• KSBB Journal
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• v.25 no.3
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• pp.205-214
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• 2010

Many successive liquid-liquid extractions occur enabling purification of the crude material to occur. In high performance counter-current chromatography (HPCCC), crude material is partitioned between two immiscible layers of solvent phases. The stationary phase (SP) is retained by hydrodynamic force field effect and the mobile phase (MP) is pumped through the column. Purification occurs because of the different solubility of the components in the liquid mobile and stationary phases. There are many key benefits of liquid stationary phases such as high mass and volume injection loadings, total sample recovery, and easy scale-up. Many researchers showed that predictable scale-up from simple test is feasible with knowledge of the stationary phase retention for the planned process scale run. In this review we review the recent advances in HPCCC research and also describe the key applications such as natural products and synthetics (small or large molecules).

• 한국전산유체공학회:학술대회논문집
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• 2004.10a
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• pp.127-130
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• 2004

In this study, three-dimensional numerical calculations are peformed to simulate the flow and heat transfer in helically coiled tube steam generator employing a commercial CFD (Computational Fluid Dynamics) code. The problem considered herein includes the boiling phase change flow of tube side fluid and the single-phase counter-current flow of shell side hot fluid transferring heat to the tube side flow thru the tube wall. Detailed investigations are performed for both shell-side and tube-side flow fields in terms of density and volume fractions of each phase of fluids as well as for the tube wall heat transfer field in terms of heat transfer coefficients.

• Nuclear Engineering and Technology
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• v.56 no.3
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• pp.886-892
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• 2024

The cladding temperatures and axial mass distribution computed by MAAP5 were compared with their measured values in the test bundle of the Phebus Test FPT0. The computed cladding temperatures were in good agreed with the measured values in the pre-transient phase. In the transient heat-up phase, the computed temperatures were overestimated by the Baker-Just correlation in MAAP5, but the computed temperatures could simulate the subsequently measured values. The computed mass distribution in the axial direction was in qualitative agreement with the measured one for post-test fuel damage observations. The calculated flow areas of inner and outer regions in the test bundle were compared with the photographic observations. MAAP5 computed them at the height of 0.2 m where the molten pool formed was in qualitative agreement with the photographic observations. It was found that the remaining steam flow paths might be caused by the gas-liquid two-phase flow counter-current flow limitation.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.12 no.1
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• pp.102-111
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• 2000

A numerical model which simulates the simultaneous heat and mass transfer within a vertical tube GAX absorber was developed. The ammonia vapor and the solution liquid are in counter-current flow, and the hydronic fluid flows counter to the solution liquid. The film thickness and the velocity distribution of the liquid film were obtained by matching the shear stress at the liquid-vapor interface. Two-dimensional diffusion and energy equations were solved in the liquid film to give the temperature and concentration, and a modified Colburn-Drew analysis was used for the vapor phase to determine the heat and mass fluxes at the liquid-vapor interface. The model was applied to a GAX absorber to investigate the absorption rates, temperature and concentration profiles, and mass flow rates of liquid and vapor phases. It was shown that the mass flux of water was negligible compared with that of ammonia except the region near the liquid inlet. Ammonia absorption rate increases rapidly near the liquid inlet and decrease slowly. Both the absorption rate of ammonia vapor and the desorption rate of water near the liquid inlet increase as the vapor mass flow rate increases, but the mass fluxes of the ammonia and the water near the liquid outlet decrease as the mass flow rate of the vapor increases.

• Proceedings of the KSME Conference
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• 2000.04b
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• pp.795-800
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• 2000

A CCFL(Counter Current Flow Limit) test have been performed in narrow annular gaps with large diameter, because it has been confirmed that the CCFL phenomena affected the critical power in hemispherical narrow gap geometries from the SONATA(Simulation Of Naturally Arrested Thermal Attack)-IV (In-Vessel)/VISU(Visualization)-II experiments. The objectives of the CCFL experiments are to investigate the small gap sizes(1, 2mm) effect on CCFL under the large diameter condition and to confirm the findings of the VISU-II study that global dryout in hemispherical narrow gaps was induced by the CCFL. The test section was made of acrylic resin to allow visual observation on the two-phase flow behaviors inside annular gaps. It was observed from visualization that a part of water supplied was accumulated in the upper plenum and a significant increase in the differential pressure across the gap was occurred, which was the definition of the CCFL occurrence in this experimental study. From the experimental results in annular gap with large diameter it can be known that an increase in the differential pressure was not big at small air flow-rates. When the CCFL was occurred, the differential pressure across gaps was increased significantly and a water accumulated in the upper plenum. The occurrence of CCFL was correlated using the Wallis parameter.

• Transactions of the Korean hydrogen and new energy society
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• v.21 no.3
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• pp.158-166
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• 2010

The purification of two liquid phases ($H_2SO_4$ phase and HIx phase) formed from a Bunsen reaction in Sulfur-Iodine (SI) hydrogen production process was investigated in order to operate SI process efficiently. The each synthetic solution for two liquid phases contained impurities was prepared on the basis of a proper composition obtained from Bunsen reaction. The purification of each solution was performed by counter-current flow using a packed column at different temperatures and $N_2$ flow rates. As the results of purification, impurities existed in each phase were decreased with increasing the temperature and the $N_2$ flow rate. In particular, the increase of the $N_2$ flow rate at the lower temperatures was effective to remove impurities by a reverse Bunsen reaction without side reactions. On the whole, it may be concluded that the purification of each phase is accomplished by mixing effects of the stripping, the evaporation, and the reverse Bunsen reaction.

• 제어로봇시스템학회:학술대회논문집
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• 2001.10a
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• pp.100.3-100
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• 2001

This article deals with the development of a mathematical model for the finishing polycarbonate polymerization process using a horizontal rotating disk-ring reactor with counter-current gas sweeping and the performance analysis of the reactor system by using the model. Here we intend to propose a model describing the reactor system consisting of two phases, in which by-product phenol is removed from the polymer of high molecular weight compatible with the products of commercial grades. The vapor phase is represented by a tanks-ln-series model while the polymer melt phase is regarded as a plug flow reactor.

• Proceedings of the KSME Conference
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• 2001.06d
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• pp.447-452
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• 2001

Quenching phenomena of hemispherical downward facing convex surfaces with narrow gaps have been investigated experimentally. Experiments employed test sections having 1 and 2 mm in gap thickness and 1 atm in system pressure. From interpretations of the temperature and the heat flux history, it was found that the flooding inside the gap was restricted by CCFL phenomena and quenching process was propagated from lower to upper region of the internal copper shell. The ratio of the maximum heat fluxes at 1 mm to 2mm in gap thickness was the almost same that obtained by steady state experiments. The quenching scenario of the hemispherical downward facing surface with narrow gap has been suggested.

• Proceedings of the KSME Conference
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• 2001.06e
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• pp.235-240
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• 2001

The CHFG (Critical Heat Flux in Gap) test results have been evaluated to quantify the critical power in hemispherical narrow gaps and a new correlation has been developed. The CHFG test results have shown that increases in the gap thickness and pressure lead to an increase in critical power. The pressure effect on the critical power was found to be much milder than predictions by CHF correlations of other researches. From the CHFG test results, a new correlation on critical power in the hemispherical gap has been developed using the non-dimensional parameters as follows: $$\frac{qCHF}{{\rho}g^hfg}{\cdot}4\sqrt{\frac{{\rho}_g^2}{g{\sigma}{\Delta}{\rho}}=\frac{0.1042}{1+0.1375({\rho}g/{\rho}l)^{0.21}(D/s)}$$ The developed correlation has been expanded to apply the spherical geometry using the Siemens/KWU's correlation.