• 제목/요약/키워드: Critical surface tension

검색결과 168건 처리시간 0.023초

계면촬성제 첨가에 따른 지하수 폭기법의 폭기효율 변화 연구 (Surfactant Aided Air-sparging for Groundwater Remediation)

  • 소효은;최경민;이승재;김헌기
    • 자원환경지질
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    • 제35권5호
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    • pp.421-428
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    • 2002
  • 계면활성제를 사용하여 지하수의 표면장력을 인위적으로 감소하였을 때, 감소된 표면장력이 지하수 폭기시의 폭기 영향권 및 VOC 제거 효율에 미치는 영향을 실험실 규모의 실험을 통하여 규명하였다. 내경 9.5 cm, 길이 100 cm의 유리 컬럼에 계면활성제(sodium dodecyl sulfate, SDS) 및 toluene 100 ppm 포함하는 물로 채운 후 일정한 속도로 공기를 주입하였을 때의 toluene의 제거 속도를 측정하였다. 또한 같은 컬럼에 토양(모래)이 채워진 상태에서 동일한 실험을 반복하였다. 토양이 존재하지 않는 상태에서의 stripping에 의한 toluene의 제거 속도는 표면장력의 감소(계면 활성제 농도의 증가)에 따라 증가하는 것으로 나타났으며, 토양이 존재하는 경우에도 비슷한 결과를 나타내었다. 2차원 유리 상자에 모래와 SBS를 포함하는 물을 채운 후 일정한 공기 유속을 유지하였을 때, 폭기의 영향권(공기의 침투영역)은 물의 표면장력 감소에 따라 현저히 증가하는 것으로 나타났다. 특히 SDS의 critical micelle concentration(CMC)보다 훨씬 낮은 농도에서 폭기 영향권이 최대화하는 것으로 밝혀졌다. 본 연구결과는 폭기에 의한 지하수 오염물질 중, 특히 휘발성 유기오염물질의 제거 공정의 효율을 증대하는데 기여할 것으로 생각된다.

스톡스 유동장 내의 한 쌍의 소오스-싱크에 의한 자유표면 유동해석 (Analysis on the free surface flow induced by a pair of source-sink in Stokes flow)

  • 정재택;박종선
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년도 춘계학술대회논문집
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    • pp.304-307
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    • 2008
  • Two-dimensional Stokes flow due to the line source and line sink of same strength in semi-infinite flow region with free surface is analysed using complex variable theory and conformal mapping. Surface tension effects are included while gravity is neglected. From the results of analysis, flow pattern and free surface shape are obtained and velocity distribution on the free surface is determined with 2 independent parameters Ca (capillary number) and h (non-dimensionalized distance between source and sink). When the location of the sink is above the source, velocity on the free surface converges and a cusp occurs on the free surface for the value of Ca above some critical capillary number.

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열전달을 수반하는 $NH_3-H_2O$ 흡수과정에서의 Marangoni 대류 불안정성 해석 (Instability Analysis of Marangoni Convection for $NH_3-H_2O$ Absorption Process Accompanied by Heat Transfer)

  • 김제익;최창균;강용태
    • 설비공학논문집
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    • 제15권2호
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    • pp.126-131
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    • 2003
  • Convective instability driven by surface tension is analyzed in an initially quiescent water absorbing ammonia gas with heat transfer using the linear stability analysis. The propagation theory is adapted to find the critical conditions of the onset of Marangoni convection. In this theory, the solutal penetration depth is chosen as the length scale factor. The results show that the liquid layer becomes more stable with decreasing the Schmidt number and increasing the Lewis number. It is also found that there is a critical Biot number to make the liquid layer be most unstable, and there is a linear relationship between the thor-mal Marangoni number and the solutal Marangoni number.

비불소계 폴리스테아릴메타크릴레이트 발수제의 합성과 발수특성 (Synthesis of Non-fluorinated Polystearyl methacrylate Water Repellent and Its Properties on Textile Fibers)

  • 김태경;강혜진;박지훈
    • 한국염색가공학회지
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    • 제29권2호
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    • pp.55-61
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    • 2017
  • A non-fluorinated polystearyl methacrylate water repellent was synthesized by emulsion polymerization. The number and weight averaged molecular weights were obtained at around 137,277 and 237,754g/mole. The melting point was observed at $32^{\circ}C$. The contact angle of water droplet on fabrics treated with the water repellent was $140{\sim}145^{\circ}$ for cotton and polyester, and $125{\sim}130^{\circ}$ for wool and nylon. Since the critical surface tension was estimated at 20.7mN/m, even though relatively not so strong as fluorinated water repellent, it is considered to be used as a good water repellent practically.

카르복시베타인 유도체(誘導體)의 계면활성(界面活性) (Surface Activities of Carboxybetaine Derivatives)

  • 손주환;김유옥
    • 한국응용과학기술학회지
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    • 제4권2호
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    • pp.43-48
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    • 1987
  • Isoelectric point and surface tension of twelve of the alkylcarboxy betaines such as 2-(trimethylammonio) dodecanoate, 2-(trimethyammonio) tetradecanoate, 2-(trimethylammonio) hexadecanoate, (dimethyldodecylammonio)ethanoate, (dimethyltetradecylammonio)ethanoate, (dimethylhexadecylammonio) ehtanoate, 2-(dimethylododecylammonio) propanoate, 2-(dimethyltetradecylammonio)proopanoate, 2-(dimethylhexadecylammonio)propanoate, 2-(dimethyltetradecylammonio)-3-phenyl propanoate, 2-(dimethyltetradecylammonio)-3-phenyl propanoate are tested. From the measurement of the isoelectric point, it was found that the isoelectric point were leaned toward the alkaline zone for c-alkylarbrxybetaines, and toward the acidic zone for N-alkylcarboxybetaines. At the range of the carboxybetaine concentration $2\;{\times}\;10^{-2}{\sim}2\;{\times}\;10^{-5}$mole/l, the surface tension of the aqueous solution were decreased to 30-38 dyne/cm, showing the tendency that the ability of lowering the surafce tension was depending on the increase of carbon atom number in the lipophilic alkyl chain. The critical micelle concetration measured by the surface tension and concentration curves have been found at the range of $10^{-2}{\sim}10^{-5}$mole/l.

Carbon Fabric/Epoxy 적층판의 인장-압축 피로거동 (Tension-Compression Fatigue Behavior of Carbon Fabric/Epoxy Laminates)

  • 김진봉;김태욱
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2001년도 춘계학술발표대회 논문집
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    • pp.60-64
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    • 2001
  • In this paper, the tension-compression fatigue test method and the fatigue life characteristics of carbon fabric/epoxy laminate coupon are presented. To avoid the buckling during the compression, a proper design for the test coupons is essential. The critical buckling loads for the coupons are calculated by assuming the coupons as columns under two types of fixed conditions. The first is that both ends of each coupon are perfectly clamped, the second is that both ends of each coupon are simply supported. The strain-load curves are obtained by compressing the representative coupons, on each surface of which a strain gage is attached. The buckling loads obtained from the tests are all between the two calculated critical buckling loads. All the coupons are broken by the compression during the fatigue tests. It is estimated to be the reason that the fatigue load causes delamination before the eventual failure of each coupon, and sequentially the micro-buckling in the delaminated region drives each coupon into fatigue failure during the compression. The S-N curve, the fatigue life characteristics of carbon fabric/epoxy is obtained.

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Characteristic responses of critical current in REBCO coated conductor tapes under tensile/compressive bending strains at 77 K

  • Diaz, Mark Angelo;Shin, Hyung Seop;Lee, Jae-Hun
    • 한국초전도ㆍ저온공학회논문지
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    • 제20권4호
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    • pp.31-35
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    • 2018
  • When REBCO coated conductors (CCs) are applied to superconducting devices such as coils and magnets, they are subjected to deformation in various modes such as compression/tension bending, uniaxial/transverse tension and torsion. Despite outstanding performances by REBCO CC tapes, their electromechanical properties have been evaluated primarily under uniaxial tension, therefore data about the critical current ($I_c$) response in the compressive strain region are lacking. In this study, the characteristic responses of $I_c$ in REBCO CC tapes under bending strains in the range from tensile to compressive were evaluated. The springboard bending beam was used, wherein the CC tape sample was soldered onto the surface of the springboard. A Goldacker-type bending test rig, which lacks a support holding the sample during testing, was used as a comparator. Degradation in $I_c$ behaviors, including strain sensitivity, in differently processed REBCO CC tapes were examined based on the test rig used.

계면활성(界面活性) 아미노싸이클리톨 유도체(誘導體)의 계면화학적(界面化學的) 성질(性質) (Surface Chemical Properties of Surface Active Aminocyclitol Derivatives)

  • 손주환;이창섭
    • 한국응용과학기술학회지
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    • 제4권1호
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    • pp.45-52
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    • 1987
  • Surface chemical properties including surface tension, Ross-Miles foaming power, foam stabilities, emulsifying properties, emulsion stabilities, effectiveness of dispersion, dispersion stabilites of the quaternary ammonium salt type deoxyaminoimositol derivatives such as sixteen kinds of dimethylafkyl-deoxyscyllo-inosityl- dimethylalkyl-2-deoxy-2-myo-inosityl-, dimethylakyl-2-deoxy-2-epi-inosityl- and dimethylalkyl-4-deoxy-4-myo-inosityl ammonium chlorides are tested. And critical micelle concentration of these compounds are estimated from the curves of surface tension and concentration. The experimental results show that the members of this class of compounds have necessary surface active properties to make them effective surfactants.

Micro-Gravity Research on the Atomization Mechanism of Near-Critical Mixing Surface Jet

  • Tsukiji, Hiroyuki;Umemura, Akira;Hisida, Manabu
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2004년도 제22회 춘계학술대회논문집
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    • pp.774-778
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    • 2004
  • The atomization process of a circular $SF_{6}$ liquid jet issued into an otherwise quiescent, high-pressure $N_2$ gas was observed to explore the breakup mechanism of liquid ligaments involved in turbulent atomization. Both liquid and gas temperatures were fixed at a room temperature but the gas pressure was elevated to more than twice the critical pressure of $SF_{6}$. Therefore, the liquid surface was in a thermodynamic state close to a critical mixing condition with suppressed vaporization. Since the surface tension and the surface gas density approach zero and the surface liquid density, respectively, phenomena equivalent to those which would appear when a very high speed laminar flow of water were injected into the atmospheric-pressure air can be observed by issuing $SF_{6}$ liquid at low speeds in micro-gravity environment which avoid disturbances due to gravity forces. The instability ob near-critical mixing surface jet was quantitatively characterized using a newly developed device, which could issue a very small amount of $SF_{6}$ liquid at small constant velocity into a very high-pressure $N_2$ gas.

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산화(酸化)/환원(還元) 조건(條件)에 따른 황화광물(黃化鑛物)의 부유선별(浮游選別)에 의한 회수성(回收性) 변화(變化) (The Effect of Oxidation/Reduction of Sulfide Mineral on Its Recovery by Flotation)

  • 김동수
    • 자원리싸이클링
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    • 제16권2호
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    • pp.12-16
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    • 2007
  • Chalcopyrite 를 대상으로 광미 중에 함유된 Sulfide 물질의 부유선별에 의한 분리회수 과정에서 산화가 부유성에 미치는 영향을 고찰하였다. Zisman Plot에 의해 도출된 Chalcopyrite 의 임계계면장력은 약 15.5 dyne/cm인 것으로 파악되었으며 포수제의 농도가 증가함에 따라 그 값은 감소하여 Chalcopyrite의 부유성이 상승하는 것으로 관찰되었다. 초기 산화에 의한 Chalcopyrite의 부유성 상승은 $S_2^{2-}$$S^o$로의 전환에 기인하는 것으로 판단되었으며 형성된 $S^o$$S_4^{2-}$$S_2O_3^{2-}$로 재전환됨에 따라 Chalcopyrite의 부유성은 다시 감소하는 것으로 사료되었다. 산화된 Chalcopyrite의 환원 시 부유성은 상승하는 것으로 나타났으며 산화/환원 과정에서의 임계계면장력의 변화 양상은 원자간 Bond Energy의 변화에 의거한 Energy Diagram으로 해석되었다.