• 한국세라믹학회지
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• 제36권4호
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• pp.432-443
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• 1999

The self-toughened Si3N4 ceramics where needle-like coarse ${\beta}$-Si3N4 grains were dispersed within fine-grain-ed matrix were prepared via hot-prssing at 1730$^{\circ}C$ for 2 h using 5 vol% ${\beta}$-Si3N4 whiskers as a seed. In this study the microstructures and mechanical properties of self-toughened Si3N4 ceramics were investigated. The flexural strength of self-toughened Si3N4 ceramics was increased from 600-800 MPa of the Si3N4 monolith to 830-1025 MPa. The KIC was also increased from 4.0-5.0MPa$.$m1/2 of the Si3N4 monolith to 5.8-6.5MPa$.$m1/2$.$The needle-like coarse Si3N4 grains in self-toughened ceramics were considered to induce various toughening mechanisms including the crack deflection pull-out and bridging and to contribute to KIC improvement. In ad-dition to toughening mechanisms the KIC improvement was considered to be partially indebted also to the orien-tation of large ${\beta}$-Si3N4 grains and to the promoting effect of ${\beta}$-Si3N4 whiskers on the ${\alpha}$ to ${\beta}$ transtion.

• Structural Engineering and Mechanics
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• 제71권3호
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• pp.211-221
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• 2019

To study the eccentric compression behavior of ultra-high performance fiber reinforced concrete (UHPFRC) columns, six UHPFRC columns and one high-strength concrete (HSC) column were tested. Variation parameters include load eccentricity, volume of steel fibers and stirrup ratio. The crack pattern, failure mode, bearing capacity, and deformation of the specimens were studied. The results showed that the UHPFRC columns had different failure modes. The large eccentric compression failure mode was the longitudinal tensile reinforcements yielded and many horizontal cracks appeared in the tension zone. The small eccentric compression failure mode was the longitudinal compressive reinforcements yielded and vertical cracks appeared in the compressive zone. Because of the bridging effect of steel fibers, the number of cracks significantly increased, and the width of cracks decreased. The load-deflection curves of the UHPFRC columns showed gradually descending without sudden dropping, indicating that the specimens had better deformation. The finite element (FE) analysis was performed to stimulate the damage process of the specimens with monotonic loading. The concrete damaged plasticity (CDP) model was adopted to characterize the behaviour of UHPFRC. The contribution of the UHPFRC tensile strength was considered in the bearing capacity, and the theoretical calculation formulas were derived. The theoretical calculation results were consistent with the test results. This research can provide the experimental and theoretical basis for UHPFRC columns in engineering applications.

• 대한치과보철학회지
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• 제38권5호
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• pp.595-605
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• 2000

Dental ceramics have good aesthetics, biocompatibility, low thermal conductivity, abrasion resistance, and color stability. However poor resistance to fracture and shrinkage during firing process have been limiting factors in their use, particularly in multiunit ceramic restorations. A new method for making all-ceramic crowns that have high strength and low processing shrinkage has been developed and is referred to as the Vita In-Ceram method. This study was performed to investigate the effect of $CeO_2$ addition in borosilicate glasses on the strength of alumina-glass composites. Porous alumina compacts were prepared by slip casting and sintered at $1,100^{\circ}C$ for 2 hours. Dense composites were made by infiltration of molten glass into partially sintered alumina at $1,140^{\circ}C$ for 4 hours. Specimens were polished sequentially from #800 to #2000 diamond disk. and the final surface finishing on the tensile side was received an additional polishing sequence through $1{\mu}m$ diamond paste. Biaxial flexure test was conducted by using ball-on-three-ball method at a crosshead speed of 0.5mm/min. To examine the microstructural aspect of crack propagation in the alumina-glass composites, Vickers-produced indentation crack was made on the tensile surface at a load of 98.0 N and dwell time of 15 sec, and the radial crack patterns were examined by an optical microscope and a scanning electron microscope. The results obtained were summarized as follows; 1. The porosity rates of partially sintered alumina decreased with the rising of firing temperature. 2. The maximum biaxial flexure strength of 423.5MPa in alumina-glass composites was obtained with an addition of 3 mol% $CeO_2$ in glass composition and strength values showed the aspect of decrease with the increase of $CeO_2$ content. 3 The biaxial flexure strength values of alumina-glass composites were decreased with rising the firing temperature. 4. Observation of the fracture surfaces of alumina-glass composites indicated that the enhancement of strength in alumina-glass composites was due to the frictional or geometrical inter-locking of rough fracture surfaces and ligamentary bridging by intact islands of materials left behind the fracture front.

• 한국세라믹학회지
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• 제31권5호
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• pp.513-519
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• 1994

In-situ 반응에 의하여 형성된 La-$\beta$-aluminate (LaAl11O18)로 강화된 알루미나 복합체에 정방정 ZrO2를 첨가하여 알루미나 복합체를 제조하였다. 사용된 분말 혼합체의 조성은 (100-x)[88 Al2O3+(La2O3+11 Al2O3)]+x vol% ZrO2였으며, x는 0부터 40까지 변화시켰다. 열간가압형성에 의하여 얻어진 치밀한 소결체는 1200MPa의 곡강도값을 나타내었다. 이러한 높은 곡강도값은 첨가한 ZrO2 입자와 기존의 La-$\beta$-aluminate platelets의 기지 입자에 대한 입성장 억제 효과와 ZrO2의 응력유기 상변태 효과로부터 기인하였다. 상기 복합체의 파괴 인성도 역시 8.58.5 MPa.m1/2까지 증가하였는데, 이러한 파괴인성의 증가는 ZrO2의 상변태 강화와 미세균열 강화, 그리고 La-$\beta$-aluminate와 ZrO2 입자의 균열 deflection과 bridging의 효과로 설명되어질 수 있다.

• 콘크리트학회논문집
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• 제22권6호
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• pp.777-786
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• 2010

이 연구에서는 강섬유로 보강된 초고성능 콘크리트(UHPC)를 적용한 대형 크기의 프리스트레스트 콘크리트 거더의 정적하중재하실험을 통하여 휨거동 특성을 파악하고자 하였다. 이 연구결과는 추후 UHPC를 적용한 프리스트레스트 콘크리트 거더의 처짐산정 및 휨강도 산정 모델링에 주요한 기초적인 실험결과를 제공한다. 휨 하중하에서의 프리스트레스트 콘크리트 T-거더의 거동을 파악하기 위하여 강섬유를 혼입하였다. 강섬유는 원형단면의 직선형상이며, 콘크리트에서 2%의 부피비를 나타낸다. 거더는 압축강도 150~190 MPa의 UHPC를 이용하여 제작하였으며, 프리스트레스트 거더의 휨내력을 파악하고자 하였다. 실험결과는 강섬유 보강 UHPC가 거더의 균열제어 및 연성거동에 효과적임을 나타낸다. 강섬유 보강 UHPC를 적용한 프리스트레스트 거더의 파괴는 인장균열에서의 가교 역할(bridging effect)을 하는 강섬유의 뽐힘(pullout)과 더불어 발생한다. 강섬유의 뽑힘과 더불어 단면의 인장강도 손실이 발생하며, 이는 거더의 휨파괴를 유발한다. 또한, 도입 프리스트레스량이 거더의 휨강도에 영향을 미치는 것으로 나타난다.

• Computers and Concrete
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• 제21권6호
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• pp.623-635
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• 2018

In order to research the influence of different recycled aggregate contents on the mechanical properties of pervious concrete, the experimental study and numerical simulation analysis of the mechanical properties of pervious concrete with five kinds of recycled aggregates contents (0%, 25%, 50%, 75% and 100%) are carried out in this paper. The experimental test were first performed on concrete specimens of different sizes in order to determine the influence of recycled aggregate on the compressive strength and splitting tensile strength, direct tension strength and bending strength. Then, the development of the internal cracks of pervious concrete under different working conditions is studied more intuitively by $PFC^{3D}$. The experimental results show that the concrete compressive strength, tensile strength and bending strength decrease with the increase of the recycled aggregate contents. This trend of reduction is not only related to the brittleness of recycled aggregate concrete, but also to the weak viscosity of recycled aggregate and cement paste. It is found that the fracture surface of pervious concrete with recycled aggregate is smoother than that of natural aggregate pervious concrete by $PFC^{3D}$, which means that the bridging effect is weakened in the stress transfer between the left and right sides of the crack. Through the analysis of the development of the internal cracks, the recycled aggregate concrete generated more cracks than the natural aggregate concrete, which means that the recycled aggregate concrete is easier to form a coalescence fracture surface and eventually break.

• Advances in concrete construction
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• 제13권4호
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• pp.315-325
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• 2022

Reinforced concrete structures are exposed throughout their lifetime to the phenomenon of carbonation, which considerably influences their durability by causing corrosion of the reinforcements. The fight against this phenomenon is usually ensured by anti-carbonation coatings which have the possibility of limiting the permeability to carbon dioxide or with coatings which absorb the CO₂ present in the air. A coating with good crack-bridging (sealing) capacity will prevent water from entering through existing cracks in concrete. Despite the beneficial effect of these coatings, their durability decreases considerably over time with temperature and humidity. In order to use coatings made from local materials, not presenting any danger, available in abundance in our country, very economical and easy to operate is the main objective of this work. This paper aim is to contribute to the formulation of a corrected dune sand-based mortar as an anti-carbonation coating for concrete. The results obtained show that the cement mortar based on dune sand formulated has a very satisfactory compressive strength, a very low water porosity compared to ordinary cement mortar and that this mortar allows an improvement in the protection of the concrete against the carbonation of 60% compared to ordinary cement mortar based on alluvial sand. Moreover, the formulated cement mortars based on dune sand have good adhesion to the concrete support, their adhesion strengths are greater than 1.5MPa recommended by the standards.

• 콘크리트학회논문집
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• 제24권1호
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• pp.3-14
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• 2012

이 논문에서는 비내진상세 골조의 손상완화능력 향상을 위한 연구의 일환으로 변형경화형 시멘트 복합체 끼움벽의 내진성능을 실험적으로 평가하였다. SHCC의 인장변형능력 및 균열거동 특성이 끼움벽의 전단 거동에 미치는 영향을 구명하기위해 총 3개의 끼움벽 실험체를 제작하여 반복하중 하에서 실험을 실시하였다. 이 연구에서 사용된 시멘트 복합체의 종류는 콘크리트와 SHCC로 하였다. SHCC는 인장 특성에 따른 영향을 검토하기위해 PVA1.3%+PE0.2% 및 PVA0.75%+PE0.75%로 두 종류의 배합조건을 갖도록 계획하였다. 끼움벽의 균열손상 발생 부위를 중앙부로 유도하기위해 모든 끼움벽 실험체의 좌 우측면에 100 mm 깊이의 노치를 설치하였다. 실험 결과, SHCC 끼움벽의 경우 철근 콘크리트 끼움벽에 비해 우수한 균열제어성능을 나타냈으며, 최대하중 도달 시점에서의 층간변위 또한 높게 나타났다. 특히, 초기 경사균열 발생 이후에도 SHCC 내의 보강 섬유간 섬유가교작용에 기인하여 완만한 강성 저하 양상을 나타냈다. 게다가 끼움벽의 균열폭을 기준으로 손상 식별 단계를 분석한 결과, PIW-SHD 실험체가 PIW-SLD 실험체에 비해 약 3배에 해당하는 우수한 내진성능을 나타냈다. 또한 대각 보강근의 변형률 진전 양상을 비교한 결과, 우수한 균열분산 특성에 기인하여 철근에 집중되는 인장응력을 SHCC 매트릭스가 일정 부분 부담하는 것으로 나타났다.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제55권11호
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• pp.505-513
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• 2006

The present study investigated the influence of the content of $Al_2O_3+Y_2O_3$ sintering additives on the microstructure, mechanical and electrical properties of the pressureless-sintered $SiC-ZrB_2$ electroconductive ceramic composites. Phase analysis of composites by XRD revealed mostly of ${\alpha}-SiC(4H),\;ZrB_2,\;{\beta}-SiC(15R)$ and In Situ $YAG(Al_5Y_3O_{12})$. The relative density and the flexural strength showed the highest value of 86.8[%] and 203[Mpa] for $SiC-ZrB_2$ composite with an addition of 8[wt%] $Al_2O_3+Y_2O_3$ as a sintering aid at room temperature respectively. Owing to crack deflection and crack bridging of fracture toughness mechanism, the fracture toughness showed 3.7 and $3.6[MPa{\cdot}m^{1/2}]\;for\;SiC-ZrB_2$ composites with an addition of 8 and 12[wt%] $Al_2O_3+Y_2O_3$ as a sintering aid at room temperature respectively. Abnormal grain growth takes place during phase transformation from ${\beta}-SiC\;into\;{\alpha}-SiC$ was correlated with In Situ YAG phase by reaction between $Al_2O_3\;and\;Y_2O_3$ additives during sintering. The electrical resistivity showed the lowest value of $6.5{\times}10^{-3}[({\Omega}{\cdot}cm]$ for the $SiC-ZrB_2$ composite with an addition of 8[wt%] $Al_2O_3+Y_2O_3$ as a sintering aid at room temperature. The electrical resistivity of the $SiC-ZrB_2$ composites was all positive temperature coefficient(PTCR) in the temperature ranges from $25[^{\circ}C]\;to\;700[^{\circ}C]$. The resistance temperature coefficient showed the highest value of $3.53{\times}10^{-3}/[^{\circ}C]\;for\;SiC-ZrB_2$ composite with an addition of 8[wt%] $Al_2O_3+Y_2O_3$ as a sintering aid in the temperature ranges from $25[^{\circ}C]\;to\;700[^{\circ}C]$. In this paper, it is convinced that ${\beta}-SiC$ based electroconductive ceramic composites for heaters or ignitors can be manufactured by pressureless sintering.

• 콘크리트학회논문집
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• 제25권4호
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• pp.419-428
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• 2013

이 연구에서는 고강도 철근콘크리트 외부 보-기둥 접합부의 시공성 및 내진성능을 개선하기 위하여 보-기둥 접합부 영역의 스터럽 및 띠철근 유무에 따라 고인성섬유 복합모르타르를 사용하여 내진성능을 평가하였다. 총 5개의 실험체를 제작하고 실험을 수행하여 내진성능을 평가하였으며, 이 연구의 시험 결과를 근거로 다음과 같은 결론을 얻었다. 기존 고강도 철근콘크리트 내부 보-기둥 접합부의 위험단면 영역을 고인성섬유 복합모르타르로 보강한 결과 재하 전 과정을 통하여 섬유의 가교역할로 인한 균열 분산효과로 인하여 균열 제어 효과가 커서 안정적인 파괴형태 및 내력을 나타내었다. 고강도 철근콘크리트 외부 보-기둥 접합부의 시공성 및 내진성능을 개선하기 위하여 고인성섬유 복합모르타르를 사용하여 보강한 실험체(BCJNSP 시리즈)는 스터럽과 띠철근이 제거 되었음에도 안정적인 이력거동을 나타내었고, 최대내력이 전단보강근이 없는 실험체 BCJNS의 1.09~2.03배로 증가하였다. 그리고 고인성섬유 복합모르타르를 사용하여 보강한 실험체(BCJNSP 시리즈)는 표준실험체 BCJC의 최대내력이 0.92~0.96배로 거의 비슷하였고, 에너지소산능력은 최대 1.62배로 크게 증가하였다.