• 제목/요약/키워드: Cross-Link

검색결과 314건 처리시간 0.023초

유무기 하이브리드 SiOC 박막의 화학적 이동에 대한 FTIR 스펙트라 분석 (Analysis of FTIR Spectra in Organic Inorganic Hybrid Type SiOC Films)

  • 오데레사
    • 대한전자공학회논문지SD
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    • 제42권6호
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    • pp.17-22
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    • 2005
  • 유무기 하이브리드 SiOC 박막은 차세대 유력한 저유전상수를 갖는 박막이다. SiOC 박막의 결합구조는 FTIR 분석기를 이용하여 화학적 이동이 일어나는 것을 확인하여 분석하였다. 유기화학분야에서의 일반적인 화학적 이동은 red shift에 해당하지만, 하이브리드 타입의 SiOC 박막은 red shift 뿐만 아니라 특이한 경우에 해당하는 blue shift도 관찰되었다. 화학적 이동의 원인은 전기음성도가 큰 원소가 주변에 존재하는 수소결합사이의 상호작용 때문인데, SiOC 박막에서 blue shift는 전자를 많이 포함하는 메틸그룹이 증가함으로 생기는 기공을 만드는 원인을 제공한다. SiOC 박막의 결합구조 역시 2가지 유형의 화학적 이동에 따라서 cross-link 구조와 case-link 구조의 두 가지 유형으로 나타난다. 유량비와 증착할 때 주어지는 열에너지에 따라서 두 가지 결합구조를 나타낸다. cross-link 구조와 cross-link breakage 구조는 박막의 유전상수가 낮아지는 원인 서로 다르며 화학적 물리적인 특성 또한 다르게 나타나는 것을 증명하고 있다. Si-O-C cross-link 구조는 red shift의 원인이 된 수소결합에 의한 원자사이의 길이가 길어지는 효과에 의해 표면접착력이 개선되며, 유전상수 역시 감소하였다.

Cross-Link Breakdown 효과와 Cage Link (Cage Link and the Effect of Cross-Link Breakdown)

  • 오데레사;김경식
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2004년도 하계종합학술대회 논문집(2)
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    • pp.517-520
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    • 2004
  • Organosilicate films are promising porous low-dielectric materials, which can replace the silicon dioxide films. It was researched that organosilicate films have two different chemical shifts according to the increase of the flow rate ratio. There are the red shift due to the electron deficient substitution group, and the blue shift of the electron rich substitution group. Among these chemical shifts, the blue shift from $1000 cm^{-1}$ to $1250 cm^{-1}$ was related with the formation of pores. The methyl radicals of the electron-rich substitution group terminate easily the Si-O-Si cross-link, and the Si-O-C cage-link near $1057 cm^{-1}$ is originated from the cross-link breakdown due to much methyl radicals.

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Electrical Properties of Organic Materials as Low Dielectric Constant Materials

  • Oh Teresa;Kim Hong Bae;Kwon Hak Yong;Son Jae Gu
    • 반도체디스플레이기술학회지
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    • 제4권3호
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    • pp.5-9
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    • 2005
  • The bonding structure of organic materials such as fluorinated amorphous carbon films was classified into two types due to the chemical shifts. The electrical properties of fluorinated amorphous carbon films also showed very different effect of two types notwithstanding a very little difference. Fluorinated amorphous carbon films with the cross-link break-age structure existed large leakage current resulting from effect of the electron tunneling. Increasing the cation due to the electron-deficient group increased the barrier height of the films with the cross-link amorphous structure, therefore the electric characteristic of the final materials with low dielectric constant was also improved. The lowest dielectric constant is 2.3 at the sample with the cross-link amorphous structure.

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Free vibrations of a two-cable network inter-supported by cross-links extended to ground

  • Zhou, H.J.;Wu, Y.H.;Li, L.X.;Sun, L.M.;Xing, F.
    • Smart Structures and Systems
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    • 제23권6호
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    • pp.653-667
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    • 2019
  • Using cross-ties to connect cables together when forming a cable network is regarded as an efficient method of mitigating cable vibrations. Cross-ties have been extended and fixed on bridge decks or towers in some engineering applications. However, the dynamics of this kind of system need to be further studied, and the effects of extending cross-links to bridge decks/towers on the modal response of the system should be assessed in detail. In this paper, a system of two cables connected by an inter-supported cross-link with another lower cross-link extended to the ground is proposed and analyzed. The characteristic equation of the system is derived, and some limiting solutions in closed form of the system are derived. Roots of cable system with special configurations are also discussed, attention being given to the case when the two cables are identical. A predictable mode behavior was found when the stiffness of inter-connection cross-link and the cross-link extended to the ground were the same. The vector of mode energy distribution and the degree of mode localization index are proposed so as to distinguish global and local modes. The change of mode behaviors is further discussed in the case when the two cables are not identical. Effects of cross-link stiffness, cross-link location, mass-tension ratio, cable length ratio and frequency ratio on $1^{st}$ mode frequency and mode shape are addressed.

Link Error Analysis and Modeling for Video Streaming Cross-Layer Design in Mobile Communication Networks

  • Karner, Wolfgang;Nemethova, Olivia;Svoboda, Philipp;Rupp, Markus
    • ETRI Journal
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    • 제29권5호
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    • pp.569-595
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    • 2007
  • Particularly in wireless communications, link errors severely affect the quality of the services due to the high error probability and the specific error characteristics (burst errors) in the radio access part of the network. In this work, we show that thorough analysis and appropriate modeling of radio-link error behavior are essential to evaluate and optimize higher layer protocols and services. They are also the basis for finding network-aware cross-layer processing algorithms which are capable of exploiting the specific properties of the link error statistics, such as predictability. This document presents the analysis of the radio link errors based on measurements in live Universal Mobile Telecommunication System (UMTS) radio access networks as well as new link error models originating from that analysis. It is shown that the knowledge of the specific link error characteristics leads to significant improvements in the quality of streamed video by applying the proposed novel network- and content-aware cross-layer scheduling algorithms. Although based on live UMTS network experience, many of the conclusions in this work are of general validity and are not limited to UMTS only.

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Investigation of Transglutaminase-Induced Peptide Cross-Linking by Matrix-Assisted Laser Desorption / Ionization Time-of-Flight Mass Spectrometry

  • 김희준;임효섭
    • Bulletin of the Korean Chemical Society
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    • 제20권11호
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    • pp.1299-1302
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    • 1999
  • Matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF-MS) was used to demonstrate cross-linking of peptides induced by transglutaminase. The presence of ε-( Υ-glutamyl)lysine isopeptide cross-link in the acid hydrolysate of the cross-linking reaction mixture was also demonstrated by MALDI-TOF-MS without prior separation. MALDI-TOF-MS quickly provided peptide mass maps after pronase digestion of the cross-linked peptide adduct, which enabled us to monitor the hydrolytic sequence. Pronase appears to preferentially hydrolyze peptide bonds distant from the cross-link before hydrolyzing peptide bonds around the cross-link. The results suggest that pronase digestion followed by MALDI-TOF-MS could be used for determination of amino acid sequence around a modification site.

링크확률과 개체명 인식을 이용한 영-한 교차언어 링크 탐색 (English-Korean Cross-lingual Link Discovery Using Link Probability and Named Entity Recognition)

  • 강신재
    • 한국지능시스템학회논문지
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    • 제23권3호
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    • pp.191-195
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    • 2013
  • 본 논문에서는 방대한 웹 자원의 연결성을 더욱 증가시키기 위해 영어 위키피디아 문서로부터 한국어 위키피디아 문서로의 교차언어 링크를 자동으로 탐색하는 방법을 제안한다. 어구의 링크확률을 대략 추정하여 사용하던 기존의 방법에 비해, 본 연구에서는 위키피디아 문서 집합으로부터 추출한 제목 목록과 링크 확률과 같은 다양한 정보들과 개체명 인식 결과를 함께 사용하여 링크가 걸릴 앵커 후보를 선택한다. 앵커 후보를 한국어 대역어로 번역한 후, 대역어에 가장 적합한 한국어 웹문서를 찾아 교차언어 링크로 설정하게 된다. 실험한 결과 MAP 수치로 0.375를 얻었다.

에폭시수지의 경화특성에 관한 연구 (A Study on the Curing Property of the Epoxy Resin)

  • 이진;이은학;송희수;김태성
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1988년도 추계학술대회 논문집 학회본부
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    • pp.246-248
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    • 1988
  • The electrical insulation characteristics of the Epoxy resin is generally depended upon the cross-Link. Therefore, when the Epoxy is cured the full cross-Link must be gotten to obtain the best electrical insulation property. This paper alms at examining the cure condition to get the best cross-link. The Epoxy used in this experiment is DGEBA, the curing materiel is MNA, and the accellator is tertiary amine. In this study, the best curing condition of cross-link is suggested by analysing the each Epoxy resin which is differenty cured according Lo the variable temperatures and curing times.

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Cross-Layer Analysis of Wireless TCP/ARQ Systems over Correlated Channels

  • Wu Yi;Niu Zhisheng;Zheng Junli
    • Journal of Communications and Networks
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    • 제7권1호
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    • pp.45-53
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    • 2005
  • In this paper, we present a cross-layer analysis of wireless TCP systems over correlated channels. The effects of error correlation on the behavior of link retransmission strategy and the end-to-end throughput of TCP layer are investigated. Based on the cross-layer analysis, an efficient refinement of link layer protocol is proposed by consciously utilizing the information of channel correlations, which leads to the performance improvement of wireless TCP systems.

De-link R를 이용한 폐고무 재활용(I) (Recycling of Waste Rubber by De-link System (I))

  • 황성혁;홍존희;유태욱;김진국
    • Elastomers and Composites
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    • 제36권2호
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    • pp.79-85
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    • 2001
  • 폐고무의 증가로 인하여 환경문제가 날로 심각해지고 있다. 그러므로 효율적인 재활용을 통하여 이러한 문제를 해결하는데 많은 연구가 진행되고 있다. 본 연구에서는 탈황시스템을 이용하여 폐고무 분말의 가황 결합을 분리함으로서 기본물성을 높이는데 목적을 두었다. 폐고무분말의 입자크기에 따른 물성의 변화와 De-link 함량 증가에 따른 물성을 조사하였고 De-link를 함유한 시료를 기존 배합물에 10phr 충전하여 유변학적, 기계적 및 가교도 등의 물성을 조사하였다. 또한 광학현미경을 사용하여 표면을 확인함으로서 제품특성을 연구하였다.

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