• Title/Summary/Keyword: Cross-linking agent

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Study on Property Modification with Polymer Compositions in the Manufacture of Compounds for Cable Sheath

  • Li, Xiang Xu;Lee, Sang Bong;Cho, Ur Ryong
    • Elastomers and Composites
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    • v.54 no.3
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    • pp.220-224
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    • 2019
  • Herein, three polymer compounds were manufactured using three polymer combination methods, ethylene-vinyl acetate/ethylene-propylene-diene-copolymer (EPDM), ethylene-vinyl acetate (EVA)/polyethylene-A (PE-A; density: 0.870), and ethylene-vinyl acetate (EVA)/polyethylene-B (PE-B; density: 0.885), for making cable sheath for use in the shipping industry. In this study, EVA, EPDM, PE-A, and PE-B were used as matrix polymers, and EVA-grafted maleic anhydride was used as a coupling agent for compounding with various compounds such as a fire retardant, cross-linking agent, filler, and other additives, besides the plasticizer. ${\Delta}T$, Mooney viscosity, and tensile strength increased in order of EPDM < PE-A < PE-B, the probable reason is due to the different crosslinking effect. The three compounds showed similar results for fire resistance and aging resistance after compounding process, but they showed excellent cold resistance owing to the non-polarity of the polymers and sufficient plasticizer content.

Preparation and Properties of Silicone Hydrogel Material Containing Silane Group with Cobalt Oxide Nanoparticles through Thermal Polymerization

  • Lee, Min-Jae;Kong, Ki-Oh;Sung, A-Young
    • Korean Journal of Materials Research
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    • v.30 no.6
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    • pp.273-278
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    • 2020
  • This research is conducted to analyze the compatibility of used monomers and produce the high functional hydrogel ophthalmic polymer containing silane and nanoparticles. VTMS (vinyltrimethoxysilane), TAVS [Triacetoxy(vinyl)silane] and cobalt oxide nanoparticles are used as additives for the basic combination of SilM (silicone monomer), MMA (methyl methacrylate) and MA (methyl acrylate). Also, the materials are copolymerized with EGDMA (ethylene glycol dimethacrylate) as cross-linking agent, AIBN (thermal polymerization initiator) as the initiator. It is judged that the lenses of all combinations are optically excellent and thus have good compatibility. Measurement of the optical and physical characteristics of the manufactured hydrophilic ophthalmic polymer are different in each case. Especially for TAVS, the addition of cobalt oxide nanoparticles increases the oxygen permeability. These materials are considered to create synergy, so they can be used in functional hydrogel ophthalmic lenses.

Synthesis of Inner Vacant Polymer Spheres (속이 빈 구형의 고분자 합성)

  • 배아현;김동원;권수한;신재섭
    • Polymer(Korea)
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    • v.25 no.5
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    • pp.754-758
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    • 2001
  • In order to use vesicle as a space of polymerization, monomer and cross-linking agent were put into hydrophobic part of vesicle. The vesicle solution of dimethyldioctadecylammonium bromide was formed by ultrasonication. Styrene and divinylbenzene were put into this solution and polymerization was conducted by adding AIBN. The polymer with sphere-shaped structure was obtained by removing all of the surfactant by extraction of ethanol And using methyl methacrylate and ethylene glycol dimethacrylate, this sphere-shaped polymer structure was also formed.

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Properties of Current due to Voltage in Heat Conductive Silicone Rubber (열전도성 실리콘 고무의 전압-전류 특성)

  • Lee, Sung-Ill
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.9
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    • pp.576-581
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    • 2014
  • This study used the heat conductive silicone rubber sample of 0.95 mm thickness to research the properties of current by changing voltage. When the 1, 10, 30, 60, and 90 minute have passed, the running current has been measured through the applied voltage range of 200 V~800 V on setting temperature of $110^{\circ}C{\sim}170^{\circ}C$. As the temperature increased in applied voltage of 800 V, so did the current value according to time in proportion to the increasing temperature. In an analysis of FT-IR (fourier transform infrared) spectrum, the hydroxyl radicals group(O-H) was created by effects of the hydrogen that methyl group is eliminated by addition of the cross-linking agent peroxide.

Hybridization and Functionalization of Aqueous-based Polyurethanes

  • Chen, Kan-Nan
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.129-129
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    • 2006
  • Conventional solvent-based polyurethane (PU) is well established for wide applications, such as textile treatments, surface coating, adhesive and so on. Due to the demands of safety, economic, and environmental protection, the solvent-based PU is restricted and has been phasing out and aqueous-based PU is becoming the world market trend, which is an environmental friendly product. The chemical resistance, physical and mechanical properties of aqueous-based PU are still not competible with solvent-based PU. Because of aqueous-based PU is a linear thermoplastic polymer with lower average molecular weight. Their improvements are normally performed by a post-curing reaction or a polymer hybridization to enhance the polymer cross-linking density. Hybridization of PU with aqueous-based epoxy resin or acrylate emulsion and then cured by a curing agent for improving the performance properties and reducing the cost of aqueous-based PU.Furthermore, a special function is added to aqueous-based PU increasing the application value, for examples, flame retardation, polymeric dyes, hydrophilic and etc.

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Low temperature curable organic gate insulator for organic field-effect transistors

  • Kim, Joo-Young;Jung, Myung-Sup;Lee, Sang-Yoon;Kim, Jong-Min;Kim, Jang-Joo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.664-666
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    • 2008
  • Low-temperature curable organic insulator was prepared through blending of polyimide type base resin and cross-linking agent. The newly developed resin can be formed into films using a wet process and cured at $130^{\circ}C$. Using the low temperature cured film as the gate dielectric layer, the field effect mobility of $0.15\;cm^2/V{\cdot}s$ was obtained from a pentacene field effect transistor in the saturation regime and no hysteresis behavior was observed in transfer curves.

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Preparation of Chitosan Microcapsules by Using Microreactor

  • Takehara, Kohsuke;Kuwahara, Yutaka;Takafuji, Makoto;Sawada, Tsuyoshi;Ihara, Hirotaka;Shosenji, Hideto;Park, Soo-Min
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2008.10a
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    • pp.41-42
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    • 2008
  • Chitosan microcapsules were prepared by microreactor method and conventional batch method using glutaraldehyde as a cross-linking agent and L-a-phosphatidylcholine as an emulsifier. The mean particle sizes of microcapsules prepared by microreactor and batch method were 1.10 and 1.96 mm, respectively. The former microcapsules showed narrower size distribution than those of the latter one.

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ANOVA for Water Repellent Finish data (발수가공 데이터의 분산분석)

  • Yun, Jung-Beom
    • Journal of Korean Society for Quality Management
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    • v.16 no.1
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    • pp.43-48
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    • 1988
  • Most of silicone used for water repellent finish is MHP (methyl hydrodiene polysiloxane), which is formed by hydrolysis and condensation polymerization of MHD (methyl hydrodiene dichlorosilane: Me H Si $Cl_2$). The cross-linking theory explains the water repellent mechanism of MHP. The silicone finish on fiber could improve in handle, softness, abrasion resistance, soil repellency, tear strength and crease resistance, as well as water repellency. According to using method silicone-water repellent finishing agents, could be devided into air dry type and curing type. MHP is the typical curing type of water repellent finishing agent, and this type requires the curing temperature above $150^{\circ}C$ at least. High curing temperature is the very drawback of this curing type. For this reason, there has been global interest in the lowering of its temperature. The objective of this study is to investigate merits of alkali treatment for silicone finishing by ANOVA and LSD (least significant difference).

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Identification of Interleukin-l Like Material in Streptornyces Culture Supernatant (Streptomyces 배양액에서의 Interleukin-1 유사물질의 동정)

  • 남명수;배윤수;윤도영;남경수;최인성;정태화
    • Microbiology and Biotechnology Letters
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    • v.21 no.2
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    • pp.144-149
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    • 1993
  • We have identified a T cell-activating material in the culture supernatant of Streptomyces species. The factor in microbial culture supernatant (MCS) induced thymocyte proliferation in a does dependent fashion and it could be detected by immunoblot analysis using anti-interleukin-1(IL-1) antibody. The factor in MCS was slightly larger(about 21 kd) in its molecular weight than IL-1 on SDS-PAGE. When 125I-MCS was covalently coupled with homo-bifunctional cross-linking agent, disuccinimidyl-propionate to IL-1 receptor(IL-1R) on mouse thymoma cell(EL-4) and immunoprecipitated with anti-IL-1R antibody the molecular weight of this complex of 110 kd was observed.

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Preparation and Characterization of Wheat Germ Agglutinin-conjugated Praecoxin A (Wheat Germ Agglutinin-conjugated Praecoxin A의 제작 및 특성)

  • 김완수;김만석;김범수;이민원;이도익
    • YAKHAK HOEJI
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    • v.45 no.3
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    • pp.302-309
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    • 2001
  • Wheat germ agglutinin (WGA) pectin, which binds to human melanoma cell line, was conjugated with Praecoxin A using 1-ethyl-3-(3-dimethylaminopropyl) carbodiimide as a cross-linking agent. Physical mixture (PM) of WGA and Praecoxin A was also prepared by using a non-specific binding property of Praecoxin A to WGA. The WGA:Praecoxin A ratio in the conjugate and PM was approximately 1:18 and 1:20, respectively. The results of hemagglutination assay and enzyme-linked lectin assay indicated that the conjugate and PM maintained the lectin-like properties of the WGA. The binding ratio of conjugate was about 70% during 4-24 hr, but the most of Praecoxin A was released within 24 hr in the case of PM. These results lead to the conclusion that the conjugate is potentially useful for the formulation of injection that requires targeting for melanoma as well as sustained release at the site.

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