• 제목/요약/키워드: Counter-transport

검색결과 77건 처리시간 0.025초

Numerical analysis of internal flow and mixing performance in polymer extruder II: twin screw element

  • Kim, Nak-Soo;Kim, Hong-Bum;Lee, Jae-Wook
    • Korea-Australia Rheology Journal
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    • 제18권3호
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    • pp.153-160
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    • 2006
  • We analyzed the non-Newtonian and non-isothermal flow with Carreau-Yasuda viscosity model in co-rotating and counter-rotating twin screw extruder systems. The mixing performances with respect to the screw speed, the screw pitch, and the rotating direction have been investigated. The dynamics of mixing was studied numerically by tracking the motions of particles. The extent of mixing was characterized in terms of the deformation rate, the residence time distribution, and the average strain. The results showed that the high screw speed decreases the residence time but increases the deformation rate. Small screw pitch increases the residence time. It is concluded that the high screw speed increases the dispersive mixing performance, while the small screw pitch increases the distributive mixing performance. Co-rotating screw extruder has the better conveying performance and the distributive mixing performance than counter-rotating screw extruder with the same screw speed and pitch. Co-rotating screw extruder developed faster transport velocity and it is advantageous the flow characteristics to the mixing that transfers polymer melt from one barrel to the other barrel.

암모니아-물 흡수식 시스템에서 유하액막식 발생기의 해석 (Analysis of Falling-film Generator in Ammonia-water Absorption System)

  • 김병주;손병후;구기갑
    • 설비공학논문집
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    • 제13권5호
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    • pp.422-430
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    • 2001
  • In the present study, an evaporative generation process of ammonia-water solution film on the vertical plate was analysed. For the utilization of waste heat, hot water of low temperature was used as the heat source. The continuity, momentum, energy and diffusion equations for the solution film and vapor mixture were formulated in integral forms and solved numerically. Counter-current solution-vapor flow resulted in the refrigerant vapor of the higher ammonia concentration than that of co-current flow. Eve the rectification of refrigerant vapor was observed near the inlet of solution film in counter-current flow. For the optimum operation of generator using hot water, numerical experiments, based on the heat exchange and generation efficiencies. revealed the inter-relationships among the Reynolds number of the solution film and hot water, and the length of generator. Enhancement of heat and mass transport in the solution film was found to be very effective for the improvement of generation performance, especially at high solution flow rate.

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Novel Interface-engineered Junction Technology for Digital Circuit Applications

  • Yoshida, J.;Katsuno, H.;Inoue, S.;Nagano, T.
    • Progress in Superconductivity
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    • 제3권1호
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    • pp.1-4
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    • 2001
  • Interface-engineered junctions with $YbBa_2$$Cu_3$$O_{7}$ as the counter electrode were demonstrated. The junctions exhibited excellent Josephson characteristics with a Josephson critical current ($I_{c}$) ranging from 0.1 mA to 8 mA and a magnetic field modulation of the $I_{c}$ exceeding 80% at 4.2 K while maintaining complete c-axis orientation of the counter-electrode layer. The$ 1\sigma$ spreads in $I_{c}$ for junctions with an average $I_{c}$ of 1-2 mA were 5-8% for 16 junctions within a chip, and 9.3% for a 100-junction array. Our dI/dV measurements suggest that a theoretical approach taking into account both a highly transparent barrier and the proximity effect is required to fully understand the Junction characteristics.ristics.

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염료감응 태양전지의 비백금 상대전극을 위한 니켈 나노입자-흑연질 탄소나노섬유 복합체 (Ni Nanoparticles-Graphitic Carbon Nanofiber Composites for Pt-Free Counter Electrode in Dye-Sensitized Solar Cells)

  • 오동현;구본율;이유진;안혜란;안효진
    • 한국재료학회지
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    • 제26권11호
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    • pp.649-655
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    • 2016
  • Ni nanoparticles (NPs)-graphitic carbon nanofiber (GCNF) composites were fabricated using an electrospinning method. The amounts of Ni precursor used as catalyst for the catalytic graphitization were controlled at 0, 2, 5, and 8 wt% to improve the photovoltaic performances of the nanoparticles and make them suitable for use as counter electrodes for dye-sensitized solar cells (DSSCs). As a result, Ni NPs-GCNF composites that were fabricated with 8 wt% Ni precursors showed a high circuit voltage (0.73 V), high photocurrent density ($14.26mA/cm^2$), and superb power-conversion efficiency (6.72%) when compared to those characteristics of other samples. These performance improvements can be attributed to the reduced charge transport resistance that results from the synergetic effect of the superior catalytic activity of Ni NPs and the efficient charge transfer due to the formation of GCNF with high electrical conductivity. Thus, Ni NPs-GCNF composites may be used as promising counter electrodes in DSSCs.

작업전극과 상대전극에 탄소나노튜브를 이용한 염료감응 태양전지의 특성연구 (The characteristics of dye-sensitized solar cells using carbon nanotube in working and counter electrodes)

  • 김보라;송수일;이학수;조남준
    • 분석과학
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    • 제27권6호
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    • pp.308-313
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    • 2014
  • 염료감응형 태양전지의 광전극 및 상대전극에 탄소나노튜브를 도입하여 전지의 광전기적 특성 변화를 EIS, J-V 특성곡선 및 UV-Vis 분광기를 이용하여 분석하였다. $TiO_2$ 광전극의 전기전도도 및 광전효율을 향상시키기 위해 전자전달 촉진자 역할을 하는 multi-wall carbon nanotube (MWCNT)를 $TiO_2$와 혼합하여 $TiO_2$-MWCNT 복합체를 sol-gel 연소 복합공정을 통해 제조하여 조사한 결과 0.1 wt% MWCNT를 첨가한 경우, $TiO_2$만을 사용한 경우에 비해 약 12.5%의 향상된 효율을 보였다. $TiO_2$-MWCNT 복합체에서 MWCNT가 $TiO_2$ 층의 전자이동을 향상시켜 저항을 감소하고 염료와 전자의 재결합을 감소시킨 결과로 생각된다. 그러나 0.1 wt%보다 많은 MWCNT를 첨가할 경우 광투과도 및 염료의 흡착량을 감소시켜 효율이 감소하였다. 또한 상대전극에 MWCNT와 MWCNT-Pt를 적용하였을 경우 각각의 효율은 1.2%와 4.1%로 MWCNT만 적용할 때 보다 백금이 담지된 MWCNT를 사용하였을 경우에 백금과 비슷한 효율을 보였다.

고에너지 엑스선을 조사한 부갑상선의 세포막모델에서 칼슘이온의 생리학적 대사에 미치는 영향 (Effect on Physiological Metabolism of Calcium Ion at Cell Membrane Model of Parathyroid which Irradiated by High Energy X-ray)

  • 고인호;여진동
    • 한국방사선학회논문지
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    • 제16권2호
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    • pp.141-150
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    • 2022
  • 이 실험에 사용한 부갑상선의 상피 세포막모델은 PS-DVB(polystyrene-diviny lbenzene)로서 술폰화 혼성 중합 막으로 제조한 이온투과성 고분자막이며 이 고분자막(세포막모델)을 이용하여 고에너지 엑스선(6MV X선)을 조사할 때 막의 수분흡수율 차이, 고정전달자(SO32-)의 농도 차이, 초기 pH 차이, OH-이온의 농도 차이가 세포의 내부·외부 사이에서 칼슘이온(Ca2+)의 농도 차이로 나타나게 되고 그 영향으로 부갑상선호르몬의 분비량과 생성량의 차이로 발생하게 되는데 이런 영향을 구명하기 위해서 상피세포의 세포막을 통한 칼슘이온(Ca2+)의 초기 병류성과 항류성 투과전달 특성에 관하여 연구를 하게 되였다. 36.5℃로 고정된 상피세포의 고분자 막(세포막모델)을 방사선을 조사할 때 막의 수분흡수율 차이로 인해서 고정전달자(SO32-)의 농도변화가 비 조사된 세포막모델보다 약 2.17배 정도 감소하였고 고정전달자(SO32-)의 농도 차이, 초기 pH 차이, OH-이온의 농도 차이에 따라서 혈중 칼슘이온(Ca2+)의 초기 병류성과 항류성 전달속도 변화가 비조사된 세포막모델보다 각각 약 2.68배 ~ 6.87배, 약 1.42배 ~ 1.63배, 약 2.07 ~ 1.67배 정도 감소하였다. 결국, 방사선 조사로 인해서 부갑상선의 상피 세포막에서 혈중 칼슘이온(Ca2+)의 초기 병류성과 항류성 전달속도변화가 비정상적으로 되어 상피세포의 장애가 발생하고 부갑상선호르몬의 분비량과 생성량 감소도 동반하게 되었다고 추론되었다.

Modeling of continuous diffusion dialysis of aqueous solutions of sulphuric acid and nickel sulphate

  • Bendova, Helena;Palaty, Zdenek
    • Membrane and Water Treatment
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    • 제2권4호
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    • pp.267-279
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    • 2011
  • At steady state, the simultaneous transport of sulphuric acid and nickel sulphate through an anion-exchange membrane Neosepta-AFN (Astom Corporation, Tokyo, Japan) was investigated in a two-compartment counter-current dialyzer with single passes. The transport was quantified by the recovery yield of acid, rejection of salt and four phenomenological coefficients, which were correlated with the acid and salt concentrations in the feed. The phenomenological coefficients were determined by the numerical integration of the basic differential equations describing the concentration profiles of the components in the dialyzer. This integration was combined with an optimizing procedure. The experiments proved that the acid recovery yield is in the limits from 63 to 91 %, while salt rejection is in the limits from 79 to 97 % in the dependence on the volumetric liquid flow rate and composition of the feed.

Poly(1-methyl-4-vinylpyridium iodide-co-styrene)막을 통한 유기음이온의 투과특성 (Transport Characteristics of Organic Anions through Poly (1-methyl-4vinylpyridium iodide-co-styrene) Membrane)

  • 이광재;한정우박돈희조영일
    • KSBB Journal
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    • 제6권2호
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    • pp.207-213
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    • 1991
  • In this study poly (1-methyl-4-vinylpyridinium iodide-co-styrene) membrane with pyridinium cation as a fixed carrier was synthesized and the transport characteristics of the membrane was examined over various factors. As the concentration of the fixed carrier in the membrane was increased, the water content was increased. Meanwhile, the counter current of the organic anion and the chloride ion, the following results were obtained. Initial flux of Cl-, organic anion and Na+ decreased with the increasing thickness of membrane, and as the concentration of the fixed carrier increases, the initial flux of Cl- and organic anion increase but the initial flux of Na+ decreased. The flux equation of the organic anion, CCl3COO- was obtained from saturation kinetics as follows;$V_{o}=\frac{(8.67{\times}10^{-5}){\cdot}[NaCl]}{9.63{\times}10^{-2}+[NaCl]} mol/cm^2h$

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국제해상컨테이너운송에서 보안강화를 위한 전자태그(IC tag)의 적용과 대응방안 (A study on the application and counter measures of IC tag in international marine container transport)

  • 한상현;최준호
    • 통상정보연구
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    • 제12권2호
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    • pp.133-158
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    • 2010
  • Since 11 September 2001, the awareness of terrorists' actions has clearly risen. The potential threat of terrorists using containers poses a large risk to our economies and to our societies. In order to protect cargo from damage and terrorist threats, business and government turn to RFID and IC tags, and tradition container is replaced by IC smart container. In this study, presented application of IC tag and future tasks to Container transport by sea in viewpoint of security strengthening. First, realization and international SCM realization structural order that cover container supply chain whole of international standardization and association between industry are certainly needed. Second, it may have to try in technical development for IC tag Ratio that can read elevation moment develop suitable IC tag or reader in International Standard. Third, Need to establish concrete use policy as soon as possible in national dimension at the same time effort for international standard normalization of frequency. Finally, it shows to uses jointly with electron sealing and must solve problem about usable plan and information leak.

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Modeling of Sediment Transport and Sand Bank Formation in a Macrotidal

  • Park, Moon-Jin
    • Journal of the korean society of oceanography
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    • 제35권1호
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    • pp.1-10
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    • 2000
  • A two-dimensional numerical model was applied to investigate the sediment transport and sand bank formation in a macrotidal sea, the Kyunggi and Asan Bays. The tidal residual currents show quite complex pattern including counter-rotating eddies off the northwestern corner of the Dugjeok Island that reflect the promontory effect. Complex residual eddies are also present off the coast of the Taeanbando and in the Asan Bay. Net sediment transport pattern shows that sandy sediments in the Kyunggi and Asan Bays are generally transported landward from the outer sea suggesting sediment trapping inside the bays. This phenomenon may be related to the formation and maintenance of numerous sand banks in this macrotidal sea. Alternate occurrences of deposition and erosion predicted from the numerical model along the coast of the Taeanbando with strong deposition on the southwestern part of the 'Jangansatoe'(JSB), a large sand ridge off the coast of the Taeanbando appear to reflect the loose connection of JSB, The 'Joongangcheontoe', a central sand bank (CSB) with the main axis in the NW-SE direction in the Asan Bay may undergo a modification with strong deposition along the northeastern flank. These results indicate that the sand banks are actively modified and maintained by the strong tidal currents in this shallow macrotidal sea.

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