• Title/Summary/Keyword: Cr addition

Search Result 942, Processing Time 0.025 seconds

Sensitizing Effect of $Cr^{3+}$ in Nd : Laser Glass of Silicate System (Silicate계 Nd : Laser Glass에서 $Cr^{3+}$이온의 Sensitizer 효과)

  • 유영문;김병호;왕영성
    • Journal of the Korean Ceramic Society
    • /
    • v.30 no.5
    • /
    • pp.339-346
    • /
    • 1993
  • Inproving laser efficiency, optimum content of Nd3+ which is active ion and effect of Cr3+ as a sensitizer are investigated in 60SiO2.30Li2O.10CaO host glass. The glasses are fabricated with the addition of Nd3+, Cr3+ and then optical properties such as absorption spectrum, fluorescence spectrum and fluorescence lifetime were studied. Finally, lasing efficiency was measured. From this study, optimum content of Nd2O3 appeared to be 3.5wt% and it was observed that the energy absorbed by optical exicitation of the Cr3+ is transfered to the Nd3+. Addition of Cr2O3 tend to improve characteristic of laser oscillation for the laser glass.

  • PDF

Effects of Spinel on the Formation Process of Nonohmic ZnO Ceramics (비오옴 ZnO 세라믹스의 형성과정에서 스피넬의 영향)

  • 김경남;한상목
    • Journal of the Korean Ceramic Society
    • /
    • v.29 no.2
    • /
    • pp.101-106
    • /
    • 1992
  • Sintering behavior, distribution of dopant oxides and electrical properties in the ZnO-Bi2O3-CoO-Sb2O3 and ZnO-Bi2O3-CoO-Sb2O3-Cr2O3 systems were studied. The linear shrinkage of ZnO varistors from 850 to 950$^{\circ}C$ was related to the decomposition reaction (py\longrightarrowsp+Bi2O3) of the pyrochlore phase. In the distribution of the dopant oxides (CoO, Sb2O3, Cr2O3), Co distribute uniformly throughout the sample, the distribution of Sb coincided with small particles (spinel phase, Zn7Sb2O12), and Cr distributed very consistently with Sb. The increase in breakdown voltage, due to the addition of Cr2O3, was not only attributed to the decrease in the ZnO grain size but also to the solution of Cr2O3 in the spinel phase. The leakage current (80% V60 ${\mu}\textrm{A}$) was increased by the addition of Cr2O3.

  • PDF

Dielectric and Piezoelectric Characteristics of PSS-PZT Piezoelectric Ceramics with CrS12TOS13t Addition (Cr2O3 첨가에 따른 PSS-PZT 압전 세라믹스의 유전 및 압전 특성)

  • 홍재일;이개명;윤석진;유주현;박창엽
    • The Transactions of the Korean Institute of Electrical Engineers
    • /
    • v.41 no.6
    • /
    • pp.687-693
    • /
    • 1992
  • To improve dielectric, piezoelectric and temperature stability in 0.50Pb(SnS11/2TSbS11/2T)OS13T - 0.35PbTiOS13T - 0.60PbZrOS13T + 0.4[wt%]MnOS12T piezoelectric ceramics which is used for surface acoustic wave devices, CrS12TOS13T was added and the specimens were fabricated by Hot Press method, and their characteristics were measured with CrS12TOS13T addition. From the results, in the specimen added by 0.2[wt%]CrS12TOS13T, dielectric constant and mechanical quality factor were 380 and 2307, respectively, and it was suited for surface acoustic wave device and the temperature coefficient of the resonant frequency in the specimen added by 0.4[wt%]CrS12TOS13T was the least value of 74.96[ppm/$^{\circ}C$].

The Effects of Mn and Cr Additions on the Microstructure of A356 Alloys Containing Impure Fe (불순 Fe를 함유한 A356 주조합금에서 미세조직 형성에 관한 Mn과 Cr의 효과)

  • Han, Sang-Won
    • Journal of Korea Foundry Society
    • /
    • v.25 no.3
    • /
    • pp.128-133
    • /
    • 2005
  • The effects of Mn and Cr on the crystallization behaviors of Fe-bearing intennetallics in A356 alloy were studied. Coarse and acicular ${\beta}-Al_{5}$FeSi phase in A356-0.20wt.%Fe alloy was modified into small ${\alpha}$-Al(Fe,Mn)Si and ${\alpha}$-Al(Fe,Cr)Si phases in response to Mn and Cr addition, respectively. Increasing of Mn addition amount elevates the crystallizing temperature of ${\alpha}$-Al(Fe,Mn)Si and the Mn/Fe ratio in the ${\alpha}$-Al(Fe,Mn)Si. Cr is more effective to modify ${\beta}-Al_{5}$FeSi in comparison with Mn. ${\alpha}$-Al(Fe,Mn)Si phase had BCC/SC dual structure.

Hot Corrosion of Fe-Cr-Si and Fe-Cr-Pt alloys in Molten Salts. (Si, Pt이 첨가된 Fe-Cr 합금의 고온 용융염에서의 부식)

  • 박철우;최송천;이동복
    • Journal of the Korean institute of surface engineering
    • /
    • v.27 no.1
    • /
    • pp.3-11
    • /
    • 1994
  • Cyclic hot corrosion studies have been carried out on(82~94) wt. % Fe-(5, 10, 15) wt. % Cr alloys con-taining either (1, 3)wt. % of Si or Pt as minor alloying elements in molten salts of($Na_2SO_4$+NaCl) between 820 and $920^{\circ}C$. Si or Pt decreased corrosion rate with the most pronounced effect being observed for alloys having 15wt. %Cr. Especially, as Si or Pt contents are increased from 1 to 3 wt. %, improved corrosion resistance was obtained. The beneficial effect of Si addition is due to the presence of the Si-rich second phase along the grain boundaries as well as the formation of the protective $SiO_2$layer between substrates and oxide scale. The Pt addition also increased the corrosion resistance by enhancing the formation ($Cr_2O_3$+layers and by increasing the adherence of the oxide scale.

  • PDF

Electrical and Dielectric Characteristics of Zn-Pr-Co-Er-M(M=Ni, Mg, Cr) Oxides-Based Varistors (Zn-Pr-Co-Er-M(M=Ni, Mg, Cr)산화물계 바리스터의 전기적, 유전적 특성)

  • 남춘우;김명준
    • Journal of the Korean Ceramic Society
    • /
    • v.41 no.8
    • /
    • pp.605-609
    • /
    • 2004
  • The microstructure, electrical and dielectric characteristics of ZnO varistors were investigated at various metal oxide (NiO, MgO, and Cr$_2$O$_3$) additives. The average grain size was increased with addition of NiO while that was decreased with addition of Cr$_2$O$_3$-Thereby, the varistor voltage was higher in Cr$_2$O$_3$-added composition. Among varistors, the varistor added with Cr$_2$O$_3$ exhibited the highest nonlinearity, with 40.5 in the nonlinear exponent and 2.7 ${\mu}$A in the leakage current and its dielectric dissipation factor was relatively low value of 0.0589.

Effect of Pt on the High Temperature Stability of NiCoCrAlY or NiAl Bond Coat in the Thermal Barrier Coating System (NiCoCrAlY 및 NiAl bond coat를 사용한 Thermal Barrier Coating의 고온안정성에 미치는 Pt의 영향)

  • Ku Seongmo;Kim Gil Moo
    • Korean Journal of Materials Research
    • /
    • v.15 no.6
    • /
    • pp.375-381
    • /
    • 2005
  • High temperature oxidation behavior of thermal barrier coating (TBC) system (IN738 substrate + NiCoCrAlY or NiAl bond coat with or without Pt + yttria stabilized zirconia) prepared by air plasma spray (APS) process has been studied in order to understand the effect of Pt addition to bond coat on the stability of TBC system. Specimens were oxidized in thermal cycling and isothermal oxidation test at $1100^{\circ}C$. The Pt addition in TBC system with NiCoCrAlY bond coat showed a longer life time compared to that without addition of Pt. Pt addition to TBC system is believed to help the formation of more stable thermally grown oxide, $Al_2O_3$, at the TBC/bond coat interface, leading to a longer lifetime of TBC system.

Effects of Alloying Element and Tempering on the Mechanical Properties of Cr-Mo Plastic Mold Steels (Cr-Mo계 금형강의 기계적 성질에 미치는 합금원소 및 템퍼링의 영향)

  • Kim, Nam-Kyu;Kim, Byoung-Ok;Lee, Oh-Yeon
    • Journal of the Korean Society for Heat Treatment
    • /
    • v.25 no.4
    • /
    • pp.196-205
    • /
    • 2012
  • The purpose of this study is to enhance the hardenability and the mechanical properties by the addition of alloying elements such as Ni, Cr, Mo and B for the development of Cr-Mo plastic mold steel with uniform hardness and microstructure. The ingots were prepared by vacuum induction melting and forged to ${\Phi}35mm$ round bar. Forged bars were quenched and tempered at $200{\sim}600^{\circ}C$ for 1.5 hour. Jominy test, boron distribution observation, microstructual observation, tensile test and charpy impact test were conducted. It was confirmed that the hardenablity of these steels was improved by increasing of alloying elements and further promoted by the addition of boron. The critical rate of cooling required to obtain the bainitic structure for 0.27C-1.23Cr-0.28Mo-B steel was $0.5^{\circ}C/sec$. Hardness and strength of Cr-Mo steels decreased with increasing tempering temperature, but elongation and reduction of area increased with increasing tempering temperature. However, impact energy tempered at $400^{\circ}C$ showed the lowest value in the range $200{\sim}600^{\circ}C$ due to the temper embrittlement.

Microstructure of Ti-Cr-Si-N Coatings Deposited by a Hybrid System of Arc ion Plating and Sputtering Techniques (하이브리드 코팅시스템에 의해 제조된 Ti-Cr-Si-N 박막의 미세구조 및 기계적 특성연구)

  • Kang Dong Shik;Jeon Jin Woo;Song Pung Keun;Kim Kwang Ho
    • Journal of the Korean institute of surface engineering
    • /
    • v.38 no.3
    • /
    • pp.95-99
    • /
    • 2005
  • Quaternary Ti-Cr-Si-N coatings were synthesized onto steel substrates (SKD 11) using a hybrid method of arc ion plating (AIP) and sputtering techniques. For the Syntheses of Ti-Cr-Si-N coatings, the Ti-Cr-N coating process was performed substantially by a multi-cathodic AIP technique rising Cr and Ti targets, and Si was added by sputtering Si target during Ti-Cr-N deposition. In this work, comparative studies on microstructure and evaluation of mechanical properties between Ti-Cr-N and Ti-Cr-Si-N coatings were conducted. As the Si was incorporated into Ti-Cr-N coatings, the Ti-Cr-Si-N coatings showed largely increased hardness value of approximately 42 GPa than one of 28 GPa for Ti-Cr-N coatings. The average friction coefficient of Ti-Cr-N coatings largely decreased from 0.7 to 0.35 with increasing Si content up to 20 at. $\%$. In addition, wear behavior of Ti-Cr-N coatings against steel ball was much improved with Si addition due to the surface smoothening effect and tribe-chemical reaction.

Effect of Chromium Picolinate on Growth Performance, Carcass Characteristics, Serum Metabolites and Metabolism of Lipid in Pigs

  • Xi, Gang;Xu, Zirong;Wu, Si-hung;Chen, Shijiang
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.14 no.2
    • /
    • pp.258-262
    • /
    • 2001
  • The study was conducted to evaluate the effects of chromium picolinate (CrP) on growth, carcass characteristics and serum metabolites in growing-finishing pigs. A total of 96 Landrace$\times$Yorkshire$\times$Duroc hybrid pigs, initial live weight about $38.12{\pm}00kg$, were randomly assigned to 2 groups (16 pigs per pen, 3 pens per group), each group had 48 pigs with an equal number of barrows and gilts. The pigs were fed the diet with or without $200{\mu}g/kg$ Cr from CrP. The results indicated that the addition of $200{\mu}g/kg$ CrP increased ADG by 3.58% and decreased feed conversion rate (FCR) by 3.00% compared to the control group. Pigs fed CrP had 7.58% (p<0.05) higher carcass lean percentage, 15.55% (p<0.05) larger longissimus muscle area (LMA) and 10.90% (p<0.05) lower back fat thickness, 15.17% (p<0.05) lower carcass fat percentage. In addition, the IGF-I level in serum was elevated by 79.20% (p<0.05), the Insulin and cortisol level decreased by 27.35% (p<0.05) and 34.58% (p<0.05) respectively with supplementation of CrP. Analysis of subcutaneous fat (10th rib) showed that the activity of hormone sensitive lipase (HSL) increased by 79.58% (p<0.05) and the activities of isocitrate dehydrogenase (ISD) and malate dehydrogenase (MDH) decreased significantly by 15.06% (p<0.05) and 54.53% (p<0.05) respectively in the $200{\mu}g/kg$ CrP group. The concentration of RNA, RNA/DNA in LMA increased by 31.89% (p<0.05) and 5.41% (p<0.05) respectively with the addition of CrP. These results suggest that CrP reduced fat deposits by decreasing lipogenic enzyme activities and increasing HSL activity and may have promoted muscle anabolic metabolism through elevated IGF-I levels.