Kim, Ji-Hye;Kim, Moon-Sun;Hong, Sung-Chul;Kim, Byung-Woo
Korean Chemical Engineering Research
/
v.49
no.1
/
pp.62-68
/
2011
In the study, acrylate copolymer as MMA-co-GMA-co-AA with a high hardness and flexibility was synthesized for applying to the clear protection film, where GMA was used as a mediator to enhance polymerization-efficiency between MMA and AA. With an increase of GMA content, molecular weight and hardness of acrylate copolymer increased, however, flexibility decreased. With an increase of AA content, its molecular weight and hardness decreased, however, flexibility increased. Molar ratio of GMA/MMA and AA/GMA were optimized as 1.6 and 1.8, respectively, at 30 g of MMA to enhance hardness and flexibility of acrylate copolymer film. Molecular weight and Tg of the acrylate copoylmer were 13,300 g/mol and 136.5 $^{\circ}C$, respectively. Hardness of the coated film at 1.4 g/$m^2$ of spread was 1 H and no crack was observed at expansion ratio of 5% and 15%, respectively. Hardness of film was improved to 3 H by increasing spread of 4.1-4.6 g/$m^2$.
In this paper an experimental program was launched to determine the mechanical and durability properties of spall repair materials (RCC: 3 items, PCC: 2 items, PC: 3 items). Test items were mechanical property tests such as setting times, strengths, modulus of elasticity, plastic shrinkage, and durability tests such as dynamic modulus ratio, bond property with freeze-thaw, water absorption, chemical resistance, ultraviolet exposure. Modulus of the PC products exhibits ductile while the modulus is in the order of RCC > PCC > PC. At early ages the PC products experience higher plastic shrinkage than others, henceforth stable at 28 days. Other test results such as dynamic modulus ratio, absorption, and chemical resistance show that the PCs are superior to the PCCs and the RCCs. Except for PC-2, all patch materials had bond strength more than 1.3MPa after freeze-thaw cycles of 200~300 while the PCs and the PCCs seem to be better than the RCCs. With 500 hours of ultraviolet exposure, all patch materials showed to have no crack or deterioration at the surface.
The aim of this study was to investigate the physical properties of visible light curing Glass Ionomer cement for restorative esthetic filling. The control group was the autopolymerizing GC Fuji II Glass Ionomer cement (2.2: 1 P/L ratio) and the experimental groups were made by following procedure. To induce the polymerization by visible light, the powder of GC Fuji II GI cement and the liquid of Vitrabond for base & liner were mixed in an amalgam capsule with 2.5:1, 3.0:1, 3.5:1 P/L ratio (% wt/wt). After fabrication of specimens, compressive strength, fracture toughness ($K_{IC}$) Scanning Electron Microscope and X-ray Diffraction, water-leachable content, marginal leakage and surface roughness were studied. The results were as follows: 1. Only experimental No. 1 group (visible light curing) showed less compressive strength than control group 1 hour after curing. Strength was increased with aging in all groups, so the compressive strength of light curing groups was no less than that of autopolymerizing group after 3 weeks. 2. Experimental No.3 group (visible light curing) was inferior to No.2 group (visible light curing) in fracture resistance but light curing groups were more resistant to fracture than autopolymerizing group and showed ductile fracture pattern as compared with the brittle fracture pattern of autopolymerizing group. 3. From scanning electron microscopic image, various sized unreacted powder particles, surrounded by silica gel, were embedded in polysalt matrix. Light curing groups showed little crack and more dense unreacted particles than autopolymerizing group. 4. From X-ray diffraction analysis, GC Fuji II Glass Ionomer cement powder and all groups showed glassy appearance but light curing groups seemed to be more intensive in crystaline than autopolymerizing group. S. The most significant dissolution was shown in early setting period in all group. Light curing groups were dissolved less than autopolymerizing group. 6. Marginal leakage was not different significantly in case of cavity margin composed of same tooth structure (ex. only enamel margin, only dentin margin) but much more leakage was shown in dentin/cementum margin than enamel margin. In only case of only enamel margin, light curing groups were superior to autopolymerizing group. 7. All groups showed relatively smooth surface, which irregularity was less than $1{\mu}m$. Light curing groups were smoother than autopolymerizing group.
Park, Cheol-Hyeon;O, Jae-Eung;No, Yeong-Gyun;Lee, Sang-Tae;Kim, Mun-Deok
Proceedings of the Korean Vacuum Society Conference
/
2013.02a
/
pp.183-184
/
2013
Two main MBE growth techniques have been used: plasma-assisted MBE (PA-MBE), which utilizes a rf plasma to supply active nitrogen, and ammonia MBE, in which nitrogen is supplied by pyrolysis of NH3 on the sample surface during growth. PA-MBE is typically performed under metal-rich growth conditions, which results in the formation of gallium droplets on the sample surface and a narrow range of conditions for optimal growth. In contrast, high-quality GaN films can be grown by ammonia MBE under an excess nitrogen flux, which in principle should result in improved device uniformity due to the elimination of droplets and wider range of stable growth conditions. A drawback of ammonia MBE, on the other hand, is a serious memory effect of NH3 condensed on the cryo-panels and the vicinity of heaters, which ruins the control of critical growth stages, i.e. the native oxide desorption and the surface reconstruction, and the accurate control of V/III ratio, especially in the initial stage of seed layer growth. In this paper, we demonstrate that the reliable and reproducible growth of GaN on Si (110) substrates is successfully achieved by combining two MBE growth technologies using rf plasma and ammonia and setting a proper growth protocol. Samples were grown in a MBE system equipped with both a nitrogen rf plasma source (SVT) and an ammonia source. The ammonia gas purity was >99.9999% and further purified by using a getter filter. The custom-made injector designed to focus the ammonia flux onto the substrate was used for the gas delivery, while aluminum and gallium were provided via conventional effusion cells. The growth sequence to minimize the residual ammonia and subsequent memory effects is the following: (1) Native oxides are desorbed at $750^{\circ}C$ (Fig. (a) for [$1^-10$] and [001] azimuth) (2) 40 nm thick AlN is first grown using nitrogen rf plasma source at $900^{\circ}C$ nder the optimized condition to maintain the layer by layer growth of AlN buffer layer and slightly Al-rich condition. (Fig. (b)) (3) After switching to ammonia source, GaN growth is initiated with different V/III ratio and temperature conditions. A streaky RHEED pattern with an appearance of a weak ($2{\times}2$) reconstruction characteristic of Ga-polarity is observed all along the growth of subsequent GaN layer under optimized conditions. (Fig. (c)) The structural properties as well as dislocation densities as a function of growth conditions have been investigated using symmetrical and asymmetrical x-ray rocking curves. The electrical characteristics as a function of buffer and GaN layer growth conditions as well as the growth sequence will be also discussed. Figure: (a) RHEED pattern after oxide desorption (b) after 40 nm thick AlN growth using nitrogen rf plasma source and (c) after 600 nm thick GaN growth using ammonia source for (upper) [110] and (lower) [001] azimuth.
Bulletin of the Society of Naval Architects of Korea
/
v.27
no.4
/
pp.58-66
/
1990
A series of test was performed measuring the failure strength and failure mode of Gr/Pi, $[0^{\circ}/45^{\circ}/90^{\circ}/-45^{\circ}]_s$ laminate containing a single pin loaded hole. The finite element method is applied to calculate the stress distribution in the laminates, then the failure load and the failure mode were predicted by means of the characteristic length. 12 different geometric variations were developed to analyze the effects of the ratio of specimen width to hole diameter (W/d) and ratio of edge distance to hole diameter (L/d). X-Ray of NDE methods were utilized in finding out the initial defects, damage and the fracture mechanism, and SEM(Scanning Electron Microscopes) was used the evaluation of the fracture mechanism and crack propagation around hole under tension pin loading. $[0^{\circ}/45^{\circ}/90^{\circ}/-45^{\circ}]_s$ laminate are found to be most sensitive to W/d but not so influenced by L/d. The failure mode and tensile strength predicted by the model show agreement with experiment data for pin loading bolted jointed test except range of $L/d{\leqq}3$.
Journal of the Korea institute for structural maintenance and inspection
/
v.17
no.5
/
pp.94-104
/
2013
Experiments were divided into two parts; one part is to understand the basic properties of high flowable VA/VeoVa-modified cement mortar with different polymer cement ratio (P/C) and the weight ratio of fine aggregate to cement (C:F) and the other part is to investigate the effect of surface water spread on the concrete substrate on adhesion in tension. To understand the basic performance, the specimens were prepared with proportionally mixing VA/VeoVa redispersible powder, ordinary portland cement, silica sand, superplasticizer and viscosity enhancing agent. Here, P/C were 10, 20, 30, 50 and 75% and C:F were 1:1 and 1:3. As the change of P/C and C:F unit weight, flow test, crack resistance and adhesion in tension were measured. Three specimens with good adhesion properties were selected among specimens with different P/C and C:F. The effect of surface water evenly sprayed on concrete substrate on adhesive strength is investigated. The results show that surface water on concrete substrate increases the adhesion in tension of high flowable VA/VeoVa-modified cement mortar and additionally improves the flowability compared to the non-sprayed case.
Journal of the Korea institute for structural maintenance and inspection
/
v.24
no.3
/
pp.39-46
/
2020
Carbonation is a deterioration which degrades structural and material performance by permitting CO2 and corrosion of embedded steel. Service life evaluation through deterministic method is conventional, however the researches with probabilistic approach on service life considering loading and cold joint effect on carbonation have been performed very limitedly. In this study, probabilistic service life evaluation was carried out through MCS (Monte Carlo Simulation) which adopted random variables such as cover depth, CO2 diffusion coefficient, exterior CO2 concentration, and internal carbonatable materials. Probabilistic service life was derived by changing mean value and COV (Coefficient of variation) from 100 % to 300 % and 0.1 ~ 0.2, respectively. From the analysis, maximum reduction ratio (47.7%) and minimum reduction ratio (11.4%) of service life were obtained in cover depth and diffusion coefficient, respectively. In the loading conditions of 30~60% for compressive and tensile stress, GGBFS concrete was effective to reduce cold joint effect on carbonation. In the tensile condition, service life decreased linearly regardless of material types. Additionally service life rapidly decreased due to micro crack propagation in the all cases when 60% loading was considered in compressive condition.
Han, Sun-Jin;Lee, Jungmin;Kim, Min-Seok;Kim, Jae-Hyun;Kim, Kang Su;Oh, Young-Hun
Journal of the Korea institute for structural maintenance and inspection
/
v.25
no.3
/
pp.77-84
/
2021
In this study, flexural tests of prestressed high strength spun concrete (PHC) piles reinforced with infilled concrete and longitudinal rebars were conducted, where the longitudinal rebar ratio and the presence of sludge formed on the inner surface of PHC pile were set as key test variables. A total of six PHC pile specimens were manufactured, and their flexural behaviors including failure mode, crack pattern, longitudinal strain distribution in a section and end slip between external PHC pile and infilled concrete were measured and discussed in detail. The test results revealed that the flexural stiffness and strength increased as the longitudinal rebar ratio became larger, and that the sludge formed on the inner surface of PHC pile did not show any detrimental effect on the flexural performance. In addition to the experimental approach, this study presents a nonlinear flexural analysis model considering compatibility conditions and strain and stress distributions of the PHC piles and infilled concrete. The rationality of the nonlinear flexural analysis model was verified by comparing it with test results, and it appeared that the proposed model well evaluated the flexural behavior of PHC piles reinforced with infilled concrete and longitudinal rebars with a good accuracy.
Ground fissures have a huge effect on the integrity of surface structures. In high-intensity ground fissure regions, however, land resource would be wasted and city building and economic development would be limited if the area avoiding principle was used. In view of this challenge, to reveal the seismic response and seismic failure characteristics of ground fissure sites, a shaking table test on model soil based on a 1:15 scale experiment was carried out. In the test, the spatial distribution characteristics of acceleration response and Arias intensity were obtained for a site exposed to earthquakes with different characteristics. Furthermore, the failure characteristics and damage evolution of the model soil were analyzed. The test results indicated that, with the increase in the earthquake acceleration magnitude, the crack width of the ground fissure enlarged from 0 to 5 mm. The soil of the hanging wall was characterized by earlier cracking and a higher abundance of secondary fissures at 45°. Under strong earthquakes, the model soil, especially the soil near the ground fissure, was severely damaged and exhibited reduced stiffness. As a result, its natural frequency also decreased from 11.41 Hz to 8.05 Hz, whereas the damping ratio increased from 4.8% to 9.1%. Due to the existence of ground fissure, the acceleration was amplified to nearly 0.476 m/s2, as high as 2.38 times of the input acceleration magnitude. The maximum of acceleration and Arias intensity appeared at the fissure zone, which decreased from the main fissure toward both sides, showing hanging wall effects. The seismic intensity, duration and frequency spectrum all had certain effects on the seismic response of the ground fissure site, but their influence degrees were different. The seismic response of the site induced by the seismic wave that had richer low-frequency components and longer duration was larger. The discrepancies of seismic response between the hanging wall and the footwall declined obviously when the magnitude of the earthquake acceleration increased. The research results will be propitious to enhancing the utilizing ratio of the limited landing resource, alleviation of property damages and casualties, and provide a good engineering application foreground.
Journal of the Korea institute for structural maintenance and inspection
/
v.25
no.3
/
pp.31-39
/
2021
In this study, the fiber blending ratio and strain rate effect on the tensile properties synergy effect of hybrid fiber reinforced cement composite was evaluated. Hooked steel fiber(HSF) and smooth steel fiber(SSF) were used for reinforcing fiber. The fiber blending ratio of HSF+SSF were 1.5+0.5, 1.0+1.0 and 0.5+1.5vol.%. As a results, in the cement composite(HSF2.0) reinforced with HSF, as the strain rate increases, the tensile stress sharply decreased after the peak stress because of the decrease in the number of straightened pull-out fibers by increase of micro cracks in the matrix around HSF. When 0.5 vol.% of SSF was mixed, the micro cracks was effectively controlled at the static rate, but it was not effective in controlling micro cracks and improving the pull-out resistance of HSF at the high rate. On the other hand, the specimen(HSF1.0SSF1.0) in which 1.0vol.% HSF and 1.0vol.% SSF were mixed, each fibers controls against micro and macro cracks, and SSF improves the pull-out resistance of HSF effectively. Thus, the fiber blending effect of the strain capacity and energy absorption capacity was significantly increased at the high rate, and it showed the highest dynamic increase factor of the tensile strength, strain capacity and peak toughness. On the other hand, the incorporation of 1.5 vol.% SSF increases the number of fibers in the matrix and improves the pull-out resistance of HSF, resulting in the highest fiber blending effect of tensile strength and softening toughness. But as a low volume fraction of HSF which controlling macro crack, it was not effective for synergy of strain capacity and peak toughness.
본 웹사이트에 게시된 이메일 주소가 전자우편 수집 프로그램이나
그 밖의 기술적 장치를 이용하여 무단으로 수집되는 것을 거부하며,
이를 위반시 정보통신망법에 의해 형사 처벌됨을 유념하시기 바랍니다.
[게시일 2004년 10월 1일]
이용약관
제 1 장 총칙
제 1 조 (목적)
이 이용약관은 KoreaScience 홈페이지(이하 “당 사이트”)에서 제공하는 인터넷 서비스(이하 '서비스')의 가입조건 및 이용에 관한 제반 사항과 기타 필요한 사항을 구체적으로 규정함을 목적으로 합니다.
제 2 조 (용어의 정의)
① "이용자"라 함은 당 사이트에 접속하여 이 약관에 따라 당 사이트가 제공하는 서비스를 받는 회원 및 비회원을
말합니다.
② "회원"이라 함은 서비스를 이용하기 위하여 당 사이트에 개인정보를 제공하여 아이디(ID)와 비밀번호를 부여
받은 자를 말합니다.
③ "회원 아이디(ID)"라 함은 회원의 식별 및 서비스 이용을 위하여 자신이 선정한 문자 및 숫자의 조합을
말합니다.
④ "비밀번호(패스워드)"라 함은 회원이 자신의 비밀보호를 위하여 선정한 문자 및 숫자의 조합을 말합니다.
제 3 조 (이용약관의 효력 및 변경)
① 이 약관은 당 사이트에 게시하거나 기타의 방법으로 회원에게 공지함으로써 효력이 발생합니다.
② 당 사이트는 이 약관을 개정할 경우에 적용일자 및 개정사유를 명시하여 현행 약관과 함께 당 사이트의
초기화면에 그 적용일자 7일 이전부터 적용일자 전일까지 공지합니다. 다만, 회원에게 불리하게 약관내용을
변경하는 경우에는 최소한 30일 이상의 사전 유예기간을 두고 공지합니다. 이 경우 당 사이트는 개정 전
내용과 개정 후 내용을 명확하게 비교하여 이용자가 알기 쉽도록 표시합니다.
제 4 조(약관 외 준칙)
① 이 약관은 당 사이트가 제공하는 서비스에 관한 이용안내와 함께 적용됩니다.
② 이 약관에 명시되지 아니한 사항은 관계법령의 규정이 적용됩니다.
제 2 장 이용계약의 체결
제 5 조 (이용계약의 성립 등)
① 이용계약은 이용고객이 당 사이트가 정한 약관에 「동의합니다」를 선택하고, 당 사이트가 정한
온라인신청양식을 작성하여 서비스 이용을 신청한 후, 당 사이트가 이를 승낙함으로써 성립합니다.
② 제1항의 승낙은 당 사이트가 제공하는 과학기술정보검색, 맞춤정보, 서지정보 등 다른 서비스의 이용승낙을
포함합니다.
제 6 조 (회원가입)
서비스를 이용하고자 하는 고객은 당 사이트에서 정한 회원가입양식에 개인정보를 기재하여 가입을 하여야 합니다.
제 7 조 (개인정보의 보호 및 사용)
당 사이트는 관계법령이 정하는 바에 따라 회원 등록정보를 포함한 회원의 개인정보를 보호하기 위해 노력합니다. 회원 개인정보의 보호 및 사용에 대해서는 관련법령 및 당 사이트의 개인정보 보호정책이 적용됩니다.
제 8 조 (이용 신청의 승낙과 제한)
① 당 사이트는 제6조의 규정에 의한 이용신청고객에 대하여 서비스 이용을 승낙합니다.
② 당 사이트는 아래사항에 해당하는 경우에 대해서 승낙하지 아니 합니다.
- 이용계약 신청서의 내용을 허위로 기재한 경우
- 기타 규정한 제반사항을 위반하며 신청하는 경우
제 9 조 (회원 ID 부여 및 변경 등)
① 당 사이트는 이용고객에 대하여 약관에 정하는 바에 따라 자신이 선정한 회원 ID를 부여합니다.
② 회원 ID는 원칙적으로 변경이 불가하며 부득이한 사유로 인하여 변경 하고자 하는 경우에는 해당 ID를
해지하고 재가입해야 합니다.
③ 기타 회원 개인정보 관리 및 변경 등에 관한 사항은 서비스별 안내에 정하는 바에 의합니다.
제 3 장 계약 당사자의 의무
제 10 조 (KISTI의 의무)
① 당 사이트는 이용고객이 희망한 서비스 제공 개시일에 특별한 사정이 없는 한 서비스를 이용할 수 있도록
하여야 합니다.
② 당 사이트는 개인정보 보호를 위해 보안시스템을 구축하며 개인정보 보호정책을 공시하고 준수합니다.
③ 당 사이트는 회원으로부터 제기되는 의견이나 불만이 정당하다고 객관적으로 인정될 경우에는 적절한 절차를
거쳐 즉시 처리하여야 합니다. 다만, 즉시 처리가 곤란한 경우는 회원에게 그 사유와 처리일정을 통보하여야
합니다.
제 11 조 (회원의 의무)
① 이용자는 회원가입 신청 또는 회원정보 변경 시 실명으로 모든 사항을 사실에 근거하여 작성하여야 하며,
허위 또는 타인의 정보를 등록할 경우 일체의 권리를 주장할 수 없습니다.
② 당 사이트가 관계법령 및 개인정보 보호정책에 의거하여 그 책임을 지는 경우를 제외하고 회원에게 부여된
ID의 비밀번호 관리소홀, 부정사용에 의하여 발생하는 모든 결과에 대한 책임은 회원에게 있습니다.
③ 회원은 당 사이트 및 제 3자의 지적 재산권을 침해해서는 안 됩니다.
제 4 장 서비스의 이용
제 12 조 (서비스 이용 시간)
① 서비스 이용은 당 사이트의 업무상 또는 기술상 특별한 지장이 없는 한 연중무휴, 1일 24시간 운영을
원칙으로 합니다. 단, 당 사이트는 시스템 정기점검, 증설 및 교체를 위해 당 사이트가 정한 날이나 시간에
서비스를 일시 중단할 수 있으며, 예정되어 있는 작업으로 인한 서비스 일시중단은 당 사이트 홈페이지를
통해 사전에 공지합니다.
② 당 사이트는 서비스를 특정범위로 분할하여 각 범위별로 이용가능시간을 별도로 지정할 수 있습니다. 다만
이 경우 그 내용을 공지합니다.
제 13 조 (홈페이지 저작권)
① NDSL에서 제공하는 모든 저작물의 저작권은 원저작자에게 있으며, KISTI는 복제/배포/전송권을 확보하고
있습니다.
② NDSL에서 제공하는 콘텐츠를 상업적 및 기타 영리목적으로 복제/배포/전송할 경우 사전에 KISTI의 허락을
받아야 합니다.
③ NDSL에서 제공하는 콘텐츠를 보도, 비평, 교육, 연구 등을 위하여 정당한 범위 안에서 공정한 관행에
합치되게 인용할 수 있습니다.
④ NDSL에서 제공하는 콘텐츠를 무단 복제, 전송, 배포 기타 저작권법에 위반되는 방법으로 이용할 경우
저작권법 제136조에 따라 5년 이하의 징역 또는 5천만 원 이하의 벌금에 처해질 수 있습니다.
제 14 조 (유료서비스)
① 당 사이트 및 협력기관이 정한 유료서비스(원문복사 등)는 별도로 정해진 바에 따르며, 변경사항은 시행 전에
당 사이트 홈페이지를 통하여 회원에게 공지합니다.
② 유료서비스를 이용하려는 회원은 정해진 요금체계에 따라 요금을 납부해야 합니다.
제 5 장 계약 해지 및 이용 제한
제 15 조 (계약 해지)
회원이 이용계약을 해지하고자 하는 때에는 [가입해지] 메뉴를 이용해 직접 해지해야 합니다.
제 16 조 (서비스 이용제한)
① 당 사이트는 회원이 서비스 이용내용에 있어서 본 약관 제 11조 내용을 위반하거나, 다음 각 호에 해당하는
경우 서비스 이용을 제한할 수 있습니다.
- 2년 이상 서비스를 이용한 적이 없는 경우
- 기타 정상적인 서비스 운영에 방해가 될 경우
② 상기 이용제한 규정에 따라 서비스를 이용하는 회원에게 서비스 이용에 대하여 별도 공지 없이 서비스 이용의
일시정지, 이용계약 해지 할 수 있습니다.
제 17 조 (전자우편주소 수집 금지)
회원은 전자우편주소 추출기 등을 이용하여 전자우편주소를 수집 또는 제3자에게 제공할 수 없습니다.
제 6 장 손해배상 및 기타사항
제 18 조 (손해배상)
당 사이트는 무료로 제공되는 서비스와 관련하여 회원에게 어떠한 손해가 발생하더라도 당 사이트가 고의 또는 과실로 인한 손해발생을 제외하고는 이에 대하여 책임을 부담하지 아니합니다.
제 19 조 (관할 법원)
서비스 이용으로 발생한 분쟁에 대해 소송이 제기되는 경우 민사 소송법상의 관할 법원에 제기합니다.
[부 칙]
1. (시행일) 이 약관은 2016년 9월 5일부터 적용되며, 종전 약관은 본 약관으로 대체되며, 개정된 약관의 적용일 이전 가입자도 개정된 약관의 적용을 받습니다.