• Title/Summary/Keyword: Critical Tension

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Emulsifying Properties of Surface-Active Substances from Defatted Rapeseed Cake by Supercritical Carbon Dioxide Extraction (초임계 $CO_2$ 유체 추출법으로 얻은 탈지 유채박 중 표면활성 물질의 유화 성질 연구)

  • Kim, Jeong-Won;Jeong, Yong-Seon;Lee, Eui-Seok;Gil, Na-Young;Kim, San-Seong;Kim, Hyun-Hyo;Kim, Tae Young;Lee, Yong-Hwa;Jang, Young-Seok;Lee, Ki-Teak;Hong, Soon-Taek
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.4
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    • pp.635-648
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    • 2013
  • This study was carried out to investigate the emulsifying properties of surface-active substances from defatted rapeseed cake by supercritical $CO_2$ extraction. Based on the interfacial tension data, a supercritical fluid extract (SFE) with the lowest value of 14.16 mN/m was chosen for evaluation which was obtained from No. 2 extraction condition (150 bar, $65^{\circ}C$, 250 g). For emulsions with SFE, some physicochemical properties (i.e., fat globule size, creaming stability, zeta potential etc) were investigated according to changes in SFE concentration, pH, and NaCl addition in an emulsion. It was found that fat globule size was decreased with increasing SFE concentration in emulsion, with showing a critical value at 0.5 wt%, thereby resulting in less susceptibility to creaming behavior. The SFE emulsion also showed instability at acidic conditions (pH<7.0) as well as by NaCl addition. This was coincided with zeta potential data of emulsion. In addition, SSL (sodium stearoyl lactylate) found to be suitable as a co-surfactant, as it helped considerably in decreasing fat globule size in emulsions and its optimum concentration to be over 0.03 wt%, based on 0.1 wt% SFE in emulsion.

Decomposition of Shear Resistance Components in Reinforced Concrete Beams (철근콘크리트 보의 전단저항 성분 분해)

  • Rhee, Chang-Shin;Shin, Geun-Ok;Kim, Woo
    • Journal of the Korea Concrete Institute
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    • v.18 no.6 s.96
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    • pp.819-825
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    • 2006
  • The objective of the present study is to verify the validity of a new truss model for evaluating the contribution by arch action to shear resistance in shear-critical reinforced concrete beams. The new truss model is based on the relationship between shear and bending moment in a beam subjected to combined shear and bending. The compatibility condition of the shear deformation that deviates from Bernoulli bending plane is formulated utilizing the smeared truss idealization with an inclined compression chord. The Modified Compression Filed Theory is employed to calculate the shear deformation of the web, and the relative axial displacements of the compression and the tension chord by the shear flow are also calculated. From this shear compatibility condition in a beam, the shear contribution by the arch action is numerically decoupled. Then the validity of the model is examined by applying the model to some selected test beams in literatures. On the basis of the analytical results, the contribution by the web to shear resistance can be constant and have an excellent linear correlation with the web reinforcement ratio. The present decoupling approach may provide a simple way for the assessment of the role of each parameter or mechanism that affects the ultimate shear behavior of reinforced concrete beams.

Reappraisal of Empowerment through Giddens's Theory of Reflexivity -In Quest of the Integrated Paradigm for Social Welfare Practice- (기든스(Giddens)의 성찰성 이론을 통한 임파워먼트의 재해석 -통합적 사회복지실천 패러다임에 대한 탐색-)

  • Choi, Myungmin;Kim, Giduk
    • Korean Journal of Social Welfare
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    • v.65 no.2
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    • pp.103-130
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    • 2013
  • Although both ecosystem theory and empowerment have become the most prevalent candidate for integrated paradigm for social welfare practices, they could not overcome completely the long-standing and sharp divides between micro and macro practices, that is, between subject and structure as a main explanatory element in social welfare realm. Along with such traditional dualism and tension, a new emerging divide between modernism and postmodernism regarding intrinsic mission and roles of social welfare has urged strongly to develop the overarching theoretical framework for social welfare practice. In this regard, this study aims to recast the ecosystem theory and empowerment through the reflexive modernization theory of critical sociologist Anthony Giddens. With relatively strong emphasis on human capability coined as the reflexivity, Giddens's own creative theory of modernization can be thoroughly expected to provide a solid foundation of integrated paradigm enough to bridge the existing dualisms in social welfare theory and practice. Especially, his unique account of integrated way of how human agency is involved in the construction of social structure and how to transform each other recursively has profound implication for empowerment to be adequate and proper comprehensive framework for social welfare practice.

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Multiscale modeling of reinforced/prestressed concrete thin-walled structures

  • Laskar, Arghadeep;Zhong, Jianxia;Mo, Y.L.;Hsu, Thomas T.C.
    • Interaction and multiscale mechanics
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    • v.2 no.1
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    • pp.69-89
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    • 2009
  • Reinforced and prestressed concrete (RC and PC) thin walls are crucial to the safety and serviceability of structures subjected to shear. The shear strengths of elements in walls depend strongly on the softening of concrete struts in the principal compression direction due to the principal tension in the perpendicular direction. The past three decades have seen a rapid development of knowledge in shear of reinforced concrete structures. Various rational models have been proposed that are based on the smeared-crack concept and can satisfy Navier's three principles of mechanics of materials (i.e., stress equilibrium, strain compatibility and constitutive laws). The Cyclic Softened Membrane Model (CSMM) is one such rational model developed at the University of Houston, which is being efficiently used to predict the behavior of RC/PC structures critical in shear. CSMM for RC has already been implemented into finite element framework of OpenSees (Fenves 2005) to come up with a finite element program called Simulation of Reinforced Concrete Structures (SRCS) (Zhong 2005, Mo et al. 2008). CSMM for PC is being currently implemented into SRCS to make the program applicable to reinforced as well as prestressed concrete. The generalized program is called Simulation of Concrete Structures (SCS). In this paper, the CSMM for RC/PC in material scale is first introduced. Basically, the constitutive relationships of the materials, including uniaxial constitutive relationship of concrete, uniaxial constitutive relationships of reinforcements embedded in concrete and constitutive relationship of concrete in shear, are determined by testing RC/PC full-scale panels in a Universal Panel Tester available at the University of Houston. The formulation in element scale is then derived, including equilibrium and compatibility equations, relationship between biaxial strains and uniaxial strains, material stiffness matrix and RC plane stress element. Finally the formulated results with RC/PC plane stress elements are implemented in structure scale into a finite element program based on the framework of OpenSees to predict the structural behavior of RC/PC thin-walled structures subjected to earthquake-type loading. The accuracy of the multiscale modeling technique is validated by comparing the simulated responses of RC shear walls subjected to reversed cyclic loading and shake table excitations with test data. The response of a post tensioned precast column under reversed cyclic loads has also been simulated to check the accuracy of SCS which is currently under development. This multiscale modeling technique greatly improves the simulation capability of RC thin-walled structures available to researchers and engineers.

Fabrication of the poly (methyl methacrylate)/clay (modified with fluorinated surfactant) nanocomposites using supercritical fluid process (초임계 공정을 이용한 poly(methyl methacrylate)/클레이 나노복합체 제조)

  • Kim, Yong-Ryeol;Jeong, Hyeon-Taek
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.2
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    • pp.231-237
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    • 2014
  • The supercritical fluids (SCFs) have been widely used for material synthesis and processing due to their remarkable properties including low viscosity, high diffusivity and low surface tension. Carbon dioxide is one of the suitable solvents in SCFs processes in terms of its advantages such as easy processibility (with low critical temperature and pressure), inexpensive, nonflammable, nontoxic, and readily available. However, it has generally low solubility for high molecular weight polymers with the exception of fluoropolymers and siloxane polymers. Therefore, hydrocarbon solvents and hydrochlorofluorocarbons have been used for various SCFs process by its high solubility for high molecular weight polymers. In this report, a PMMA/clay nanocomposites were fabricated by using supercritical fluid process. The $Na^+$-MMT(montmorillonites)was modified by a fluorinated surfactant which is able to enhance compatibility with the chlorodifluoromethane(HCFC-22) and thus, improve dispersability of the clay in the polymer matrix. The PMMA/fluorinated surfactant modified clay nanocomposite shows enhanced mechanical and thermal properties which characterized by X-raydiffraction(XRD), Thermo gravimetric analysis(TGA), Dynamic mechanical analysis (DMA) and Transmission electron microscopy (TEM).

Soil Evaporation Evaluation Using Soil Moisture Measurements at a Hillslope on a Mountainous Forest (산림 사면에서 실측 토양수분을 이용한 토양증발평가)

  • Gwak, Yong-Seok;Kim, Sang-Hyun
    • Journal of Korea Water Resources Association
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    • v.45 no.6
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    • pp.557-568
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    • 2012
  • In order to understand the hydrological processes on the mountainous forest, the configuration of soil evaporation (E) out of evapotranspiration (ET) is a challenging and important topic. In this study, we attempted to understand the soil evaporation process for a humid forest hillslope via measuring and analyzing soil moistures with a sampling interval in 2 hours at three locations for 10 days between May 22th and 31th 2009. Two methods were used to estimate soil evaporation in every 2hr; one is a method using soil moisture measurement ($E_{SM}$), the others methods are based on Penman equation (Penman (1948), Staple (1974), Konukcu (2007), Equilibrium Penman ($E_{equili}$)). As a critical parameter in determining $E_{SM}$, the dry surface layer (DSL), was estimated using energy balance equation. The accumulated soil evaporation ($E_{SM}$) of A, B, C points were estimated as 2.09, 1.08 and 2.88 mm, respectively. The estimated evaporation of Penman (1948), Staple (1974), Konukcu (2007), $E_{equili}$ were 4.91, 8.80, 8.63 and 3.28 mm. The proposed method with soil moisture measurement showed lower soil evaporations than the other conventional methods. The increasing soil temperature and interaction between soil and atmosphere due to existence of litter and DSL are considered as dominant factors for soil evaporation. The $E_{SM}$ has the apparent lag time between 2 and 4 hr compared with $E_{equili}$ and net radiation. The DSL and surface resistance ($r_s$) were increased as soil moisture was decreased for in this study. The estimated DSL through the temporal distribution analysis of soil moisture and tension measurements was also similar to that of the energy balance relationship.

EXPRESSION OF BMP-2, -4 DURING DISTRACTION OSTEOGENESIS IN THE RABBIT MANDIBLE (집토끼 하악골에서 신연 골형성술시 BMP-2,-4의 발현)

  • Kim, Sang-Woo;Jee, Yu-Jin;Song, Hyun-Chul
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.30 no.3
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    • pp.193-202
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    • 2004
  • Distraction osteogenesis(DO) is defined as a gradual mechanical process of mechanical stretching two vascularized bone surface apart with a critical rate and rhythm such that new bone forms within the expanding gap, reliably bridges the gap, and ultimately remodels to normal structure. DO has become a mainstay in bone tissue engineering and has significantly improved our armamentarium for reconstructive craniomaxillofacial procedures. But the molecular and biological mechanisms that regulate the formation of new bone during distraction osteogenesis are not completely understood. BMPs are potent osteoinductive agents. Our hypothesis was that BMPs, especially BMP-2 and BMP-4, might play an importent role in the signaling pathways that link the mechanical forces created by distraction to biological responses and in promting new bone formation. Using a rabbit's mandible, we investigated the expression of BMP-2, -4 at different time points during distraction osteogenesis. The purpose of this study is to research the pattern of expression of BMP-2, -4 in new bone formation during distraction osteogenesis of the rabbit mandible. The experimental group was applied gradual distraction (0.7mm a day by twice a day, 4.9mm in total, for 7 days) and the control group was carried out osteotomy alone. They were examined clinically, histologically, and by RT-PCR analysis. On 3 days after osteotomy, the high level of expression of BMP-2, -4 was detected. But, the expression of BMP-4 was decreased during latency period. As distraction was started, its expression was increased and maintained till postoperative 28days. In control group, the expression of BMP-4was remarkably decreased till postoperative 14 days. On the other hand, the expression of BMP-2 was no difference between experimental group and control group. The expression of BMP-4 was maintanined at high level during the entire experimental period in both group. These findings suggested that excellent bone formation during distraction osteogenesis is associated with enhanced expression of BMP-4 genes by mechanical tension stress.

The Neuroanatomy and Psychophysiology of Attention (집중의 신경해부와 정신생리)

  • Lee, Sung-Hoon;Park, Yun-Jo
    • Sleep Medicine and Psychophysiology
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    • v.5 no.2
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    • pp.119-133
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    • 1998
  • Attentional processes facilitate cognitive and behavioral performance in several ways. Attention serves to reduce the amount of information to receive. Attention enables humans to direct themselves to appropriate aspects of external environmental events and internal operations. Attention facilitates the selection of salient information and the allocation of cognitive processing appropriate to that information. Attention is not a unitary process that can be localized to a single neuroanatomical region. Before the cortical registration of sensory information, activation of important subcortical structures occurs, which is called as an orienting response. Once sensory information reaches the sensory cortex, a large number of perceptual processes occur, which provide various levels of perceptual resolution of the critical features of the stimuli. After this preattentional processing, information is integrated within higher cortical(heteromodal) systems in inferior parietal and temporal lobes. At this stage, the processing characteristics can be modified, and the biases of the system have a direct impact on attentional selection. Information flow has been traced through sensory analysis to a processing stage that enables the new information to be focused and modified in relation to preexisting biases. The limbic and paralimbic system play significant roles in modulating attentional response. It is labeled with affective salience and is integrated according to ongoing pressures from the motivational drive system of the hypothalamus. The salience of information greatly influences the allocation of attention. The frontal lobe operate response selection system with a reciprocal interaction with both the attention system of the parietal lobe and the limbic system. In this attentional process, the search with the spatial field is organized and a sequence of attentional responses is generated. Affective, motivational and appectitive impulses from limbic system and hypothalamus trigger response intention, preparation, planning, initiation and control of frontal lobe on this process. The reticular system, which produces ascending activation, catalyzes the overall system and increases attentional capacity. Also additional energetic pressures are created by the hypothalamus. As psychophysiological measurement, skin conductance, pupil diameter, muscle tension, heart rate, alpha wave of EEG can be used. Event related potentials also provide physiological evidence of attention during information process. NI component appears to be an electrophysiological index of selective attention. P3 response is developed during the attention related to stimulus discrimination, evaluation and response.

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The Limitations of Holocaust Narratives and the Possibility of Healing Narratives Suggested by Smith's Fires in the Mirror ('홀로코스트' 서사의 한계와 스미스의 『거울 속에 반영된 분노』에 제시된 치유 서사의 가능성)

  • Jung, Sun-kug
    • Cross-Cultural Studies
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    • v.43
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    • pp.377-404
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    • 2016
  • In this paper, I intend to focus on the 1991 racial tension and violence portrayed in Anna Devear Smith's book Fires in the Mirror, which was published in book form in 1993. I make use of a series of interviews with many of those involved in the conflicts, which were based on the Jewish Holocaust and the history of African American enslavement. In Crown Heights, the black community and the Jewish community have each suffered terrible losses, but individuals and communities become rhetorically attached to foundational historical traumas that lie at the center of each group's cultural identity rather than try to understand each other's pain. Smith lets this rhetoric dominate Fires in the Mirror by putting contradictory monologues side by side in order to show how discourses on 'slavery' and 'the Holocaust' still have control over specific ethnic communities. My intention is not to delve into the conflict between the Jewish and black communities exclusively. Rather, I attempt to form an understanding of the problems of the critical/theoretical tenets proposed by 'the rhetoric of holocaust,' including the Jewish Holocaust and the black experience of enslavement. Such an understanding will help us see the failure in the theories, illuminating the ways that such rhetoric should have recognized its own violence and helped to forge a new relationship between racism and anti-Semitism. Fires in the Mirror mirrors back to us the ways that 'the Holocaust' betrays the possibility of error to indicate its own susceptibility to blindness. The cracks brought forth by conflicting narratives enable readers to observe wounds being healed and the possibility of new narrative looming up.

Synthesis of Saccharide Nonionic Biosurfactants from Coconut Oil and Characterization of Their Interfacial Properties (코코넛 오일로부터 유래된 당계 비이온 계면활성제 합성 및 계면 특성 연구)

  • Jo, SeonHui;Lee, YeJin;Park, KiHo;Lim, JongChoo
    • Applied Chemistry for Engineering
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    • v.30 no.4
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    • pp.435-444
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    • 2019
  • In this study, two types of nonionic saccharide biosurfactants, GP-6 and GP-7, were prepared from coconut oil and the structure of resulting products was investigated by FT-IR, $^1H-NMR$ and $^{13}C-NMR$ spectrophotometer. The interfacial properties of GP-6 and GP-7 were found to be excellent from interfacial property measurements such as critical micelle concentration, static and dynamic surface tensions, interfacial tension, emulsification power, wetting property and foam stability. Detergency test evaluated by using a Terg-o-tometer showed moderately good detergency compared to that of conventional surfactants used in detergent formulations. Biodegradability, acute oral toxicity, acute dermal irritation and acute eye irritation tests revealed that both surfactants possess excellent mildness and superior environmental compatibility indicating the potential applicability to detergent products formulations. In particular, GP-6 can be considered as a strong candidate in detergent formulations since it is more surface active, mild and readily biodegradable than GP-7.