• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2002년도 추계학술발표대회 논문집
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• pp.265-268
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• 2002

In this work, the blend system of epoxy and PMR-15 polyimide is investigated in terms of the cure behaviors and thermal stabilities. The cure behaviors are studied in DSC measurements and thermal stabilities are also carried out by TGA analysis. DDM (4, 4'-diamino diphenyl methane) is used as curing agent for EP and the content of PMR-15 is varied within 0, 5, 10, 35, and 20 phr to neat EP. As a result, the cure activation energy ($E_a$) is increased at 10 phr of PMR-15, compared with that of neat EP. From the TGA results of EP/PMR-15 blend system, the thermal stabilities based in the initial decomposed temperature (IDT) and integral procedural decomposition temperature (IPDT) are increased with increasing the PMR-15 content. The fracture toughness, measured in the context of critical stress intensity factor ($K_{IC}$) and critical strain energy release rate ($G_{IC}$), shows a similar behavior with $E_a$. This result is probably due to the crosslinking developed by the interactions between intermolecules in the polymer chains.

• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2009년도 학술논문요약집
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• pp.187-187
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• 2009

Opening of fractures induced by shear dilation or normal deformation can be a significant source of fracture permeability change in fractured rock, which is important for the performance assessment of geological repositories for spent nuclear fuel. As the repository generates heat and later cools the fluid-carrying ability of the rocks becomes a dynamic variable during the lifespan of the repository. Heating causes expansion of the rock close to the repository and, at the same time, contraction close to the surface. During the cooling phase of the repository, the opposite takes place. Heating and cooling together with the, virgin stress can induce shear dilation of fractures and deformation zones and change the flow field around the repository. The objectives of this work are to examine the contribution of thermal stress to the shear slip of fracture in mid- and far-field around a KBS-3 type of repository and to investigate the effect of evolution of stress on the rock mass permeability. In the first part of this study, zones of fracture shear slip were examined by conducting a three-dimensional, thermo-mechanical analysis of a spent fuel repository model in the size of 2 km $\times$ 2 km $\times$ 800 m. Stress evolutions of importance for fracture shear slip are: (1) comparatively high horizontal compressive thermal stress at the repository level, (2) generation of vertical tensile thermal stress right above the repository, (3) horizontal tensile stress near the surface, which can induce tensile failure, and generation of shear stresses at the comers of the repository. In the second part of the study, fracture data from Forsmark, Sweden is used to establish fracture network models (DFN). Stress paths obtained from the thermo-mechanical analysis were used as boundary conditions in DFN-DEM (Discrete Element Method) analysis of six DFN models at the repository level. Increases of permeability up to a factor of four were observed during thermal loading history and shear dilation of fractures was not recovered after cooling of the repository. An understanding of the stress path and potential areas of slip induced shear dilation and related permeability changes during the lifetime of a repository for spent nuclear fuel is of utmost importance for analysing long-term safety. The result of this study will assist in identifying critical areas around a repository where fracture shear slip is likely to develop. The presentation also includes a brief introduction to the ongoing site investigation on two candidate sites for geological repository in Sweden.

• 콘크리트학회지
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• 제11권2호
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• pp.177-186
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• 1999

본 연구의 목적은 탄소섬유쉬트로 보강된 시험체의 주요 파괴모드인 계면모드인 계면박리 모드에 의한 부재의 파괴를 규명하는 것이다. 탄소섬유쉬트로 보강된 손상된 보시험체의 계면박리 모드를 해석하기 위하여 선형탄성 파괴역학(LEFM)의 컴플라이언스법과 유한요소법을 사용하여 계면파괴 역학변수인 에너지해방율(strain energy release rate, G)을 고찰하였다. 손상된 단순 보시험체의 해석결과, 최대 에너지해방율($G_{max}$)은 에폭시 접착두께에 관계없이 바깥 휨균열에서 시작된 계면 전단 균열 길이가 18mm 부근에서 발생하였다. 보강보의 강도 해석결과, 극한강도 설계법에 따른 단면의 공칭 휨 강도에 대한 계면박리에 의해 부재가 파괴되는 것으로 해석되었다. 또한 적용된 접착두께 1mm~3mm는 에너지해방율에 거의 영향을 미치지 않아 계면박리의 주요 인자가 아닌 것으로 나타났다.

• 폴리머
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• 제27권1호
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• pp.33-39
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• 2003

본 논문에서는 비스페놀계 2관능성 에폭시 수지 DGEBA/DGEBS 블렌드 시스템의 경화거동, 열안정성, 그리고 파괴인성 특성을 고찰하였다. DGEBA/DGEBS 블렌드 시스템의 함량비율을 100 : 0, 90 : 10, 80 : 20, 70 : 30, 그리고 60 : 40 wt%까지 변화시켰으며, DSC에 의한 열분석을 통하여 Ozawa식으로 경화 활성화 에너지 ($E_a$)를 계산하였으며, TGA 열분석을 사용하여 열분해 개시 온도(IDT), 최대 무게 감량시 온도($T_{max}$), 그리고 적분 열분해 진행 온도(IPDT) 등 열안정성 인자를 고찰하였다. 경화된 시편의 파괴인성 특성은 크랙성장 저항을 나타내는 임계응력세기 인자 ($K_{IC}$) 실험을 통하여 알아보았으며, 주사전자현미경 (SEM)을 사용하여 시편의 파단 특성을 조사하였다. 실험 결과 DGEBA/DGEBS 블렌드 시스템의 $E_a$, IPDT, 그리고 $K_{IC}$는 DGEBS 함량이 20 wt%인 경우 최대값을 나타내었는데, 이는 설폰기의 도입으로인한 치밀한 네트워크 구조의 형성때문이라 사료된다.

• Carbon letters
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• 제14권1호
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• pp.58-61
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• 2013

In this work, the effect of catalysts on the mechanical properties of carbon fibers-reinforced epoxy matrix composites cured by cationic latent thermal catalysts, i.e., N-benzylpyrazinium hexafluoroantimonate (BPH) was studied. Differential scanning calorimetry was executed for thermal characterization of the epoxy matrix system. Mechanical interfacial properties of the composites were studied by interlaminar shear strength (ILSS), critical stress intensity factor ($K_{IC}$), and specific fracture energy ($G_{IC}$). As a result, the conversion of neat epoxy matrix cured by BPH was higher than that of one cured by diaminodiphenyl methane (DDM). The ILSS, $K_{IC}$, $G_{IC}$, and impact strength of the composites cured by BPH were also superior to those of the composites cured by DDM. This was probably the consequence of the effect of the substituted benzene group of BPH catalyst, resulting in an increase in the cross-link density and structural stability of the composites studied.

• Carbon letters
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• 제11권2호
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• pp.102-106
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• 2010

In this work, the effect of aminized multi-walled carbon nanotubes (NH-MWNTs) on the mechanical interfacial properties of epoxy nanocomposites was investigated by means of fracture toughness, critical stress intensity factor ($K_{IC}$), and impact strength testing, and their morphology was examined by scanning electron microscope (SEM). It was found that the incorporation of amine groups onto MWNTs was confirmed by the FT-IR and Raman spectra. The mechanical interfacial properties of the epoxy nanocomposites were remarkably improved with increasing the NH-MWNT content. It was probably attributed to the strong physical interaction between amine groups of NH-MWNTs and epoxide groups of epoxy resins. The SEM micrographs showed that NH-MWNTs were uniformly embed and bonded with epoxy resins, resulted in the prevention of the deformation and crack propagation in the NH-MWNTs/epoxy nanocomposites.

• 한국안전학회지
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• 제24권3호
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• pp.1-6
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• 2009

Recently power plants and oil refineries are focusing on capacity enlargement for better efficiency through higher temperature and higher pressure. Thickness of boiler tubes becomes lessened due to oxidation and erasion caused by high temperature bums gas flowing over tubes outside. Accordingly, mechanical stress of tubes is increasing and that is a critical factor to make a crack and fracture. To prevent those sorts of accidents, aging assessment for proper periodic repair and replacement should be conducted reliably and reasonably. We performed IIT test on Cr-Mo steel, one of the most heat-resistant materials for facilities in power plants, and we report the test result and the considerable effectiveness of IIT test.

• Journal of the Korean Wood Science and Technology
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• 제17권4호
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• pp.83-88
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• 1989

목재의 섬유방향에 경사진 균열의 모-드I과 모-드II의 혼합모-드파괴시의 파괴거동을 조사하기 위하여 라왕(Shorea Spp.)의 LA시스템에 있어서 서로 다른 경사각도를 가진 SEN시험편(Single edge notch specimen)에 대하여 휨 시험을 행하였다. 얻이진 결과는 혼합모-드파괴시, 모-드I응력확대계수$K_I$과 모-드II응력확대계수$K_II$간에 일정한 상호작용이 존재한다는 것을 나타내었다. 또한, 모-드I과 모-드II의 임계응력확대계수(Critical stress intensity factor) $K_{IC}$와 $K_{IIC}$ 이용하여 혼합모-드파괴시의 $K_I$과 $K_II$간의 상호관계를 규정할 수 있었으며, 이미 보고된 여러 실험식과 본 실험결과를 비교하여 가장 적합한 관계로서 아래와 같은 관계를 얻을 수 있었다.

• 콘크리트학회논문집
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• 제16권6호
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• pp.841-850
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• 2004

전 세계적으로 많은 수의 크고 작은 댐이 사용되고 있으나, 콘크리트 댐의 안전성 평가에 있어서 댐 내에 필연적으로 존재하는 균열을 함께 고려한 실질적 해석은 아직 미진한 실정이다. 따라서 향후 건설될 댐에 대해서는 설계 단계에서부터 이러한 파괴역학적 해석이 뒷받침되어야 댐의 안전성 확보에 매우 유리하다고 볼 수 있다. 특히 댐 제체와 지반이 접하는 경계면은 많은 균열 발생이 예상되는 영역으로써 이 균열 사이에 작용하는 양압력의 모델링은 중력식 콘크리트 댐 해석시 매우 중요한 요소이다. 즉, 콘크리트 댐의 균열 안정성 평가는 정확한 양압력의 모델링이 선행되어야 올바른 예측이 가능하다. 댐에 있어서 양압력의 취급은 단지 댐 체제 안정성 평가를 위한 전형적인 수계산 방법으로 널리 사용되고 있으나, 양압력에 대한 유한요소 모델링 방법은 연구가 부족한 실정이다. 본 연구에서는 중력식 콘크리트 댐과 지반이 접하는 부분에 발생된 균열에 양압력이 작용할 경우, 선형탄성파괴역학의 관점에서 접근하여 양압력이 응력확대계수에 미치는 영향을 비교 분석하였다. 양압력의 분포형상은 현재 등분포로 가정한 간략해석법으로 수행되고 있으나 최근의 연구 결과에 의하면 양압력 분포형상이 균열면에 따라 변화함을 보이고 있어, 본 연구에서는 수압의 형태를 등분포 형상 외에 삼각형 분포, 제형분포 및 포물선 분포 형상에 대해서도 각각 고려하여 각 분포형상별 응력확대계수를 평가하였다. 응력확대계수의 계산은 일반 8절점 등매개변수요소를 사용한 표면적분법을 사용하였으며, 자중의 영향 및 월류 수압의 영향도 함께 고려하여 해석 결과를 나타내었다.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2005년도 춘계학술대회논문집
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• pp.925-934
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• 2005

The dynamic response due to the unbalance and crack and the quasi-static response due to gravity are analytically derived based on the complex transfer matrix. The additional slope is expressed as function of the bending moment at crack position based on the fracture mechanics concept, and inversely the bending moment is expressed as function of the additional slope at the crack position. At each angle step during the shaft revolution, the additional slope and bending moment are calculated by an iterative method. The transient behavior is considered by introducing Fourier series expansion concept for the additional slope. Simulation is carried out for a simple rotor similar to those available in the literature and comparison of the basic crack behavior is shown. Using the additional slope, the cracked rotor behavior is explained with the crack depth increased: the magnitude of the additional slope increases and the closed crack duration during a revolution decreases as the crack depth increases. The direction of unbalance is also shown as a factor to affect the crack breathing. Whirl orbits are shown near the sub-critical speed ranges of the rotor.