different types of characteristic growth stages are found.

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Crystal pulling법에 의한 Bi-Sr-Ca-Cu-O계의 결정 성장과 특성 평가 (Growth and characterization of a Bi-Sr-Ca-Cu-O phase by crystal pulling method)

  • 윤대호;좌등혜유;길본칙지;길택정인
    • 한국결정성장학회지
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    • 제7권1호
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    • pp.1-5
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    • 1997
  • $Bi_2Sr_2Ca_{n-1}Cu_nOy$(BSCCO)계는 강한 이방성의 움직임을 갖는 초전도체로서 잘 알려져 있으며, 결정육성시 성장방향의 제어에 큰 어려움이 있다. 본 연구에서는 종자 결정과 도가니의 회전을 이용한 crystal pulling법을 이용하여 Bi-Sr-Ca-Cu-O계의 결정성장을 시도하였으며, 이로부터 $5{\times}5{\times}5{\textrm}{mm}^3$ 크기의 비교적 큰 결정을 성장하였. 또한 성장결정의 초전도 특성을 조사하였으며, $BiO_{1.5}$ -(Sr, Ca)O-CuO 3원 상태도에서의 결정화 가능 영역을 검토하였다.

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표면상변이의 강인력 의존성 : 점유통계를 이용한 정성적 고찰 (On the strong attractive force dependence of the surface phase transition : Qualitative consideration from the occupation statistics)

  • 김철호
    • 한국결정성장학회지
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    • 제7권4호
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    • pp.573-577
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    • 1997
  • 표면상변이 현상은 표면 흡착입자들 사이에 강력한 인력포텐셜이 존재할 경우 일어나는 것으로 알려져 있다. 본 논문에서는 표면상변이 현상의 강인력 의존성을 간단한 점유통계를 이용하여 고찰하였다. 압력이 임계점에 도달하였을 때 표면 결정화가 급속히 진행되는 상변이 효과가 나타났으며, 온도가 증가함에 따라서 상변이가 일어나는 임계압력은 증가하였다. 이러한 결과는 표면상변이 현상에 대한 정성적 고찰로 사료된다.

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X-ray Scattering Studies for Phase Separated Composite Organic Films

  • Choi, H.;Eom, K.E.;Wang, Q.;Kumar, S.;Kim, J.H.;Shin, S.T.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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    • pp.1229-1232
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    • 2004
  • The ratio of optimized concentration on optical characteristics for phase-separated composite organic films (PSCOF) liquid crystal display is 30% of pre-polymer (NOA65) and 70% of ferroelectric liquid crystal (Felix). The layer structure in ferroelectric liquid crystal cell made by 30% NOA65 and 70% Felix materials is tilt-bookshelf layer structure. The angle of tilt-bookshelf structure are 17$^{\circ}$, 12$^{\circ}$ which are almost same of tilt angle of ferroelectric liquid crystal in Sm $C^{\ast}$ phase. We know that this result is from compensating the layer buckling. In this paper, we will discuss the effect of layer structure in PSCOF cell on ratio of concentration between pre-polymer and liquid crystal by x-ray measurements. We believe that technology of PSCOF is a good solution to solve the problems of align-defect and mechanical shock for future TV application and plastic LCD.

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Formation of 3-Dimensional Networks of Colloidal Particles in a Nematic Host

  • West, John L.;Glushchenko, Anatoliy;Zhang, Ke;Reznikov, Yuri
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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    • pp.191-192
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    • 2002
  • We reported pushing of colloidal particles by a moving isotropic-nematic phase boundary. Here, we report tailoring the structure of 3-dimensional networks formed by these particles by adjusting the rate of phase transition and by application of an electric field. The resulting networks affect the electro-optic performance of liquid crystal devices.

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KAlSiO4의 단결정 합성 및 동질 다상 (Synthesis of Single Crystal and Polymorphism of KAlSiO4)

  • 박병규;정수진
    • 한국세라믹학회지
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    • 제25권1호
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    • pp.73-77
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    • 1988
  • Single crystals of kalsilite were synthesized by hydrothermal method at 420$^{\circ}C$-480$^{\circ}C$ and 100 atm-1500 atm. The crystal habits are similar to those of KLiSiO4 single crystals. The crystal structure was investigated by means of X-ray single crystal diffraction. The space group of kalsilite is P63. Phase transitiions were determined by use of DTA and high temperature X-ray Guinier camera. Phase transitions of kalsilite are summerized and discussed.

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Thin film growth by charged clusters

  • Hwang, N.M.
    • 한국결정성장학회:학술대회논문집
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    • 한국결정성장학회 1998년도 PROCEEDINGS OF THE 15TH KACG TECHNICAL MEETING-PACIFIC RIM 3 SATELLITE SYMPOSIUM SESSION 4, HOTEL HYUNDAI, KYONGJU, SEPTEMBER 20-23, 1998
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    • pp.33-33
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    • 1998
  • Invisible charged clusters are suggested to form in the gas phase and to become the growth unit in the thin film process. Similar suggestion had been made by Glasner el al. in the crystal growth of KBr and KCL in the solution where the lead ions were added. The charged cluster model, which was suggested in the diamond CVD process by our group, will be extended to the other thin film processes. It will be shown based on both the theoretical analysis and the experimental evidences that the charged clusters are formed in the gas phase and become the growth unit of the crystal in the thin film process.

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MgO가 첨가된 (Ca,Sr)(Zr,Ti)O3의 결정구조, 미세구조 및 저손실 유전특성 (Crystal structure, microstructure, and low-loss dielectric property of MgO-added (Ca,Sr)(Zr,Ti)O3)

  • 이도혁;문경석
    • 한국결정성장학회지
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    • 제33권6호
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    • pp.261-267
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    • 2023
  • 마이크로파 유전체 적용을 위해 (Ca, Sr)(Zr, Ti)O3 (CSZT) 계에서 MgO 첨가에 따른 결정 구조, 미세 구조, 및 유전 특성을 연구하였다. 고상 반응법을 통해 합성된 CSZT 분말은 orthorhombic 단일상을 형성하였다. CSZT의 시편을 각각 1200℃, 1300℃ 및 1400℃에서 소결하였고, 소결 후 모든 시편은 orthorhombic 단일상을 확인하였다. 또한 모든 소결 시편은 온도가 증가함에 따라 입자 크기가 증가하였다. 1 mol% MgO를 첨가한 시편의 경우도 소결 이후에 orthorhombic 구조를 갖는 것을 확인하였다. EDS 분석을 통해 1400℃에서 소결 중에 이차상이 형성된 것을 확인하였다. MgO 첨가된 CSZT의 입자크기분포와 치밀화는 첨가하지 않은 경우와 거의 유사했으나, 입자크기분포가 좁아지며 균일해지는 것을 확인하였다. MgO 첨가된 CSZT는 1 k Hz에서 εr = 34.14, tanδ = 0.00047, τε = -3.58 ppm/℃로 우수한 저손실 유전 특성을 가졌다.

Phase Transformation of Sn-Pb-Bi Solder for Photovoltaic Ribbon: A Real-time Synchrotron X-ray Scattering Study

  • Cho, Tae-Sik
    • Transactions on Electrical and Electronic Materials
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    • 제15권3호
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    • pp.155-158
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    • 2014
  • The phase transformation of Sn-Pb-Bi solder for photovoltaic ribbon during soldering was studied using real-time synchrotron x-ray scattering. At room temperature, Sn and Pb crystal phases in the solder existed separately. By heating to $92^{\circ}C$, a new PbBi alloy crystal phase was formed, which grew further up to $160^{\circ}C$. The Sn crystal phase first started to melt at $160^{\circ}C$, and was mostly melted at $165^{\circ}C$. In contrast, the Pb and PbBi crystal phases started to melt at $165^{\circ}C$, and were mostly melted at $170^{\circ}C$. The useful result was obtained, that the solder's melting temperature decreased from $183^{\circ}C$ to $170^{\circ}C$ by addition of a small amount of Bi atoms to the eutectic Sn62-Pb38 (wt%) solder. Our study first revealed the detailed in-situ phase transformation of Sn-Pb-Bi solder during heating to the eutectic temperature. Considering the results of peel strength and hardness, adding 1 wt% of Bi atoms to the Sn62-Pb38 (wt%) solder produced an appropriate composition.