• Korean Chemical Engineering Research
• /
• v.50 no.2
• /
• pp.282-291
• /
• 2012

The PGLE and PGLE3 nonionic surfactants were synthesized from the reaction between glycidol and lauryl acid and their structures were confirmed by $^1H$ and $^{13}C$ NMR analysis. The CMCs of PGLE and PGLE3 surfactants were found to be $3.59{\times}10^{-2}$ mol/L and $8.80{\times}10^{-2}$ mol/L respectively and the surface tensions at their CMC conditions were 26.09 mN/m and 28.68 mN/m respectively. Dynamic surface tension measurement has shown that the adsorption rate of surfactant molecules at the interface between air and surfactant solution was found to be relatively fast in both surfactant systems, presumably due to high mobility of surfactant molecules. The contact angles of PGLE and PGLE3 nonionic surfactants were $25.5^{\circ}$ and $9.5^{\circ}$ respectively. Dynamic interfacial tension measurement showed that both surfactant systems reached equilibrium in 20 minutes and the interfacial tensions at equilibrium condition in both systems were 0.42 mN/m and 0.53 mN/m respectively. The PGLE surfactant system has indicated higher foam stability than the PGLE3 surfactant system, which is consistent with surface tension measurement. The phase behavior experiments performed at $25{\sim}60^{\circ}C$ in systems containing nonionic surfactant, water, n-hydrocarbon oil and cosurfactant showed a lower phase or oil in water microemulsion in equilibrium with excess oil phase at all conditions investigated during this study.

• Korean Chemical Engineering Research
• /
• v.50 no.3
• /
• pp.455-463
• /
• 2012

In this study, the measurement of physical properties of ethylene oxide-propylene oxide adducted zwitterionic surfactants were measured such as critical micelle concentration, surface tension, interfacial tension, contact angle, viscosity and foam stability. Also, the dual function characteristics of a zwitterionic surfactant were investigated by determining an isoelectric point, which were obtained using zeta potential measurement and QCM (quartz crystal microbalance) experiments. The isoelectric point of DEP-OSA82-AO zwitterionic surfactant determined by zeta potential measurement was close to that obtained by QCM experiment and both results have shown almost the same trend as that determined by the frictional property measured using an automated mildness tester. In particular, it has been observed that DEP32-OSA82-AO and DEP34-OSA82-AO surfactants provide better softening effect at a pH of acidic or neutral condition than at an alkaline condition. This result indicates that both surfactants act as a cationic surfactant at a pH of acidic or neutral condition and thus provide good softening effect during a rinsing cycle in the detergency process.

• Smart Structures and Systems
• /
• v.20 no.5
• /
• pp.549-562
• /
• 2017

The US railroad network carries 40% of the nation's total freight. Railroad bridges are the most critical part of the network infrastructure and, therefore, must be properly maintained for the operational safety. Railroad managers inspect bridges by measuring displacements under train crossing events to assess their structural condition and prioritize bridge management and safety decisions accordingly. The displacement of a railroad bridge under train crossings is one parameter of interest to railroad bridge owners, as it quantifies a bridge's ability to perform safely and addresses its serviceability. Railroad bridges with poor track conditions will have amplified displacements under heavy loads due to impacts between the wheels and rail joints. Under these circumstances, vehicle-track-bridge interactions could cause excessive bridge displacements, and hence, unsafe train crossings. If displacements during train crossings could be measured objectively, owners could repair or replace less safe bridges first. However, data on bridge displacements is difficult to collect in the field as a fixed point of reference is required for measurement. Accelerations can be used to estimate dynamic displacements, but to date, the pseudo-static displacements cannot be measured using reference-free sensors. This study proposes a method to estimate total transverse displacements of a railroad bridge under live train loads using acceleration and tilt data at the top of the exterior pile bent of a standard timber trestle, where train derailment due to excessive lateral movement is the main concern. Researchers used real bridge transverse displacement data under train traffic from varying bridge serviceability levels. This study explores the design of a new bridge deck-pier experimental model that simulates the vibrations of railroad bridges under traffic using a shake table for the input of train crossing data collected from the field into a laboratory model of a standard timber railroad pile bent. Reference-free sensors measured both the inclination angle and accelerations of the pile cap. Various readings are used to estimate the total displacements of the bridge using data filtering. The estimated displacements are then compared to the true responses of the model measured with displacement sensors. An average peak error of 10% and a root mean square error average of 5% resulted, concluding that this method can cost-effectively measure the total displacement of railroad bridges without a fixed reference.

• Journal of the Korean Magnetics Society
• /
• v.24 no.2
• /
• pp.60-65
• /
• 2014

We obtained resonance field ($H_{res}$) and linewidth (${\Delta}H_{PP}$) from measured ferromagnetic resonance signal in the functions of polar angle (${\Theta}_H$) in Ni thin film of 240 nm thickness fabricated by electrodeposition method. The angular dependence of $H_{res}$ was well fitted with the calculated ones. We confirmed that the g-factor and effective demagnetization field were 2.18 and 445 emu/cc by the theoretical analysis of the resonance field, respectively. The angular dependence of ${\Delta}H_{PP}$ showed very large values at in-plane direction (${\Theta}_H=90^{\circ}$), which could not explained by the homogenous linewidth due to the Gilbert damping and inhomogeneous linewidth due to the angular variations and magnetization variations by the surface layer. Therefore, we considered the spin wave scattering (two magnon scattering) process in order to analyze the measured inhomogeneous linewidth, which was appeared in thicker film than the critical thickness of 50 nm. The defect medicated spin wave scattering played a key role in the electrodoposited Ni thin film of 240 nm thickness.

• Journal of the Earthquake Engineering Society of Korea
• /
• v.15 no.2
• /
• pp.23-33
• /
• 2011

In this study, a CFPBS (Cone-type Friction Pendulum Bearing System) was developed which controls the acceleration delivered to the structure to prevent damage and degradation of the critical communication equipment in case of an earthquake. The isolation performance of the CFPBS was evaluated by numerical analysis. The CFPBS was manufactured in the shape of a cone differenced from the existing FPS (Friction Pendulum System), and a pattern was engraved on the friction surface. The natural frequencies of the CFPBS were evaluated from a free-vibration test with the seismic isolator system consisting of four CFPBSs. In order to verify its earthquake-resistant performance, a numerical analysis program was created from the equation of the CFPBS induced from the equations of motion. A simplified theoretical equation of the CFPBS was proposed to manufacture the equipment which could demonstrate the necessary performance. Artificial seismic waves satisfying the maximum earthquake scale of the Korean Building Code-Structural (KBC-2005) were created and verified to review the earthquake-resistant performance of the CFPBS by numerical analysis. The superstructural mass of the CFPBS and skew angle of the friction surface were considered for numerical analysis with El Centro NS (1940), Kobe NS (1995) and artificial seismic waves. The CFPBS isolation performance evaluation was based on the results of numerical analysis and the executed comparative analysis between the results from numerical analysis and the simplified theoretical equation under the same conditions.

• Polymer(Korea)
• /
• v.36 no.2
• /
• pp.223-228
• /
• 2012

Temperature and pH sensitive graft copolymers [Pluronic-$g$-poly(NIPAAm-$co$-MMA), Polymer A] and [Pluronic-$g$-poly( NIPAAm-$co$-MAA), Polymer C] were synthesized by macro radical graft polymerization with $N$-isopropylacrylamide (NIPAAM)/$N,N$-diethylaminoethylmethacrylate (DEAEMA) and $N$-isopropylacrylamide (NIPAAm)/methacrylic acid (MAA) based on Pluronic, respectively. The chemical structure and molecular weight of the graft copolymers was characterized by $^1H$ NMR and gel permeation chromatography. The aqueous solution properties of graft copolymers were measured using a UV-visible spectrophotometer, contact angle and dynamic light scattering equipment with different temperature and pH conditions. The obtained graft copolymers showed a very sensitive phase transition in response to temperature and pH in aqueous media which suggested that the amine group of DEAEMA segment and carboxylic group of MAA had a great influence on the lower critical solution temperatures (LCST) in Polymer A and C, respectively. The graft copolymers can be utilized for drug delivery system and molecular switching applications where responses to temperature and pH changes are relevant.

• The Journal of Engineering Geology
• /
• v.1 no.1
• /
• pp.19-37
• /
• 1991

The geology of the northwestern Cheju Island consist of Pleistocene to Holocene volcanic rocks which could be devided into basalt layers, the Sungsan Formation composed mainly of volcaniclastic debris exposed along the shoreline, and more than 30 cinder cones. Columnar joints and vesicles are dominant in the basalts of the Pyeosunri and the Sihungri basalt Formations. Volcaniclast and clay layers are intercalated in basaltic layers. When volcaniclast of the interlayers would be swept away by ground water and some caves of channel shape would be formaed. Overlying lavas cracked by columnar joints could be easily destroyed, collapsed and/or sunk. Geomechananical nature of the rocks such as strength may be controlled by the vesicularity(size, shape, and orientation of the vesicles) of the rocks. On the basis of vesicularity as a factor of strength, the effective strength ratio(Ke) could be calculated as Ke=0.3-0.72, in which the smaller Ke value reflects the lower in internal stress. In the studied area, the strength of the rocks tends to decrease as increasing in altitude of provenance of the rocks. The rocks in the area show relatively low values in angle of failure strength($\phi$) ranging from 10$^{\circ}$ to 30$^{\circ}$. In conclnsion, the rocks in question, majority of which the critical value exceeds 0.33, belong to the unstable rocks in the aspect of engineering geology.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.31 no.7
• /
• pp.15-25
• /
• 2003

An experimental. study is carried out to investigate the near-wake characteristics of an airfoil oscillating in pitch. An NACA 4412 airfoil is sinusoidally pitched about the quarter chord point between the angle of attack -6$^{\circ}$ and +6$^{\circ}$. A hot-wire anemometer is used to measure the phase-averaged mean velocities in the near-wake region of an oscillating airfoil. The freestream velocities of present work are 3.4, 12.4, 26.2 m/s, and the corresponding Reynolds numbers are 5.3${\times}10^4$, 1.9${\times}10^5$, 4.l${\times}10^5$, and the reduced frequency is 0.1. Streamwise velocity profiles are presented to show the Reynolds number effects on the near-wake region behind an airfoil oscillating in pitch. All the cases in these measurements show that the velocity defects by the change of the Reynolds number are very large at the lowest Reynolds number $R_N$=5.3${\times}10^4$: and are small at the other Reynolds numbers ($R_N$=1.9${\times}10^5$ and 4.l${\times}10^5$) in the near-wake region. A significant difference of phase-averaged mean velocity between 5.3${\times}10^4$, and 1.9${\times}10^5$ is observed. The present study shows that a critical value of Reynolds number in the near-wake of an oscillating airfoil exists in the range between 5.3${\times}10^4$, and 1.9${\times}10^5$.

• Applied Chemistry for Engineering
• /
• v.23 no.6
• /
• pp.521-528
• /
• 2012

In this study, we analyzed the physical properties of an ethylene oxide adducted amphoteric surfactant such as critical micelle concentration, surface tension, interfacial tension, contact angle, viscosity and phase behavior. The dual function characteristics of an amphoteric surfactant were investigated by determining an isoelectric point, which were attained using zeta potential measurements and quartz crystal microbalance (QCM) experiments. The isoelectric points of DE3-OSA82-AO, DE5-OSA82-AO and DE9-OSA82-AO surfactant systems determined by zeta potential measurements were 6.97, 6.93 and 7.10 respectively and they are in good agreement with the isoelectric point values measured by QCM experiments. The frictional property measured using an automated mildness tester showed that the DE-OSA82-AO surfactant could provide a good softening effect at neutral condition.

• Membrane Journal
• /
• v.32 no.4
• /
• pp.253-263
• /
• 2022

This study suggests a guideline for designing unit process of wastewater reuse in terms of a maintenance of the process based on critical parameters to draw a high quality performance of RO unit. Defining the parameters was done by applying membrane integrity test (MIT) in pretreatment process utilizing lab-scale MF. SDI is utilized for judging whether permeate is suitable to RO unit. However, result said TOC concentration matching with particle count analysis is better for judging the permeate condition. When membrane test pressure (P_test) was measured to derive log removal value in PDT, virgin state of membrane fiber was used to measure dynamic contact angle utilizing surface tension of the membrane fiber. Actually, foulant affects to the state of membrane surface, and it decreases the P_test value along with time elapsed. Consequently, LRV_DIT is also affected by P_test value. Thus, sensitivity of direct integrity test descends with result of P_test value change, so P_test value should be considered not the virgin state of the membrane but its current state. Overall, this study focuses on defining design parameters suitable to MF pretreatment for RO process in wastewater reuse by assessing its impact. Therefore, utilities can acknowledge that the membrane surface condition must be considered when users conduct the direct integrity test so that P_test and other relative parameter used to calculate LRV_DIT are adequately measured.