• Composites Research
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• v.16 no.3
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• pp.25-31
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• 2003

In this work the effect of surface treated SiC on thermal stability and mechanical interfacial properties of carbon fiber/epoxy resin composites. The surface properties of the SiC were determined by acid/base values and contact angles. The thermal stabilities of carbon fiber/epoxy resin composites were investigated by TGA. The mechanical interfacial properties of the composites were studied in ILSS, critical stress intensity factor ($\textrm{K}_{IC}$), and critical strain energy release rate($\textrm{G}_{IC}$) measurements. As a result, the acidically treated SiC(A-SiC) had higher acid value than untreated SiC(V-SiC) or basically treated SiC(B-SiC). According to the contact angle measurements, it was observed that chemical treatments led to an increase of surface free energy of the SiC surfaces, mainly due to the increase of the specific(polar) component. The mechanical interfacial properties of the composites including ILSS, $\textrm{K}_{IC}$, and $\textrm{G}_{IC}$ had been improved in the specimens treated by chemical solutions. These results were explained that good wetting played an important role in improving the degree of adhesion at interfaces between SiC and epoxy resin matrix.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2002.10a
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• pp.265-268
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• 2002

In this work, the blend system of epoxy and PMR-15 polyimide is investigated in terms of the cure behaviors and thermal stabilities. The cure behaviors are studied in DSC measurements and thermal stabilities are also carried out by TGA analysis. DDM (4, 4'-diamino diphenyl methane) is used as curing agent for EP and the content of PMR-15 is varied within 0, 5, 10, 35, and 20 phr to neat EP. As a result, the cure activation energy ($E_a$) is increased at 10 phr of PMR-15, compared with that of neat EP. From the TGA results of EP/PMR-15 blend system, the thermal stabilities based in the initial decomposed temperature (IDT) and integral procedural decomposition temperature (IPDT) are increased with increasing the PMR-15 content. The fracture toughness, measured in the context of critical stress intensity factor ($K_{IC}$) and critical strain energy release rate ($G_{IC}$), shows a similar behavior with $E_a$. This result is probably due to the crosslinking developed by the interactions between intermolecules in the polymer chains.

• Polymer(Korea)
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• v.37 no.1
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• pp.61-65
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• 2013

In this work, the anodic oxidation of carbon fibers was carried out to enhance the mechanical interfacial properties of carbon fibers-reinforced epoxy matrix composites. The surface characteristics of the carbon fibers were studied by FTIR, X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM). Also, the mechanical interfacial properties of the composites were studied with interlaminar shear strength (ILSS), critical stress intensity factor ($K_{IC}$), and critical strain energy release rate ($G_{IC}$). The anodic oxidation led to a significant change in the surface characteristics of the carbon fibers. The anodic oxidation of carbon fiber improved the mechanical interfacial properties, such as ILSS, $K_{IC}$, and $G_{IC}$ of the composites. The mechanical interfacial properties of the composites anodized at 20% sulfuric/nitric (3/1) were the highest values among the anodized carbon fibers. These results were attributed to the increase of the degree of adhesion at interfaces between the carbon fibers and the matrix resins in the composite systems.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.22 no.2
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• pp.416-427
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• 1998

Unidirectional commingled-yarn-based carbon fiber(CF)/polyamide(PA) 6 composite was fabricated under molding pressures of 0.4, 0.6 and 1.0 MPa to study its flexural deformation and fracture behavior. Fiber/matrix interfacial bonding area became larger with an increase of molding pressure from 0.4 to 0.6 MPa. For molding pressures .geq. 0.6 MPa, good flexural performance of similar magnitudes was attained. For the fracture test, four kinds of notch direction were adopted : edgewise notches parallel (L) and transverse (T) to the major direction of fiber bundles, and flatwise notches parallel(ZL) and perpendicular(ZT) to this direction. Nominal bend strength for L and ZL specimens exhibited high sensitivity to notching. ZL specimens revealed the lowest values of the critical stress intensity factor $K_c$ which was slightly superior to those of unfilled PA6 matrix. Enlargement of the compression area for T specimens was analyzed by means of the rigidity reduction resulting from the fracture occurrence.

• Journal of the Korean Society of Safety
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• v.32 no.3
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• pp.1-7
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• 2017

Particle reinforced composites are materials that have enhanced physical properties by adding particle reinforcements to polymer materials and have been applied to a wide range of fields such as the aerospace, bio-technology and automative industry. In this study, particle reinforced composites were prepared by mixing $SiC/Al_2O_3$ to the vinyl ester as the thermoset resin. The purpose of this study is to evaluate mechanical properties and fracture behavior by the tensile test and single edge notch specimen according to the addition ratio of reinforcement. Addition of 1 and 2 wt% of the particle reinforcement to the vinyl-ester resin was effective for the strength improvement. However, when it was more than 3 wt%, its strength was decreased. Also the highest elastic modulus obtained as 3.19 GPa was found at the 2 wt% addition of reinforcement. Futhermore the fracture toughness was evaluated by the energy release rate and the maximum critical energy release rate was obtained when 1 wt% reinforcement. The results show that the limit of adding of $SiC/Al_2O_3$ for improvement of the mechanical and fracture performance is 2 wt% reinforcement particles.

• Structural Engineering and Mechanics
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• v.37 no.2
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• pp.149-162
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• 2011

The aim of this research is a comprehensive review and evaluation of beam theories resting on elastic foundations that used to model mode-I delamination in multidirectional laminated composite by DCB specimen. A compliance based approach is used to calculate critical strain energy release rate (SERR). Two well-known beam theories, i.e. Euler-Bernoulli (EB) and Timoshenko beams (TB), on Winkler and Pasternak elastic foundations (WEF and PEF) are considered. In each case, a closed-form solution is presented for compliance versus crack length, effective material properties and geometrical dimensions. Effective flexural modulus ($E_{fx}$) and out-of-plane extensional stiffness ($E_z$) are used in all models instead of transversely isotropic assumption in composite laminates. Eventually, the analytical solutions are compared with experimental results available in the literature for unidirectional ($[0^{\circ}]_6$) and antisymmetric angle-ply ($[{\pm}30^{\circ}]_5$, and $[{\pm}45^{\circ}]_5$) lay-ups. TB on WEF is a simple model that predicts more accurate results for compliance and SERR in unidirectional laminates in comparison to other models. TB on PEF, in accordance with Williams (1989) assumptions, is too stiff for unidirectional DCB specimens, whereas in angle-ply DCB specimens it gives more reliable results. That it shows the effects of transverse shear deformation and root rotation on SERR value in composite DCB specimens.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.23 no.6 s.165
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• pp.1026-1038
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• 1999

Interlaminar fracture toughness of carbon/epoxy composite materials has been studied under tensile and flexural loading by the use of width tapered double cantilever beam(WTDCB) and end notched flexure(ENF) specimens. This study has significantly examined the effect of various interfacial ply orientation, ${\alpha}(0^{\circ},\;45^{\circ}\;and\;90^{\circ})$ and crack propagation direction, ${\theta}(0^{\circ},\;15^{\circ},\;30^{\circ}\;and\;45^{\circ})$ in terms of critical strain energy release rate through experiments. Twelve differently layered laminates were investigated. The data reduction for evaluating the fracture energy is based on compliance method and beam theory. Beam theory is used to analyze the effect of crack propagation direction. The geometry and lay-up sequence of specimens are considered various conditions such as skewness parameter, beam volume, and so on. The results show that the fiber bridging occurred due to the non-midplane crack propagation and causes the difference of fracture energy evaluated by both methods. For safer and more reliable composite structures, we obtain the optimal stacking sequence from initial fracture energy in each mode.

• Journal of the Korean Society of Safety
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• v.17 no.1
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• pp.1-5
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• 2002

An approach for the damage of delamination which is the major concern during mechanical working for composite laminate material is proposed based on linear elastic fracture mechanics. This paper presents method evaluating of damage crack length using by average thrust force with AE characteristics. Also, the relations of AE characteristics are obtained from delamination damages. We found the onset ply of the delamination and a critical energy release rate and expressed a stress intensity factor by AEcount equation.

• Journal of Ocean Engineering and Technology
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• v.10 no.4
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• pp.84-91
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• 1996

A fractal analysis on fracture surface of aluminium-particulate SiC composites was attempted. As the volume fraction of SiC in composites increases, the fractal dimension tends to increase. However, no correlation between the fractal dimension and the fracture toughness in terms of critical energy release rate was observed. Since the fractal dimension represents the roughness of fracture surface, the fracture toughness would be a function of not only fracture surface roughness but also additional parameters. Thus the applicability of fractal analysis to the estimation of fracture toughness must depend on the proper choice and interpretation of additioal paramerters. In this paper, the size of characteristic strctural unit for fracture was considered as an additional parameter. As a result, the size appeared to be a function of only volume fraction of SiC. Finally, a master curve for fracture toughness of aluminium-particulate SiC composites was proposed as a function of fractal dimension and volume fraction of SiC.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2005.04a
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• pp.80-83
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• 2005

In this work, effects of oxygen plasma on surface characteristics of carbon fibers were investigated in mechanical properties interfacial of carbon fibers-reinforced composites. The surface properties of the carbon fibers were determined by acid/base values, FT-IR, and X-ray photoelectron spectroscopy (XPS). Also, the mechanical properties of the composites were studied in and critical stress intensity factor ($K_{IC}$) and critical strain energy release rate mode II ($G_{IIC}$) measurements. As experimental results, the $O_{lS}/C_{lS}$ ratio of the carbon fiber surfaces treated by oxygen plasma was increased compared to that of untreated ones, possibly due to development of oxygen-containing functional groups. The mechanical properties of the composites, including $K_{IC}$ and $G_{IIC}$ had been improved in the oxygen plasma on fibers. These results could be explained that the oxygen plasma was resulted in the increase of the adhesion of between fibers and matrix in a composite system.