• Progress in Superconductivity
• /
• 제8권1호
• /
• pp.71-74
• /
• 2006

High $J_c$ over 1 $MA/cm^2$ YBCO film has been successfully prepared using nitrate precursors by spray pyrolysis method. Aerosol drolpets generated using a concentric spray nozzle were directly sprayed on a $LaAlO_3$(100) single crystal substrate. The cation ratio of precursor solution was Y:Ba:Cu=1:2.65:1.35. The distance between nozzle and substrate was 15 cm. Deposition temperature was ranging from $750^{\circ}C\;to\;800^{\circ}C$. Deposition pressure was 100 Torr, and oxygen partial pressure was varied from 10 Torr to 50 Torr. The microstructure, phase formation, texture development and superconducting properties of deposited films were largely changed with oxygen partial pressure. Deposited films showed a texture with(001) planes parallel to substrate plane. High quality film was obtained when film was deposited at $760^{\circ}C$ with an oxygen partial pressure of 30 Torr. The critical current density($J_c$) of the YBCO film was 1.75 $MA/cm^2$ at 77 K and self-field.

• Progress in Superconductivity
• /
• 제8권1호
• /
• pp.59-64
• /
• 2006

High $J_c\;YBa_2Cu_3O_x$ superconducting films were fabricated by MOD method using fluorine-free dichloroacetic acid(DCA) as chelating solvent for preparing precursor solution. Coating solutions were prepared by dissolving Y-, Ba- and Cu-acetates in DCA solvent followed by drying in rota vapor to obtain the blue gel that is diluted in methanol and 2-methoxyethanol for adjusting the cation concentration. DCA-MOD precursor solution was coated on a single crystal(001) $LaAlO_3(LAO)$ substrate by a dip coating method with a speed of 25 mm/min. Coated films were calcined at lower temperature up to $500^{\circ}C$ in flowing oxygen atmosphere with a 7.2% humidity. Conversion heat treatment was performed at various temperatures of $780{\sim}810^{\circ}C$ for 2 h in flowing Ar gas containing 1000 ppm oxygen with a humidity of 9.45%. SEM observations showed that films have very dense microstructures for the films prepared at the temperature higher than $800^{\circ}C$ regardless of diluting solvent; methanol or 2-methoxyethanol. X-ray diffraction analysis showed that YBCO grains grew with a (001) preferred orientation. A High critical current density($J_c$) of 1.28 $MA/cm^2$(@77 K and self-field) was obtained id. the YBCO film prepared using 2-methoxyethanol as a solvent.

• Progress in Superconductivity
• /
• 제9권1호
• /
• pp.5-10
• /
• 2007

We prepared four different $MgB_2$ films on $Al_2O_3$ by hybrid physical chemical vapor deposition method with thicknesses ranging from $0.65\;{\mu}m$ to $1.2\;{\mu}m$. X-ray diffraction patterns confirm that all the $MgB_2$ films are c-axis oriented perpendicular to $Al_2O_3$ substrates. The superconducting onset temperature of $MgB_2$ films were between 39.39K and 40.72K. The residual resistivity ratio of the $MgB_2$ films was in the range between 3.13 and 37.3. We measured the angle dependence of critical current density ($J_c$) and resistivity, and determined the upper critical field ($H_{c2}$) from the temperature dependence of the resistivity curves. The anisotropy ratios defined as the ratio of the $H_{c2}$ parallel to the ab-plane to that perpendicular to the ab-plane were in the range of 2.13 to 4.5 and were increased as the temperature was decreased. Some samples showed increase of $J_c$ and decrease of resistivity when a magnetic field in applied parallel to the c-axis. We interpret this angle dependence in terms of enhanced flux pinning due to columnar growth of $MgB_2$ along the c-axis.

• 한국전기전자재료학회논문지
• /
• 제29권2호
• /
• pp.110-113
• /
• 2016

(YNdSm)-Ba-Cu-O system high Tc composite superconductors were directionally grown by zone melting process, having large temperature gradient, in air atmosphere. Cylindrical green rods of $(YNdSm)_{1.8}Ba_{2.4}Cu_{3.4}O_x$ [(YNS)1.8]composite oxides by CIP (cold isostatic pressing) method using rubber mold were fabricated. The microstructure and superconducting properties were investigated by XRD, TEM and SQUID magnetometer. The size of nonsuperconducting $(YNdSm)_2BaCuO_5$ inclusions of the melt-textured (YNS)1.8 sample with $CeO_2$ additive were remarkably reduced and uniformly distributed within the superconducting (YNS)1.8 matrix. (YNS)1.8 samples, with / without $CeO_2$ additive, showed an onset $T_c{\geq}90K$ and sharp superconducting transition. The critical current density $J_c$ value of the (YNdSm)1.8 superconductor with $CeO_2$ additive were 840 A, $1.2{\times}104A/cm^2$ in 77 K, 0 Tesla by direct current transport method.

• Progress in Superconductivity
• /
• 제3권2호
• /
• pp.213-217
• /
• 2002

We have fabricated successfully single-filament composite $MgB_2$/SUS tapes, as an ultrarobust conductor type. The fabrication of the $MgB_2$/SUS tapes was performed by power-in-tube (PIT) process such as swaging and cold rolling. The critical transition temperatures $T_{c}$~38.5 K and ~36 K were observed for the sintered and the nonsintered $MgB_2$/SUS tapes, respectively In addition, the isothermal magnetization M(H) of the sintered $MgB_2$/SUS tapes was measured at temperatures T (between 5 and 50 K) in fields up to 6 T, employing a PPMS-9 (Quantum Design). The persistent current density (J$T_{P}$) values were obtained from the M(H) data, using Bean model, fur the sintered $MgB_2$/SUS tapes. The estimated values were higher than ~ 6$\times$ $10^{5}$ $A/\textrm{cm}^2$ at T = 5 K, with H : 0 G. We also investigated the cross section of the sintered tapes, by using SEM and EDX. An evidence of weak reaction on boundary between $MgB_2$ and SUS tube is found in the SEM and EDX.X.X.X.

• 한국정보통신학회:학술대회논문집
• /
• 한국해양정보통신학회 2003년도 춘계종합학술대회
• /
• pp.758-761
• /
• 2003

The goal of the research is to study and describe a new stressed state of High Temperature Superconducting (High-T$_{c}$) YBCO Films, to create of SQUIDs (Superconducting Quantum Interference Device) on the bases of these films with maximal sensitivity. With the experimental investigation of the stressed films grown by laser ablation method and its properties, the fabrication of the dc-SQUIDs with maximal sensitivity on the bases of the stressed YBCO films were carried out. The stressed film having the value of the critical current density J$_{c}$=3ㆍ$10^{5}$A/$\textrm{cm}^2$ was the more stable than others.ers.s.

• 한국초전도ㆍ저온공학회논문지
• /
• 제19권1호
• /
• pp.30-35
• /
• 2017

The effects of the crystallographic orientation and sample thickness on the magnetic levitation forces (F) and trapped magnetic field (B) of single grain YBCO bulk superconductors were examined. Single grain YBCO samples with a (001), (110) or (100) surface were used as the test samples. The samples used for the force-distance (F-d) measurement were cooled at 77 K without a magnetic field (zero field cooling, ZFC), whereas the samples used for the B measurement were cooled under the external magnetic field of a Nd-B-Fe permanent magnet (field cooling, FC). It was found that F and B of the (001) surface were higher than those of the (110) or (100) surface, which is attributed to the higher critical current density ($J_c$) of the (001) surface. For the (001) samples with t=5-18 mm, the maximum magnetic levitation forces ($F_{max}s$) of the ZFC samples were larger than 40 N. About 80% of the applied magnetic field was trapped in the FC samples. However, the F and B decreased rapidly as t decreased below 5 mm. There exists a critical sample thickness (t=5 mm for the experimental condition of this study) for maintaining the large levitation/trapping properties, which is dependent on the material properties and magnitude of the external magnetic fields.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2010년도 하계학술대회 논문집
• /
• pp.191-191
• /
• 2010

초전도 전력 기기를 안정적으로 운용하기 위해서는 고자장하에서 높은 임계 전류 밀도($J_c$)를 지닌 초전도체 개발이 필수적이다. 최근 고자기장에서 전기적 특성을 향상시키는 방법으로는 YBCO 박막선재에 인위적 피닝센터로 고자장하에서도 $J_c$가 크게 증가 되었다고 보고되고 있다. 본 연구에서는 STO(100) 기판 위에 SAM 방법을 이용하여 금 나노분말을 분산시킨 후 PLD로 YBCO 박막을 증착하여 미세구조와 전기적인 특성을 분석하였다. 분산된 금 나노분말은 열처리전 나노입자의 높이는 29~32 nm, 지름은 41~49 nm툴 나타내었고 $800^{\circ}C$에서 진공 열처리 후에는 높이는 25~30 nm, 지름은 52~60 nm로 변형되었다. 임계온도는 순수 YBCO에서 85 K을 나타냈지만 금 나노입자를 적용한 YBCO의 경우는 80K으로 낮아진 것을 확인하였다. 임계전류밀도는 4T에서 측정된 경우 65 K에서는 순수한 YBCO는 141 KA/$cm^2$에서 금 나노입자가 형성된 기판에 증착한 YBCO는 42 KA/$cm^2$로 낮아졌다.

• Progress in Superconductivity
• /
• 제10권1호
• /
• pp.12-16
• /
• 2008

In this work, nano size $BaCeO_3$, which is a possible flux pinning medium of melt processed $YBa_{2}Cu_{3}O_x$ superconductor, was synthesized by the conventional solid state reaction method using powders. $BaCeO_3$ and $CeO_2$ were mixed thoroughly using a ball milling for 24 hours and calcined at $1200^{\circ}C$ for 5 hours for the formation $BaCeO_3$ powder. The obtained $BaCeO_3$ powder was attrition milled at various milling times of 60 min, 120 min and 240 min. The $BaCeO_3$ powders of various milling times were mixed with $YBa_{2}Cu_{3}O_x$ powder. Seed melt processed $YBa_{2}Cu_{3}O_x$-$BaCeO_3$ (15wt.%) superconductors were prepared and the superconducting properties were investigated. It was found that $T_c$ of $Y_{1.5}Ba_{2}Cu_{3}O_x$ samples was not significantly affected by $BaCeO_3$ addition, but $J_c$ of samples was increased by $BaCeO_3$ addition. The $J_c$ improvement by fine $BaCeO_3$ powder (120 min attrition-milled) was effective at low magnetic fields less than 2 T.

• 한국초전도ㆍ저온공학회논문지
• /
• 제18권1호
• /
• pp.37-40
• /
• 2016

We have investigated the addition effect of NiO magnetic nanoparticles on crystal structure, microstructure as well as superconducting properties of $MgB_2$. NiO-added $MgB_2$ samples were prepared by the solid-state reaction method. The superconducting transition temperature ($T_c$) of 37.91 K was obtained for pure $MgB_2$, and $T_c$ was found to decrease systematically on increasing the addition level of NiO. X-ray diffraction (XRD) analysis revealed that no substitution of Ni for Mg in the lattice of $MgB_2$ was occurred. The microstructural analysis shows that the pure $MgB_2$ sample consists of plate shape $MgB_2$ grains, and the grains get refined to smaller size with the addition of NiO nanoparticles. At 5 K, high values of critical current density ($J_c$) were obtained for small amount NiO-added $MgB_2$ samples as compared to pure sample. The enhancement in $J_c$ could be attributed to the refinement of $MgB_2$ grains which leads to high density of grain boundaries in NiO-added $MgB_2$ samples.