• Title/Summary/Keyword: Cosmetic Surfactant

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A STUDY OF GEL STRUCTURE IN THE NONIONIC SURFACTANT / CETOSTEARYL ALCOHO L/ WATER TERNARY SYSTEMS BY DIFFERENTIAL SCANNING CALORIMETER

  • Yoon, Moung-Seok;Chung, Youn-Bok;Kun Han
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.26 no.1
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    • pp.213-232
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    • 2000
  • Cetostearyl alcohol has been incorporated into cosmetic or pharmaceutial emulsions to give them an appropriate consistency and a long term stability. It is well known that cetostearyl alcohol forms a gel phase with a nonionic surfactant in an aqueous system, and the properties of the gel phase depend on several factors such as the ratio of fatty alcohols. The aim of the present Paper is to investigate the effect of the structural difference of the lipophilic part of surfactants on the stability of the gel phase in the nonionic surfactant / cetostearyl alcohol / water ternary systems using differential scanning calorimeter. It is concluded that the gel phase formed by the surfactant having the bended alkyl chain is more unstable than that formed by the case of the straight alkyl chain, and we discussed the reason why the former is more unstable after long term storage by means of the measurements of the ${\Delta}$H.

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The effect of the structure of each component on the o/w microemulsion droplet size and stability

  • Changgui Han;You
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.22 no.2
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    • pp.20-40
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    • 1996
  • The oil in water type ME of 4 component system was composed with POE monoalkyl ether and POE sorbitan monoalkyl ester as surfactant, saturated hydrocarbon, side chain structure and aromatic structure as oil, and glycerine as cosurfactant using high pressure homogenizer. The objective of this study was to examine the role of surfactant and oil structure on droplet size and stability. The experimental results showed that the droplet size was smaller with bigger polarity of oil, less hydrocarbon, longer hydrophilic chain of surfactant and higher concentration of glycerine. SQ and LP systems showed very stable but AB and ISB system unstable microemulsion.

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Gel Type Formulation Utilizing Polymer-Surfactant Interaction (폴리머와 계면활성제의 상호작용을 이용한 젤타입 제형의 제조)

  • Kim, Dong-Joo;Kang, Tae-Jun;Lee, Cheon-Koo;Lee, Jung-No
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.33 no.1 s.60
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    • pp.7-10
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    • 2007
  • The interaction between polymers and surfactants was investigated by means of rheological and surface tension measurements. The polymers used in this study were acrylates/$C_{10-30}$ alkyl acrylate crosspolymer (AC) and ammonium acryloyldimethyltaurate/VP copolymer (AV). And the surfactants were PEG-40 hydrogenated castor oil (HC) and polysorbate 60 (P60). HC and P60 made the micelles intervening between AC polymers, resulting in the increase of viscosity. However, HC showed a similar behavior over the wider range of surfactant concentration than P60. Regarding of surface tensions in the same range of surfactant concentration, AC/HC solution showed the area of increasing surface tension with surfactant concentration in contrast to the AC/P60 solution showing no increasing area. It is assumed that the micelles between AC/HC were formed so cooperatively and strongly that the surfactants located at the surface originally moved to the micelles.

Development of a Natural Surfactant from Extracts of Saponaria officinalis L. (비누풀 잎 추출물로부터 천연 계면활성제 개발)

  • Jang, A Reum;Kim, Hyo Jeong;Kim, Kwang Soo;Park, Eun Kyung
    • KSBB Journal
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    • v.28 no.3
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    • pp.202-207
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    • 2013
  • In this study, saponin content of extract from modified preconditioning process was investigated in Saponaria officinalis L. for cosmetic natural surfactant. Saponin content in steamed leaves from S. officinalis L. was about three times more than that in dried leaves (tea saponin and quillaja saponin). And saponin extracts from steamed leaves was excellently shown in both forming force and forming stability. In emulsion activity, saponin extracts from steamed leaves had a similar level to quillaja saponin and tea saponin. Saponin extracts from steamed leaves in S. officinalis L. showed nontoxic effect below in $1,000{\mu}g/mL$ of concentration and dose-dependent inhibition of NO production. From the experiment, the extracts of S. officinalis L. showed good cosmetic agent.

Nano-emulsion Formed with Phospholipid-Nonionic Surfactant Mixtures and its Stability (인지질-비이온계면활성제 혼합물로 형성된 나노에멀젼과 이의 안정성)

  • Cho, Wan Goo;Kim, Eun Hee
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.40 no.3
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    • pp.221-226
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    • 2014
  • IIn this study, O/W type nano-emulsions were prepared by phospholipid-nonionic surfactant mixtures and octyldodecylmyristate using the phase transition low-energy emulsification method. The nano-emulsions were formed only in the very narrow area of the concentration of mixed surfactant and oil molar ratio of around 1 : 1. The particle size of the emulsions was decreased as adding the aqueous phase into the emulsions after phase inversion point unlike the emulsions formed only with nonionic surfactant. Nano-emulsion was stable at room temperature for more than a month. Thus, the nano-emulsions containing phospholipids can be widely used as a cosmetic formulations.

The effects of surfactant and cosurfactant on the stability and rheological properties of O/W microemulsion (계면활성제와 보조계면 활성제가 O/W형 microemulsion의 안정성과 유동특성에 미치는 영향)

  • 오주영;백승석
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.20 no.1
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    • pp.52-63
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    • 1994
  • It was investigated that the effects of surfactant to cosurfactant ratio on the stability and rheological properties of o/w microemulsion. The stability of microemulsion was good in the surfactant to cosurfactant ratio 20/40 - 30/30. In the point of rheological properties, a yield stress meande the inner structure formation was detected and the area of hysteresis loop was increased with increasing of surfactant content of the ratio. The microemulsion prepared by the Microfluidizer was characterized by rheopetic.

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THE STUDY ON STABLE EMULSION SYSTEM AND SELECTIVE ADDITION OF ACTIVE INGREDIENT IN W/O/W ONE STEP MULTIPLE EMULSION

  • Kim, Se-gie;Park, Hee-nam;Kim, Tae-kyoo
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.24 no.3
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    • pp.96-104
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    • 1998
  • It was possible to produce W/O/W one step multiple emulsion on the system which satisfied following conditions. 1. 1-5% of hydrophilic liquid surfactant over HLB20 and lipophilic liquid surfactant which has HLB 3∼5 2. Non wax copolymers as oil thickener 3. More than 0.5% of carbomer as aqueous thickener 4. The manufacturing process which neutralize the dispersed carbomer (2.0% in water), after emulsifying. For the selective addition into inner and outer aqueous phase, we melted the glucose in water before emulsifying. Using an Anthrone analysis method, we analyzed the encapsulation yield of glucose in inner water phase. It was possible to raise the water encapsulation yield of the multiple emulsion through the following conditions. 1. Using of anionic hydrophilic surfactant(HLB 40) and lipophilic surfactant (HLB 3∼5) 2. Controlling the ratio of hydrophilic surfactant and lipophilic surfactant 3. Strengthening interface with increase of non wax oil thickener. When the separated adding process of glucose was adopted, approximately 85% of glucose was added selectively within inner aqueous phase.

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A Study on Emulsion Stability of O/W and W/S Emulsion according to HLB of Emulsifier (유화제의 HLB에 따른 O/W 및 W/S 에멀젼의 유화 안정성에 관한 연구)

  • Yeon, Jae Young;Shin, Bo Ram;Kim, Ta Gon;Seo, Jeong Min;Lee, Cheong Hee;Lee, Sang Gil;Pyo, Hyeong Bae
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.40 no.3
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    • pp.227-236
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    • 2014
  • In this study, O/W and W/S emulsions were prepared by combining oils having different required hydrophilic lipophilic balance (HLB) values under the diverse conditions of HLB values composed of a hydrophilic surfactant and a lipophilic surfactant and their stability was investigated. Results showed that the higher the viscosity of O/W emulsions was as the lower the HLB value of emulsifier and emulsion particle showed a tendency to be a smaller and compact and stabler in centrifugal filtration. W/S emulsions also showed a similar tendency to be a smaller and compact as HLB values of emulsifier was higher and stabler in centrifugal filtration. However, the viscosity of W/S emulsion tended to get lower in HLB conditions of all emulsifiers as the time passed. This indicated that the emulsions had an unstable feature in long-term stability. In conclusion, the results showed opposite to the known theory that O/W emulsion is proper to be applied by nonionic surfactant with a high HLB value and W/S emulsion to be applied by nonionic surfactant with a low HLB value and provide useful information for the cosmetics research and related areas.