• 대한기계학회논문집B
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• 제32권8호
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• pp.604-611
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• 2008

Detailed analysis of NO formation routes and its contributions with strain rate in hydrogen/air flames were numerically investigated. LiG detailed reaction mechanism has been used for calculation, which is compared with experimental data in literature. It shows good agreement with experiment for both temperature and NO mole fraction. Three routes have been found important for NO formation in hydrogen flames. These are the Thermal route, NNH route and $N_2O$ route. Strain rate were varied to discuss the $EI_{NO}$ reduction trend in hydrogen nonpremixed flames, which are analyzed by each NO formation routes. As a result, as the strain rate increase, $EI_{NO}$ decrease sharply until strain rate $100s^{-1}$ and decrease slowly until strain rate $310s^{-1}$ again, after that $EI_{NO}$ keeps nearly constant. It can be identified that $EI_{NO}$ trend with the strain rate is well explained by a combination of variation of production rate of above Thermal, NNH and $N_2O$ route. Also result of Thermal-Mech. that includes only thermal NO reaction is compared with those of Full-Mech. As a result, It can be identified that there was difference between the two results of calculation. It is attributed to result that Thermal-mech did not consider contributions of NNH and $N_2O$ route. From these result, we can conclude that NOx emission characteristics of hydrogen nonpremixed flames should consider contributions of above three routes simultaneously.

• 한국화재소방학회논문지
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• 제22권3호
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• pp.221-227
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• 2008

본 연구에서는 FDS 코드를 이용하여 외부 자연풍에 의한 터널 내의 미세물분무 소화특성을 검토하였으며, 상세반응이 고려된 1차원 대향류 비예혼합화염을 이용하여 화염내부에서 미세물분무의 냉각 및 화학반응효과에 의한 소화현상을 규명하였다. 연구결과로서, 외부 자연풍의 유속 증가에 따라 고온 연기층의 분포 및 분무 특성의 큰 변화가 발생됨을 확인하였다. 외부 자연풍이 없는 경우에는 분무입자 직경이 작을수록 소화성능이 좋지만, 풍속이 증가함에 따라 입자직경이 클수록 소화성능이 좋아짐을 알 수 있었다. 자연풍은 입자의 화염면 침투를 방해할 뿐 아니라. 충분한 산소의 공급으로 화제 억제를 방해할 것으로 예측된다. 또한 자연풍이 존재하는 조건의 화염은 화염 신장효과에 의해 밀폐된 공간에서의 화염 보다 작은 양의 $H_2O$침투에 의해서도 소화될 수 있으며, $H_2O$의 화학반응에 의한 소화효과는 외부 자연풍의 유속에 크게 영향을 받지 않음을 확인하였다.

• 대한기계학회논문집B
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• 제20권2호
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• pp.710-719
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• 1996

Laser applied combustion diagnostic techniques-laser induced fluorescence (LIF) and coherent anti-Stokes Ramann spectroscopy (CARS)-are demonstrated. The profiles of hydroxyl radical (OH) and temperature in the counterflow burner are measured and compared with the numerical results. OH radical is excited on the Q$_1$(6) line of the $A^2$$\sum^+$$\leftarrow$$X^2{\prod}$(1, 0) band transition (281.1 nm) and LIF signal is measured at the the bands of (0, 0) and (1, 1) transition (306~326 nm). Absolute OH radical is obtained by using the laser absorption technique. The quenching effects are considered. Temperature is measured using broadband CARS system. Two dimensional OH radical profile is also obtained. The profiles of OH radical and temperature are found to agree well with those of numerical calculation.